Articles and sheets containing glass-filled poly(arylene ether)-polyolefin composition
View Patent ↗An article includes a reinforced thermoplastic composition containing specific amounts of a poly(arylene ether), a homopolymer of an alkenyl aromatic monomer, a polyolefin, a hydrogenated block copolymer with a high styrene content, an unhydrogenated block copolymer, and glass fibers. The composition contributes very high stiffness and high impact strength to the article.
1. An article comprising a thermoplastic composition, wherein the thermoplastic composition comprises the reaction product of:
about 10 to about 46 weight percent of a poly(arylene ether);
about 2 to about 30 weight percent of a homopolymer of an alkenyl aromatic monomer, wherein the weight ratio of the homopolymer of an alkenyl aromatic monomer to the poly(arylene ether) is at least about 1:10;
about 15 to about 50 weight percent of a polyolefin;
about 1 to about 15 weight percent of a hydrogenated block copolymer of alkenyl aromatic compound and a conjugated diene having an alkenyl aromatic content of 40 to about 90 weight percent;
about 1 to about 15 weight percent of an unhydrogenated block copolymer of alkenyl aromatic compound and a conjugated diene; and
about 5 to less than 20 weight percent of glass fibers;
wherein all weight percents are based on the total weight of the thermoplastic composition.
2. The article of claim 1 , wherein the poly(arylene ether) comprises a plurality of structural units of the formula
wherein for each structural unit, each Q 1 is independently halogen, primary or secondary C 1 -C 8 alkyl, phenyl, C 1 -C 8 haloalkyl, C 1 -C 8 aminoalkyl, C 1 -C 8 hydrocarbonoxy, or C 2 -C 8 halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; and each Q 2 is independently hydrogen, halogen, primary or secondary C 1 -C 8 alkyl, phenyl, C 1 -C 8 haloalkyl, C 1 -C 8 aminoalkyl, C 1 -C 8 hydrocarbonoxy, or C 2 -C 8 halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms.
3. The article of claim 1 , wherein the poly(arylene ether) comprises a copolymer of 2,6-dimethylphenol and 2,3,6-trimethylphenol.
4. The article of claim 1 , wherein the homopolymer of an alkenyl aromatic monomer is a polymerization product of an alkenyl aromatic monomer of the formula
wherein R 1 is hydrogen, C 1 -C 8 alkyl, or halogen; Z is vinyl, halogen, or C 1 -C 8 alkyl; and p is 0 to 5.
5. The article of claim 1 , wherein the homopolymer of an alkenyl aromatic monomer comprises homopolystyrene.
6. The article of claim 1 , wherein the polyolefin comprises a homopolymer or copolymer having at least about 80 weight percent of units derived from polymerization of ethylene, propylene, butylene, or a mixture thereof.
7. The article of claim 1 , wherein the polyolefin is a propylene polymer; and
wherein the propylene polymer comprises a homopolymer of polypropylene, or a random, graft, or block copolymer of propylene and at least one olefin selected from ethylene and C 4 -C 10 alpha-olefins, with the proviso that the copolymer comprises at least about 80 weight percent of repeating units derived from propylene.
8. The article of claim 1 , wherein the hydrogenated block copolymer comprises:
(A) at least one block derived from an alkenyl aromatic compound having the formula
wherein R 2 and R 3 each represent a hydrogen atom, a C 1 -C 8 alkyl group, or a C 2 -C 8 alkenyl group; R 4 and R 8 each represent a hydrogen atom, a C 1 -C 8 alkyl group, a chlorine atom, or a bromine atom; and R 5 -R 7 each independently represent a hydrogen atom, a C 1 -C 8 alkyl group, or a C 2 -C 8 alkenyl group, or R 4 and R 5 are taken together with the central aromatic ring to form a naphthyl group, or R and R are taken together with the central aromatic ring to form a naphthyl group including; and
(B) at least one block derived from a conjugated diene, in which the aliphatic unsaturated group content in the block (B) is reduced by hydrogenation.
