Method for making a conductive thermoplastic composition
View Patent ↗PROBLEM TO BE SOLVED: To provide a production method for a thermoplastic resin composition, composed of a polyphenylene ether and a polyamide, having an electric conductivity, and excellent in balance of fluidity and impact strength, by producing with a specific process, and to provide the thermoplastic resin composition obtained thereby. SOLUTION: The thermoplastic resin composition is composed of the following component (A)-(E), wherein a weight ratio of (A)/(B) is 5/95-70/30, an amount of (C) is effective to phase-solvate (A) and (B), the amount of (D) is 0.8-10 pts.wt. per the total 100 pts.wt. of (A) and (B), and the amount of component (E) is 5-40 pts.wt. per the total 100 pts.wt. of (A) and (B). The production method for the thermoplastic resin composition is provided. (A): a polyphenylene ether, (B): a polyamide. (C): a phase-solvating agent, (D): an electrically conductive carbon black and/or a fine fibrous carbon, and (E) an improving agent for shock resistance.
1. A method of making conductive carbon black masterbatch comprising dry mixing conductive carbon black and a first resin to form a carbon black/resin mixture; and compounding the carbon black/resin mixture with a second resin, wherein the first resin is a powder having a particle size of about 20 micrometers to about 4 millimeters, and further wherein the first resin and second resin are polyamide.
2. The method of claim 1 , wherein the conductive carbon black has average particle size less than about 200 nanometers.
3. The method of claim 1 , wherein the first resin has a particle size of about 100 micrometers to about 1 millimeter.
4. The method of claim 1 , wherein the conductive masterbatch comprises about 4 to about 16 weight percent conductive carbon black based on the total weight of the conductive masterbatch.
5. The method of claim 1 , wherein the first resin and second resin are chemically identical.
6. The method of claim 1 , wherein the first resin and second resin are chemically different.
7. The method of claim 1 , wherein the conductive masterbatch comprises about 84 to about 96 weight percent resin based on the total weight of the masterbatch.
8. The method of claim 1 , wherein compounding occurs in an extruder having a feedthroat and a feedport and the second resin is added at the feedthroat and the conductive carbon black/resin mixture is added via a feedport downstream ofthe feedthroat.
9. The method of claim 1 , wherein the first resin is a polyamide and the second resin is a polyamide in pellet form and the weight ratio of the first resin to the second resin is about 1:9 to about 9:1.
10. A method of making a conductive thermoplastic composition comprising:
dry mixing conductive carbon black and a first resin to form a conductive carbon black/resin mixture;
compounding the conductive carbon black/resin mixture with a second resin to form a conductive masterbatch; and
compounding the conductive masterbatch with a third resin and fourth resin, wherein the first resin is a powder having a particle size of about 20 micrometers to about 4 millimeters and wherein the first, second and fourth resin are polyamides and the third resin is a poly(arylene ether).
11. The method of claim 10 , wherein the conductive carbon black has average particle size less than about 200 nanometers.
12. The method of claim 10 wherein the first resin has a particle size of 100 micrometers to about 1 millimeter.
13. The method of claim 10 , wherein the first resin and second resin are chemically identical.
14. The method of claim 10 , wherein the first resin and second resin are chemically different.
15. The method of claim 10 , further comprising compounding the third resin with a compatibilizer prior to compounding with the masterbatch and fourth resin.
16. The method of claim 10 , further comprising compounding the third resin with a compatibilizer, and impact modifier prior to compounding with the masterbatch and fourth resin.
17. The method of claim 10 , wherein an impact modifier and a compatibilizer are compounded with the masterbatch and third and fourth resins.
18. A method of making a conductive thermoplastic composition comprising:
dry mixing conductive carbon black and a first polyamide resin to form a conductive carbon black/resin mixture;
compounding the conductive carbon black/resin mixture with a second polyamide resin to form a conductive masterbatch;
compounding a poly(arylene ether) resin, an impact modifier and a compatibilizer to form a resin mixture; and
and compounding the conductive masterbatch and third polyamide with the resin mixture, wherein the first resin is a powder having a particle size of about 20 micrometers to about 4 millimeters.
19. The method of claim 18 , wherein the conductive masterbatch and third polyamide are added to the resin mixture concurrently.