POLY-O-HYDROXYAMIDES, POLYBENZOXAZOLES, PROCESSES FOR PRODUCING POLY-O-HYDROXYAMIDES, PROCESSES FOR PRODUCING POLYBENZOXAZOLES, DIELECTRICS INCLUDING A POLYBENZOXAZOLE, ELECTRONIC COMPONENTS INCLUDING THE DIELECTRICS, AND PROCESSES FOR MANUFACTURING THE ELECTRONIC COMPONENTS
View Patent ↗Poly-o-hydroxyamides are cyclicized to obtain polybenzoxazoles. The poly-o-hydroxyamides provide effective filling of trenches. In particular, the poly-o-hydroxyamides can fill trenches having a width of less than 100 nm and an aspect ratio of more than 4. Further, the polybenzoxazoles of the invention are very suitable for the damascene process. A dielectric can be made from the polybenzoxazole. In turn, semiconductor devices can include the dieletric. Processes for making the poly-o-hydroxyamides, polybenzoxazoles, and semiconductor devices are included.
1. A polybenzoxazole, comprising a Formula II:
where
Q′ is
Z′ is
A′ is
X′ is
R 1 is a substituent selected from the group consisting of
R 2 is a substituent selected from the group consisting of a hydrogen atom, a trifluoromethyl group, an alkyl group having from 1 to 10 carbon atoms,
R 3 is a substituent selected from the group consisting of an alkyl group having from 1 to 10 carbon atoms and an aryl group having from 5 to 22 carbon atoms;
R 4 is a divalent substituent selected from the group consisting of
Y 1 and Y 2 each independently of one another are a radical selected from the group consisting of
where if R 4 is —CH 2 —, then x is an integer from 0 to 10; and
n is a number between 1 and 100;
m is a number between 1 and 100;
p is a number between 0 and 50;
x is a number between 1 and 10;
y is a number between 1 and 10; and
w is a number between 0 and 10, provided that Q′ and Z′ are not identical.
2. The polybenzoxazole according to claim 1 , where R 1 is a trifluoromethyl radical.
3. An electronic component, comprising a dielectric including a polybenzoxazole according to claim 1 .
4. A dielectric for an electronic component, comprising a polybenzoxzaole according to claim 1 .