Method and installation for heat treating carbon bodies containing sodium
View Patent ↗Carbon bodies are heated in an oven under low pressure and while being swept with an inert gas, gaseous effluent containing elemental or compound sodium in sublimed form being continuously extracted from the oven via an effluent exhaust pipe. At least one sodium-neutralizing agent is injected into the effluent exhaust pipe immediately downstream from the outlet for exhausting gaseous effluent from the oven. The sodium-neutralizing agent is selected from carbon dioxide and steam, and it can be injected continuously into the flow of gaseous effluent.
1. A method for continuously purifying a carbon fiber body by heat treating the carbon fiber body to remove sodium contained in carbon fibers, the method comprising the steps of:
placing the carbon fiber body to be treated in an oven having a gas inlet and an effluent gas outlet connected to an exhaust pipe;
heating the carbon fiber body in the oven at a temperature at which sodium contained in the carbon fibers is sublimed, under an atmosphere of inert gas supplied through the gas inlet; continuously extracting a gaseous effluent containing said inert gas and sodium in sublimed form from the oven through the effluent gas outlet and via the exhaust pipe, while maintaining within the oven a pressure lower than atmospheric pressure, and
injecting at least one sodium-neutralizing agent continuously into the gaseous effluent extracted from the oven during heat treatment at a location immediately downstream from the gas effluent outlet while maintaining any sodium contained in the gaseous effluent in sublimed form at the location of injection.
2. A method according to claim 1 , wherein the sodium-neutralizing agent is selected from carbon dioxide and steam.
3. A method according to claim 2 , wherein the injected sodium-neutralizing agent is diluted in an inert gas.
4. A method according to claim 3 , wherein the inert gas is nitrogen or argon.
5. A method according to claim 1 , wherein the sodium-neutralizing agent is injected at or downstream from a bend formed by the pipe for exhausting effluent from the oven.
6. A method according to claim 1 , wherein the sodium-neutralizing agent is injected into the exhaust pipe after the end of heat treatment in order to neutralize sodium deposited on the wall of the exhaust pipe prior to cleaning it.
7. A method according to claim 1 , wherein the carbon fiber body is heated at a temperature lying in range of about 1400° C. and about 2500° C.
8. A method according to claim 1 , wherein the pressure inside the oven is maintained at a value below about 50 kilopascals.