Ion triggerable, cationic polymers, a method of making same and items using same
View Patent ↗The present invention is directed to ion triggerable, water-dispersible cationic polymers. The present invention is also directed to a method of making ion triggerable, water-dispersible cationic polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising ion triggerable, water-dispersible binder compositions and their applicability in water-dispersible personal care products, such as wet wipes.
1. A nonwoven fabric comprising fibrous material and a binder material, said binder material comprising a binder composition comprising a polymer having the structure:
wherein x=1 to about 15 mole percent; y=about 60 to about 99 mole percent; and z=0 to about 30 mole percent; Q is selected from C 1 –C 4 alkyl ammonium, quaternary C 1 –C 4 alkyl ammonium, and benzyl ammonium; Z is selected from —O—, —COO—, —OOC—, —CONH—, and —NHCO—; R 1 , R 2 , R 3 are independently selected from hydrogen and methyl; R 4 is methyl; and R 5 is selected from hydrogen, methyl, ethyl, butyl, ethylhexyl, decyl, dodecyl, hydroxyethyl, hydroxypropyl, polyoxyethylene, and polyoxypropylene;
wherein the nonwoven fabric is not dispersible when in an aqueous salt solution comprising about 0.3% to about 10% by weight of a mono or divalent salt, and the nonwoven fabric is dispersible when in water containing up to 200 ppm Ca 2+ and/or Mg 2+ ions.
2. A nonwoven fabric comprising fibrous material and a binder material, said binder material comprising a binder composition that is the polymerization product of a cationic acrylate or methacrylate and one or more alkyl acrylates or methacrylates having the structure:
wherein x=1 to about 15 mole percent: y=about 60 to about 99 mole percent; and z=0 to about 30 mole percent; R 3 is selected from hydrogen and methyl; R 4 is methyl; and R 5 is selected from hydrogen, methyl, ethyl, butyl, ethylhexyl, decyl, dodecyl, hydroxyethyl, hydroxypropyl, polyoxyethylene, and polyoxypropylene;
wherein the nonwoven fabric is not dispersible when in an aqueous salt solution comprising about 0.3% to about 10% by weight of a mono or divalent salt and the nonwoven fabric is dispersible when in water containing up to 200 ppm Ca 2+ and/or Mg 2+ ions.
3. A nonwoven fabric comprising fibrous material and a binder material, said binder material comprising a binder composition having the structure:
wherein x=about 3 to about 6 mole percent, y=about 94 to about 97 mole percent and R 4 is methyl;
wherein the nonwoven fabric is not dispersible when in an aqueous salt solution comprising about 0.3% to about 10% by weight of a mono or divalent salt, and the nonwoven fabric is dispersible when in water containing up to 200 ppm Ca 2+ and/or Mg 2+ ions.
4. A fibrous substrate comprising:
fibrous material; and
a binder composition for binding said fibrous material into an integral web, said binder composition comprising the solution polymerization product of a vinyl-functional cationic monomer, a hydrophobic vinyl monomer with a methyl side chain, and one or more hydrophobic vinyl monomers with alkyl side chains of 1 to 4 carbon atoms;
wherein the fibrous material is not dispersible when in an aqueous salt solution comprising about 0.3% to about 10% by weight of a mono or divalent salt, and the fibrous material is dispersible when in water containing up to 200 ppm Ca 2+ and/or Mg 2+ ions.
5. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from [2-(acryloxy)ethyl]dimethyl ammonium chloride, [2-(methacryloxy)ethyl]dimethyl ammonium chloride, [2-(acryloxy)ethyl]trimethyl ammonium chloride, [2-(methacryloxy)ethyl]trimethyl ammonium chloride, (3-acrylamidopropyl) trimethyl ammonium chloride N,N-diallyldimethyl ammonium chloride, [2-(acryloxy)ethyl]dimethylbenzyl; ammonium chloride, and [2-(methacryloxy)ethyl]dimethylbenzyl ammonium chloride.
6. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from precursor monomers selected from vinylpyridine, dimethylaminoethyl acrylate and dimethylaminoethyl methacrylate followed by quaternization of the polymer.
7. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from [2-(acryloxy)ethyl]dimethyl ammonium chloride, [2-(acryloxy)ethyl]dimethyl ammonium bromide, [2-(acryloxy)ethyl]dimethyl ammonium iodide, and [2-(acryloxy)ethyl]dimethyl ammonium methyl sulfate.
8. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from [2-(methacryloxy)ethyl]dimethyl ammonium chloride, [2-(methacryloxy)ethyl]dimethyl ammonium bromide, [2-(methacryloxy)ethyl]dimethyl ammonium iodide, and [2-(methacryloxy)ethyl]dimethyl ammonium methyl sulfate.
9. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from [2-(acryloxy)ethyl]trimethyl ammonium chloride, [2-(acryloxy)ethyl]trimethyl ammonium bromide, [2-(acryloxy)ethyl]trimethyl ammonium iodide, and [2-(acryloxy)ethyl]trimethyl ammonium methyl sulfate.
10. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from [2-(methacryloxy)ethyl]trimethyl ammonium chloride, [2-(methacryloxy)ethyl]trimethyl ammonium bromide, [2-(methacryloxy)ethyl]trimethyl ammonium iodide, and [2-(methacryloxy)ethyl]trimethyl ammonium methyl sulfate.
11. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from (3-acrylamidopropyl) trimethyl ammonium chloride, (3-acrylamidopropyl) trimethyl ammonium bromide, (3-acrylamidopropyl) trimethyl ammonium iodide, and (3-acrylamidopropyl) trimethyl ammonium methyl sulfate.
12. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from N,N-diallyldimethyl ammonium chloride, N,N-diallyldimethyl ammonium bromide, N,N-diallyldimethyl ammonium iodide, and N,N-diallyldimethyl ammonium methyl sulfate.
13. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from [2-(acryloxy)ethyl]dimethylbenzyl ammonium chloride, [2-(acryloxy)ethyl]dimethylbenzyl ammonium bromide, [2-(acryloxy)ethyl]dimethylbenzyl ammonium iodide, and [2-(acryloxy)ethyl]dimethylbenzyl ammonium methyl sulfate.
14. The fibrous substrate of claim 4 , wherein the vinyl-functional cationic monomer is selected from [2-(methacryloxy)ethyl]dimethylbenzyl ammonium chloride, [2-(methacryloxy)ethyl]dimethylbenzyl ammonium bromide, [2-(methacryloxy)ethyl]dimethylbenzyl ammonium iodide, and [2-(methacryloxy)ethyl]dimethylbenzyl ammonium methyl sulfate.
15. The fibrous substrate of claim 4 , wherein the hydrophobic vinyl monomer is selected from branched or linear alkyl vinyl ethers, vinyl esters, acrylamides, and acrylates.
16. A water-dispersible article comprising the fibrous substrate of claim 4 .
17. A fibrous substrate comprising:
fibrous material; and
a binder composition for binding said fibrous material into an integral web, said binder composition comprising a composition that is the solution polymerization product of a cationic acrylate or methacrylate and one or more alkyl acrylates or methacrylates, the polymerization product having the structure:
wherein x=1 to about 15 mole percent; y=about 60 to about 99 mole percent; and z=0 about 30 mole percent; Q is selected from C 1 –C 4 alkyl ammonium, quaternary C 1 –C 4 alkyl ammonium and benzyl ammonium; Z is selected from —O—, —COO—, —OOC—, —CONH—, and —NHCO—; R 1 , R 2 , R 3 are independently selected from hydrogen and methyl; R 4 is methyl; and R 5 is selected from hydrogen , methyl, ethyl, butyl, ethylhexyl, decyl, dodecyl, hydroxyethyl, hydroxypropyl, polyoxyethylene, and polyoxypropylene;
wherein the fibrous material is not dispersible when in an aqueous salt solution comprising about 0.3% to about 10% by weight of a mono or divalent salt, and fibrous material is dispersible when in water containing up to 200 ppm Ca 2+ and/or Mg 2+ ions.
18. The fibrous substrate of claim 17 , wherein said polymerization product has the structure:
wherein x=1 to about 15 mole percent; y=about 60 to about 99 mole percent; and z=0 to about 30 mole percent; R 3 is selected from hydrogen and methyl; R 4 is methyl; and R 5 is selected from hydrogen, methyl, ethyl, butyl, ethylhexyl, decyl, dodecyl, hydroxyethyl, hydroxypropyl, polyoxyethylene, and polyoxypropylene.
19. The fibrous substrate of claim 17 , wherein said polymerization product has the structure:
wherein x=1 to about 15 mole percent; y=about 85 to about 99 mole percent and R 4 is methyl.
20. The fibrous substrate of claim 19 , wherein x=about 3 to about 6 mole percent, y=about 94 to about 97 mole percent and R 4 is methyl.
21. A water-dispersible article comprising the fibrous substrate of claim 17 .
22. A water-dispersible article comprising the fibrous substrate of claim 18 .
23. A water-dispersible article comprising the fibrous substrate of claim 19 .
24. A water-dispersible article comprising the fibrous substrate of claim 20 .