Reactive hot-melt-type adhesive granules for fabricating insulating glass
View Patent ↗A mixture of at least two thermoplastic particles having reactive grups which when melted and mixed react to form a high molecular weight polymer. The blend of particles when molten is particularly useful in forming double insulating glass or plastic panels.
1. A blend of reactive thermoplastic polymer particles which comprises:
a) a first portion of the particle blend comprises thermoplastic polymers with reactive groups selected from the group consisting hydroxyl groups, amino groups, carboxyl groups, carboxylic anhydride groups, mercapto groups, silane groups, hydrosilyl groups and mixtures thereof, said thermoplastic polymer comprising a block copolymer selected from the group consisting of styrene-butadiene, styrene-butadiene-styrene, styrene-isoprene, styrene-isoprene-styrene, styrene-ethylene-butylene-styrene and styrene-ethylene-propylene-styrene, and mixtures thereof;
b) a second portion of the particle blend comprises (i) thermoplastic polymers with reactive groups selected from the group consisting of isocyanate groups, epoxide groups and reactive olefinically unsaturated double bonds, (ii) thermoplastic polymers containing water-binding fillers or (iii) mixtures thereof; and
c) optionally the blend particles contain auxiliaries and additives which do not react with the functional polymers of the a) and b) particles as a part of the particle a), b) or both or as separate particles;
wherein said blend is in the form of granules, said granules having a mean particle size from 0.5 millimeter (mm) to 40 millimeter (mm).
2. A blend of reactive thermoplastic polymer particles, said blend comprising:
a) first granules comprising a first thermoplastic polymer comprising at least one reactive group selected from the group consisting of hydroxyl groups, amino groups, carboxyl groups, carboxylic anhydride groups, mercapto groups, silane groups, hydrosilyl groups, and combinations thereof, said thermoplastic polymer comprising a block copolymer selected from the group consisting of styrene-butadiene, styrene-butadiene-styrene, styrene-isoprene, styrene-isoprene-styrene, styrene-ethylene-butylene-styrene and styrene-ethylene-propylene-styrene, and mixtures thereof; and
b) second granules comprising
(i) a second thermoplastic polymer comprising at least one reactive group selected from the group consisting of isocyanate groups, epoxide groups, and reactive olefinically unsaturated double bonds, and combinations thereof,
(ii) a third thermoplastic polymer containing water-binding fillers, or
(iii) a mixture thereof
said blend being in the form of a granulation, said first granules and said second granules having a mean particle size from 0.5 millimeter (mm) to 40 millimeter (mm).
3. A blend of reactive thermoplastic polymer particles which comprises:
a) first particles comprising thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof, said thermoplastic polymers having reactive groups selected from the group consisting of hydroxyl groups, amino groups, carboxyl groups, carboxylic anhydride groups, mercapto groups, silane groups, hydrosilyl groups and mixtures thereof;
b) second particles comprising (i) thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof; said thermoplastic polymers having reactive groups selected from the group consisting of isocyanate groups, epoxide groups, and combinations thereof, (ii) thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof; said thermoplastic polymers containing water-binding fillers or (iii) mixtures thereof; and
optionally auxiliaries and additives that do not react with the functional polymers of the first particles and the second particles, said auxiliaries and additives being present in the first particles, the second particles, as separate particles or a combination thereof,
said blend being in the form of granules, said granules having a mean particle size from 0.5 millimeter to 40 millimeter.
4. The blend of reactive thermoplastic polymer particles as claimed in claim 3 wherein the particles of parts a), b) and optionally c) of the blend are granules with a mean particle size of from 2 mm to 20 mm.
5. The blend of reactive thermoplastic polymer particles of claim 3 wherein the auxiliaries and additives comprise at least one member selected from the group consisting of catalysts, drying agents, flow aids, dyes and pigments.
6. The blend of reactive thermoplastic polymer particles of claim 3 wherein the particles of parts a), b) and optionally c) of the blend comprise granules with a mean particle size of from 1 to 30 mm.
7. The blend of reactive thermoplastic polymer particles as claimed claim 3 wherein the surface of the granules is treated with at least one member selected from the group consisting of tack-reducing agents and moisture-binding agents.
8. The blend of reactive thermoplastic polymer particles as claimed in claim 7 wherein the at least one tack-reducing agent is selected from the group consisting of carbon black, highly disperse silica, polyethylene powder, talcum, waxes and paraffins.
9. A blend of reactive thermoplastic polymer particles which comprises:
a) first particles comprising thermoplastic polymers selected from the group consisting of, elastomeric block copolymers, polyisobutylenes and combinations thereof, said thermoplastic polymers having reactive groups selected from the group consisting of hydroxyl groups, amino groups, carboxyl groups, carboxylic anhydride groups, mercapto groups, silane groups, hydrosilyl groups and mixtures thereof; and
b) second particles comprising (i) thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof, said thermoplastic polymers having reactive groups selected from the group consisting of isocyanate groups, epoxide groups, and reactive olefinically unsaturated double bonds, (ii) thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof, said thermoplastic polymers containing water-binding fillers or (iii) mixtures thereof.
10. The blend of reactive thermoplastic polymer particles as claimed in claim 9 wherein the reactive groups of parts a) and b) of the blend are present in substantially stoichiometric quantities.
11. The blend of reactive thermoplastic polymer particles as claimed in claim 9 wherein the surface of the granules is treated with at least one member selected from the group consisting of tack-reducing agents and moisture-binding agents.
12. The blend of reactive thermoplastic polymer particles as claimed in claim 11 wherein the at least one tack-reducing agent is selected from the group consisting of carbon black, highly disperse silica, polyethylene powder, talcum, waxes and paraffins.
13. The blend of reactive thermoplastic polymer particles as claimed in claim 9 wherein the particles of parts a) and b) of the blend are granules with a mean particle size of from 0.5 mm to 40 mm.
14. The blend of reactive thermoplastic polymer particles of claim 9 wherein the particles of parts a) and b) of the blend comprise granules with a mean particle size of from 2 mm to 20 mm.
15. The blend of reactive thermoplastic polymer particles of claim 9 wherein the granules comprise a non-tacky surface layer.
16. The blend of reactive thermoplastic polymer particles of claim 15 wherein the non-tacky surface layer comprises a continuous layer that covers more than 90% of the surface of the granules.
17. The blend of reactive thermoplastic particles of claim 9 , further comprising auxiliaries and additives that do not react with the functional polymers of the first particles and the second particles, said auxiliaries and additives being present in the first particles, the second particles, as separate particles or a combination thereof.
18. The blend of reactive thermoplastic polymer particles claimed in claim 17 wherein the auxiliaries and additives are comprised of at least one member selected from the group consisting of catalysts, drying agents, flow aids, antiagers, dyes and pigments.
19. A blend of reactive thermoplastic polymer particles which comprises:
a) first particles comprising thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof, said thermoplastic polymers having reactive groups selected from the group consisting of hydroxyl groups, amino groups, carboxyl groups, carboxylic anhydride groups, mercapto groups, and mixtures thereof; and
b) second particles comprising (i) thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof, said thermoplastic polymers having reactive groups selected from the group consisting of isocyanate groups, epoxide groups, and reactive olefinically unsaturated double bonds, (ii) thermoplastic polymers selected from the group consisting of poly-α-olefins, elastomeric block copolymers, polyisobutylenes and combinations thereof, said thermoplastic polymers containing water-binding fillers or (iii) mixtures thereof.