High water permeability proton exchange membrane
View Patent ↗A high water permeability proton exchange membrane ( 12 ) is disclosed for use in an electrochemical cell, such as a fuel cell ( 10 ) or an electrolysis cell. The membrane ( 12 ) includes: a. between about 20 volume percent (“vol. %”) and about 40 vol. % of a structural insulating phase (40); between about 50 vol. % and about 70 vol. % of a hydrated nanoporous ionomer phase ( 42 ); and, about 10 vol. % of a microporous water-filled phase ( 44 ). The structural insulating material ( 40 ) defines an overall membrane volume, and the ionomer phase ( 42 ) fills all but 10% of the overall volume so that the microporous water-filled phase ( 44 ) is defined within the ionomer phase ( 42 ) and consists of open pores having a diameter of between 0.3 microns and 1.0 microns. Water transport is enhanced between opposed catalytic surfaces ( 14 ), ( 16 ) of the membrane ( 12 ).
1. A high water permeability proton exchange membrane ( 12 ) for use in an electrochemical cell, the membrane ( 12 ) comprising:
a. between about 20 volume percent and about 40 volume percent of a structural insulating phase ( 40 ) selected from the group consisting of a particulate material, a whisker material, or a fibrous material, which materials are electronically non-conductive;
b. between about 50 volume percent and about 70 volume percent of a hydrated nanoporous ionomer phase ( 42 ) consisting of a cation exchange resin; and,
c. about 10 volume percent of a microporous water-filled phase ( 44 ) consisting of open pores having a diameter of between 0.3 and 1.0 microns defined within the hydrated nanoporous ionomer phase ( 42 ) so that water may flow through the open pores between a first catalytic surface ( 14 ) and an opposed second catalytic surfaces ( 16 ) of the high water permeability proton exchange membrane ( 12 ).
2. The high water permeability proton exchange membrane ( 12 ) of claim 1 , wherein the membrane ( 12 ) has a thickness of between 10 and 25 microns, wherein the thickness is a shortest distance between the opposed catalytic surfaces ( 14 ), ( 16 ) of the membrane ( 12 ).
3. The high water permeability proton exchange membrane ( 12 ) of claim 1 , wherein the hydrated nanoporous ionomer phase ( 42 ) includes open pores having a diameter of about 0.004 microns defined within the ionomer and a hydrated porosity of about 40 percent.
4. The high water permeability proton exchange membrane ( 12 ) of claim 1 , wherein the membrane ( 12 ) provides a bubble pressure of 35 kPa or greater.
5. The high water permeability proton exchange membrane ( 12 ) of claim 1 , wherein the structural insulating phase ( 40 ) further comprises materials selected from the group consisting of silicon carbide, alumina, titania, zirconia, silica, and glass, or mixtures thereof.
6. The high water permeability proton exchange membrane ( 12 ) of claim 1 , wherein the structural insulating phase ( 40 ) comprises whiskers of silicon carbide having diameters of about 1 micron, and lengths of about 10 microns, and the hydrated nanoporous ionomer phase ( 42 ) comprises a perflourosulfonic acid ionomer.
7. A method of making a high water permeability proton exchange membrane ( 12 ), comprising the steps of:
a. positioning a structural insulating material ( 40 ) to define an overall membrane volume, wherein the structural insulating material is selected from the group consisting of a particulate material, a whisker material, or a fibrous material, which materials are electronically non-conductive; and,
b. filling all but 10 percent of the overall membrane volume with a hydrated nanoporous ionomer material ( 42 ), wherein the hydrated nanoporous ionomer material ( 42 ) is a cation exchange resin, so that a microporous water-filled phase ( 44 ) consisting of open pores having a diameter of between 0.3 and 1.0 microns is defined within the hydrated nanoporous ionomer material ( 42 ).
8. The method of making a high water permeability proton exchange membrane ( 12 ) of claim 7 , comprising the further step of positioning the structural insulating material ( 40 ) to define an overall volume of the membrane ( 12 ) having a thickness of between 10 microns and 25 microns, wherein the thickness of the overall volume is a shortest distance between a first catalytic surface ( 14 ) and an opposed second catalytic surface ( 16 ) of the overall volume of the membrane ( 12 ).
9. The method of making a high water permeability proton exchange membrane ( 12 ) of claim 8 , comprising the further step of filling all but 10 percent of the overall membrane volume with a hydrated nanoporous ionomer material ( 42 ) so that the membrane ( 12 ) provides a bubble pressure of 35 kPa or greater.