Method of modifying crosslinked rubber

1. A method of modifying crosslinked rubber comprising subjecting the rubber to mechanical elongational and shear forces in the presence of a supercritical fluid that is normally gaseous, wherein the ratio by weight of rubber to said fluid is 100:1 to 20:1.

2. Method according to claim 1 wherein the supercritical fluid is ethane, ethene, propane, propene, xenon, nitrogen, ammonia, nitrous oxide, fluoroform or carbon dioxide.

3. Method according to claim 2 wherein the supercritical fluid is carbon dioxide.

4. Method according to claim 1 wherein said supercritical fluid is at a pressure of from about 90% to about 300% of its critical pressure.

5. Method according to claim 1 wherein said supercritical fluid is at a temperature expressed in ° K of about 90% to about 300% of its critical temperature.

6. Method according to claim 1 wherein the rubber is provided in finely divided form.

7. Method according to claim 6 wherein the rubber particle size is 150 microns to 5 mm.

8. Method according to claim 7 wherein said particle size is 160 to 1000 microns.

9. Method according to claim 7 wherein said particle size is 170 to 500 microns.

10. Method according to claim 1 wherein the rubber comprises a material selected from the group consisting of natural rubber, styrene-butadiene rubber, EPDM (ethylene-propylene diene rubbers), EPT (ethylene-propylene terpolymer rubbers), TPU (thermoplastic urethane rubbers), TPEs (thermoplastic elastomers), TPVs (thermoplastic vulcanizates), butyl rubber, nitrile rubber, polysulfide elastomes, polybutadiene, polyisoprene rubber, polyisobutylene, polyester rubbers, isoprene-butadiene copolymers, neoprene rubber, acrylic elastomers, diisocyanate-linked condensation elastomers, silicone rubbers, crosslinked polyethylene, ethylene-vinylacetate polymers, and mixtures thereof.

11. Method according to claim 10 wherein the rubber comprises styrene butadiene rubber.

12. Method according to claim 10 wherein the rubber comprises EPDM rubber.

13. A method of modifying crosslinked rubber comprising subjecting the rubber to mechanical elongational and shear forces in the presence of a supercritical fluid that is normally gaseous, wherein the weight content of supercritical fluid, based on the weight of rubber, is 0.5 to 3%.

14. Method according to claim 13 wherein the supercritical fluid is ethane, ethene, propane, propene, xenon, nitrogen, ammonia, nitrous oxide, fluoroform or carbon dioxide.

15. Method according to claim 14 wherein the supercritical fluid is carbon dioxide.

16. Method according to claim 13 wherein said supercritical fluid is at a pressure of from about 90% to about 300% of its critical pressure.

17. Method according to claim 13 wherein said supercritical fluid is at a temperature expressed in ° K of about 90% to about 300% of its critical temperature.

18. Method according to claim 13 wherein the rubber is provided in finely divided form.

19. Method according to claim 18 wherein the rubber particle size is 150 microns to 5 mm.

20. Method according to claim 19 wherein said particle size is 160 to 1000 microns.

21. Method according to claim 13 wherein the rubber comprises a material selected from the group consisting of natural rubber, styrene-butadiene rubber, EPDM (ethylene-propylene diene rubbers), EPT (ethylene-propylene terpolymer rubbers), TPU (thermoplastic urethane rubbers), TPEs (thermoplastic elastomers), TPVs (thermoplastic vulcanizates), butyl rubber, nitrile rubber, polysulfide elastomes, polybutadiene, polyisoprene rubber, polyisobutylene, polyester rubbers, isoprene-butadiene copolymers, neoprene rubber, acrylic elastomers, diisocyanate-linked condensation elastomers, silicone rubbers, crosslinked polyethylene, ethylene-vinylacetate polymers, and mixtures thereof.

22. Method according to claim 21 wherein the rubber comprises styrene butadiene rubber.

23. Method according to claim 21 wherein the rubber comprises EPDM rubber.