9. The article of claim 1 , wherein the hydrogenated block copolymer comprises a styrene-(ethylene-butylene)-styrene triblock copolymer.
10. The article of claim 1 , wherein the hydrogenated block copolymer has a styrene content of about 50 to about 85 weight percent.
11. The article of claim 1 , wherein the unhydrogenated block copolymer comprises a styrene-butadiene diblock copolymer or a styrene-butadiene-styrene triblock copolymer.
12. The article of claim 1 , wherein the glass fibers have a diameter of about 2 to about 25 micrometers.
13. The article of claim 1 , wherein the thermoplastic composition further comprises about 0.5 to about 10 weight percent of a polypropylene-polystyrene graft copolymer having a propylene polymer backbone and one or more styrene polymer grafts wherein all weight percentages are based on the total weight of the thermoplastic composition.
14. The article of claim 1 , wherein the thermoplastic composition further comprises about 1 to about 15 weight percent of an ethylene/alpha-olefin elastomeric copolymer wherein all weight percentages are based on the total weight of the thermoplastic composition.
15. The article of claim 1 , wherein the thermoplastic composition further comprises about 1 to about 40 weight percent, based on the total weight of the thermoplastic composition, of a rubber-modified poly(alkenyl aromatic) resin comprising a polymer derived from at least one alkenyl aromatic monomer, and further comprising a rubber modifier in the form of a blend and/or a graft.
16. The article of claim 1 , wherein the thermoplastic composition further comprises about 1 to about 20 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, wherein the hydrogenated block copolymer has an alkenyl aromatic content of about 10 to less than 40 weight percent wherein all weight percentages are based on the total weight of the thermoplastic composition.
17. The article of claim 1 , wherein the thermoplastic composition further comprises about 0.1 to about 10 weight percent of a polyolefin-graft-cyclic anhydride copolymer wherein all weight percentages are based on the total weight of the thermoplastic composition.
18. The article of claim 1 , wherein the article is a power tool casing.
19. An article comprising a thermoplastic composition, wherein the thermoplastic composition comprises the reaction product of:
about 15 to about 30 weight percent of a poly(arylene ether) that is the polymerization product of 2,6-dimethylphenol, 2,3,6-trimethylphenol, or a combination thereof;
about 3 to about 25 weight percent of a homopolystyrene;
about 20 to about 50 weight percent of a homopolypropylene;
about 1 to about 10 weight percent of a styrene-(ethylene-butylene)-styrene triblock copolymer having an alkenyl aromatic content of about 55 to about 75 weight percent;
about 1 to about 10 weight percent of a styrene-butadiene-styrene triblock copolymer;
about 3 to about 14 weight percent of an ethylene-butylene rubber, an ethylene-propylene rubber, or a mixture thereof; and
about 5 to less than 20 weight percent of glass fibers having a diameter of about 10 to about 20 micrometers;
wherein all weight percents are based on the total weight of the thermoplastic composition.
20. A sheet comprising a thermoplastic composition, wherein the thermoplastic composition comprises the reaction product of:
about 10 to about 46 weight percent of a poly(arylene ether);
about 2 to about 30 weight percent of a homopolymer of an alkenyl aromatic monomer, wherein the weight ratio of the homopolymer of an alkenyl aromatic monomer to the poly(arylene ether) is at least about 1:10;
about 15 to about 50 weight percent of a polyolefin;
about 1 to about 15 weight percent of a hydrogenated block copolymer of alkenyl aromatic compound and a conjugated diene having an alkenyl aromatic content of 40 to about 90 weight percent;
about 1 to about 15 weight percent of an unhydrogenated block copolymer of alkenyl aromatic compound and a conjugated diene; and
about 5 to about 20 weight percent of glass fibers;
wherein all weight percents are based on the total weight of the thermoplastic composition.