Method and an installation for subjecting carbon fabrics to high temperature heat treatment and to densification by chemical vapor infiltration
View Patent ↗Heat treatment is performed on preforms placed in an enclosure accompanied by sweeping with an inert gas under reduced pressure, and with a gaseous effluent being exhausted continuously via a first effluent outlet connected to an effluent exhaust circuit. At the end of the heat treatment, the first gaseous effluent outlet is closed so as to isolate the effluent exhaust circuit from the enclosure, sweeping of the enclosure with the inert gas is interrupted, and the heat-treated preforms are left in the enclosure and are subjected to densification by admitting a reagent gas into the enclosure via at least one reagent gas admission duct opening out into the enclosure, with gaseous effluent being exhausted via a second effluent outlet separate from the first, said second outlet being closed during the heat treatment step. Advantageously, metal, in particular sodium, contained in the gaseous effluent exhausted from the enclosure during the heat treatment step is neutralized.
1. A method of subjecting carbon fiber preforms to high temperature heat treatment and to densification by chemical vapor infiltration, the method comprising the steps of:
placing the carbon fiber preforms in an enclosure;
subjecting the preforms in the enclosure to a heat treatment at a temperature sufficient for eliminating all or nearly all metallic impurities contained in the carbon fibers while sweeping the enclosure with inert gas under low pressure;
during the heat treatment, continuously extracting gaseous effluent containing metallic impurities through a first effluent outlet connected to an effluent exhaust circuit;
at the end of heat treatment, closing the first gas effluent outlet so as to isolate the effluent exhaust circuit from the enclosure;
interrupting sweeping of the enclosure with inert gas; and
leaving the heat-treated preforms in the enclosure and subjecting them to densification by admitting a reagent gas into the enclosure through at least one reagent gas admission duct opening out into the enclosure, gaseous effluent being extracted through a second effluent outlet distinct from the first, said second outlet being closed during the heat treatment step.
2. A method according to claim 1 , including neutralization of sodium that is contained in the gaseous effluent extracted from the enclosure during the heat treatment step.
3. A method according to claim 2 , wherein neutralization is performed by injecting steam into an effluent exhaust pipe connected to the first effluent outlet.
4. A method according to claim 3 , wherein neutralization is performed by injecting a mixture of inert gas and steam.
5. A method according to claim 2 , wherein neutralization is performed by injecting carbon dioxide into an effluent exhaust pipe connected to the first effluent outlet.
6. A method according to claim 5 , wherein neutralization is performed by injecting a mixture of inert gas and carbon dioxide into an effluent exhaust pipe connected to the first effluent outlet.
7. A method according to claim 3 , wherein neutralization is performed continuously while the gaseous effluent is being extracted during heat treatment.
8. A method according to claim 3 , wherein neutralization is performed after the end of heat treatment by hydrating metal condensed on the wall of an exhaust pipe connected to the first effluent outlet.
9. A method according to claim 1 , wherein the effluent exhaust circuit connected to the first effluent outlet is purged after the end of the heat treatment.
10. A method according to claim 9 , wherein the effluent exhaust circuit is purged during the step of densification by chemical vapor infiltration.
11. A method according to claim 1 , wherein said duct for admitting reagent gas into the enclosure is swept by the inert gas during heat treatment.
12. A method according to claim 1 , including a step of cooling densified preforms by admitting a cooling gas into the enclosure after the step of densifying the preforms by chemical vapor infiltration, wherein the cooling gas is admitted via the first effluent outlet.
13. A method according to claim 12 , wherein the cooling gas is admitted via at least a portion of the effluent exhaust circuit.