IP Library Granted Patent US 6,852,469
Granted Patent B2
US 6,852,469 · App. 10/270,599 · Granted Feb 8, 2005

Lithographic printing plate precursor

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Quick Facts
Patent No.
US 6,852,469
App. No.
10/270,599
Granted
Feb 8, 2005
Kind
B2
Abstract

A lithographic printing plate precursor comprises a support and a hydrophilic layer capable of hydrophobicizing by heat, wherein the hydrophilic layer comprises: a particulate hydrophobicizing precursor; a photo-heat converting agent; a hydrophilic polymer having a silane coupling group, and a metal complex catalyst.

Claims (20)

1. A lithographic printing plate precursor comprising a support and a hydrophilic layer capable of hydrophobicizing by heat,

wherein the hydrophilic layer comprises:

a particulate hydrophobicizing precursor;

a photo-heat converting agent;

a hydrophilic polymer having a terminal silane coupling group, and a metal complex catalysts,

wherein the hydrophilic nolymer is a polymer represented by the following general formula (1-1):

wherein R 1 , R 2 , R 3 and R 4 each independently represents a hydrogen atom or a hydrocarbon groud having 8 or less carbon atoms, m represents an inteaer of 0 to 2, n represents an integer of from 1 to 8, p represents an inteaer of from 30 to 300, Y represents —NHCOCH 3 , —CONH 2 , —CON(CH 3 ) 2 , —COCH 3 , —OH, —CO 2 M or —CONHC(CH 3 ) 2 SO 3 M, M represents a hydrogen atom, an alkaline metal, an alkaline earth metal or onium, and L represents a single bond or an organic connectina group.

2. The lithographic printing plate precursor according to claim 1 , wherein the metal complex catalyst is ametal complex composed of: a metal element selected from the group consisting of elements belonging to the groups 2A, 3B, 4A and 5A; and an oxo or hydroxyoxygen-containing compound selected from the group consisting of β-diketone, ketoester, hydroxycarboxylic acid, ester of hydroxycarboxylic acid, aminoalcohol, enolic active hydrogen compound and acetyl acetone derivative.

3. The lithographic printing plate precursor according to claim 2 , wherein the metal element constituting the metal complex catalyst is a metal element selected from the group consisting of Zr, Ti and Al.

4. The lithographic printing plate precursor according to claim 2 , wherein the acetyl acetone derivative constituting the metal complex catalyst is acetylacetoile or diacetylacetone.

5. The lithographic printing plate precursor according to claim 1 , wherein the metal complex catalyst is a mononuclear complex having from 1 to 4 acetylacetone derivative molecules per one metal element.

6. The lithographic printing plate precursor according to claim 1 , wherein the metal complex catalyst is a tris(acetylacetonato) aluminum complex salt represented by the following general formula (1):

7. The lithographic printing plate precursor according to claim 1 , which further comprises solid particles.

8. A lithographic printing plate precursor comprising a support and a hydrophilic layer capable of hydrophobicizing by heat,

wherein the hydrophilic layer comprises:

a particulate hydrophobicizing precursor;

a photo-heat converting agent;

a hydrophilic polymer having a silane coupling group, and

a metal complex catalyst,

wherein the metal complex catalyst is a metal complex composed of: a metal element selected from the group consisting of elements belonging to the groups 2A, 3B, 4A and 5A; and an oxo or hydroxyoxygen-containing compound selected from the group consisting of β-diketone, ketoester, hydroxycarboxylic acid, ester of hydroxycarboxylic acid, aminoalcohol, enolic active hydrogen compound and acetyl acetone derivative, and the acetyl acetone derivative is acetylacetone having a substituent on at least one carbon atom of the methyl group, the methylene group or the carbonyl carbon.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 15, 2007
From: FUJIFILM HOLDINGS CORPORATION (FORMERLY FUJI PHOTO FILM CO., LTD.)
To: FUJIFILM CORPORATION
Reel/Frame 018904/0001 →