Detergent compositions
View Patent ↗A particulate laundry detergent composition which comprises a detergent base powder comprising surfactant and builder and, as separate particulate components: (a) an alkali metal carbonate salt selected from carbonate, bicarbonate, sesquicarbonate and combinations thereof; and (b) a water-soluble organic acid which, when reacted with (a) in the presence of water, generates carbon dioxide gas; wherein the alkali metal carbonate salt, when taken separately, has a 90% dissolution time of less than 15 seconds, preferably less than 10 seconds, more preferably less than 7 seconds; and the water-soluble organic acid has a d 50 particle size which is in the range of from 150 to 1500 microns. The alkali metal carbonate salt preferably has an average bulk density of at most 1000 g/l, preferably at most 800 g/l, more preferably at most 600 g/l. The alkali metal carbonate salt preferably has a d 50 particle size of at most 250 microns, preferably from 1 to 200 microns, more preferably from 10 to 150 microns. The alkali metal carbonate salt is preferably sodium and/or potassium carbonate.
1. A particulate laundry detergent composition which comprises a detergent base powder comprising surfactant and builder and, as separate particulate components:
(a) an alkali metal carbonate salt selected from carbonate, bicarbonate, sesquicarbonate and combinations thereof; and
(b) a water-soluble organic acid which, when reacted with (a) in the presence of water, generates carbon dioxide gas;
wherein the alkali metal carbonate salt, when taken separately, has a 90% dissolution time of less than 15 seconds; has an average bulk density of at most 1000 g/l and a d 50 particle sixe of at most 250 microns and the water-soluble organic acid has a d 50 particle size which is in the range of from 250 to 1500 microns.
2. A composition as claimed in claim 1 , wherein the alkali metal carbonate salt has a 90% dissolution time of less than 10 seconds, preferably less than 7 seconds.
3. A composition as claimed in claim 1 , wherein the composition comprises at least 1 wt % of the alkali metal carbonate salt, preferably from 2 to 10 wt %.
4. A composition as claimed in claim 1 , wherein the alkali metal carbonate salt has an average bulk density of at most 800 g/l, preferably at most 600 g/l.
5. A composition as claimed in claim 1 , wherein the alkali metal carbonate salt has a d 50 particle size of from 1 to 200 microns, preferably from 10 to 150 microns.
6. A composition as claimed in claim 1 , wherein the alkali metal carbonate salt comprises sodium and/or potassium carbonate.
7. A composition as claimed in claim 1 , wherein the composition comprises at least 0.5 wt % of the water-soluble solid organic acid, preferably from 1 to 10 wt %, more preferably 2 to 5 wt %.
8. A composition as claimed in claim 1 , wherein the water-soluble solid organic acid has a d 50 particle size which is in the range of from 250 to 1000 microns, preferably in the range of from 350 to 750 microns.
9. A composition as claimed in claim 1 , wherein the water-soluble organic acid is selected from citric acid, succinic acid and glutaric acid.
10. A composition as claimed in claim 1 , which comprises a granular detergent base powder comprising surfactant and builder and having a bulk density of at least 0.5 kg/l.
11. A composition as claimed in claim 1 , which comprises from 5 to 60 wt % surfactant.
12. A composition as claimed in claim 1 , which comprises from 10 to 80 wt % builder.
13. A process for making a laundry detergent composition according to claim 1 , which comprises the steps of:
(i) preparing a detergent base powder, comprising surfactant and builder; followed by
(ii) dry-mixing with the base powder
(a) an alkali metal carbonate salt selected from carbonate, bicarbonate, sesquicarbonate and combinations thereof; and
(b) a water-soluble organic acid which, when reacted with (a) in the presence of water, generates carbon dioxide gas
wherein the alkali metal carbonate salt, when taken separately, has a 90% dissolution time of less than 15 seconds; and the water-soluble organic acid has a d 50 particle size which is in the range of from 250 to 1500 microns.
14. A process as claimed in claim 13 , wherein the base powder is prepared by a non-spray drying granulation process.