Sizing composition for glass yarns, method using said composition and resulting products
View Patent ↗A sizing composition which is useful for coating glass strands contains a solution having a solvent content of less than 5% by weight. The solution contains at least 45% by weight of components capable of curing. At least 40% of the components capable of curing have a molecular mass of between 750 and 5000. The components capable of curing contain at least one mixture containing a) one or more components having at least one acrylic reactive functional group and/or methacrylic reactive functional group, and b) one or more components having at least one primary amine reactive functional group and/or secondary amine reactive functional group.
1. A glass strand coated with a sizing composition, comprising:
a solution having a solvent content of less than 5% by weight;
said solution comprising at least 45% by weight of components capable of curing,
wherein at least 40% of said components capable of curing have a molecular mass of between 750 and 5000; and
wherein said components capable of curing comprise
at least one mixture comprising
one or more components having at least one acrylic reactive functional group and/or methacrylic reactive functional group, and
one or more components having at least one primary amine reactive functional group and/or secondary amine reactive functional group.
2. The glass strand as claimed in claim 1 , wherein at least 40% of the components capable of curing have at least two reactive functional groups selected from the group consisting of acrylic functional groups, methacrylic functional groups, primary amine functional groups, secondary amine functional groups and mixtures thereof.
3. The glass strand as claimed in claim 1 , wherein more than 50% of the components capable of curing have at least one reactive functional group selected form the group consisting of acrylic functional groups, methacrylic functional groups, primary amine functional groups and mixtures thereof.
4. The glass strand as claimed in claim 1 , wherein the mixture comprises at least one component having at least two acrylic reactive functional groups and/or methacrylic reactive functional groups and having a molecular mass of between 750 and 5000.
5. The glass strand as claimed in claim 1 , wherein a content of component(s) having at least one acrylic functional group and/or at least one methacrylic reactive functional group is between 15 and 60% by weight of the sizing composition.
6. The glass strand as claimed in claim 1 , comprising at least 50% by weight of the components capable of curing having at least two reactive functional groups of acrylic functional groups, methacrylic functional groups and mixtures thereof.
7. The glass strand as claimed in claim 1 , wherein a proportion of component(s) having at least one primary amine reactive functional group and/or secondary amine reactive functional group is between 4 and 40% by weight of the sizing composition.
8. The glass strand as claimed in claim 1 , wherein a ratio r of the number of (meth)acrylic reactive sites to the number of primary reactive sites and/or secondary amine reactive sites is between 0.15 and 3.
9. The glass strand as claimed in claim 1 , wherein at least 20% by weight of the components capable of curing have
i) at least two reactive functional groups selected from the group consisting of acrylic functional groups, and methacrylic functional groups and mixtures thereof, and have
ii) a molecular mass of between 750 and 5000.
10. The glass strand as claimed in claim 1 , wherein the sizing composition comprises up to 8% by weight of at least one catalyst.
11. The glass strand as claimed in claim 1 , wherein the composition comprises at least one coupling agent in a proportion of between 0 and 30% by weight.
12. The glass strand as claimed in claim 1 , wherein the composition includes comprises at least one textile processing aid in a proportion of between 0 and 35%.
13. The glass strand as claimed in claim 1 , wherein the composition comprises up to 8% by weight of at least one film-forming agent.
14. A sizing composition for glass strand, comprising:
a solution having a solvent content of less than 5% by weight;
said solution comprising at least 45% by weight of components capable of curing,
wherein at least 40% of said components capable of curing have a molecular mass of between 750 and 5000; and
wherein said components capable of curing comprise
at least one mixture comprising
one or more components having at least one acrylic reactive functional group and/or methacrylic reactive functional group, and
one or more components having at least one primary amine reactive functional group and/or secondary amine reactive functional group.
15. The composition as claimed in claim 14 , wherein at least 40% of the components capable of curing have at least two reactive functional groups selected from the group consisting of acrylic functional groups, methacrylic functional groups, primary amine functional groups, secondary amine functional groups and mixtures thereof.
16. A process for producing sized glass strands, comprising
drawing a multiplicity of streams of molten glass, flowing out from a multiplicity of orifices located at the base of one or more bushings, in the form of one or more sheets of continuous filaments;
assembling the filaments into one or more strands which are collected on a moving support;
depositing, on the surface of the filaments while they are being drawn and before the filaments have been assembled into strands, at least some of the sizing composition as claimed in claim 14 , the strand or strands being coated with the sizing composition at the latest during collection of the strand or strands.
17. The process as claimed in claim 16 , wherein the composition is deposited in one step on the surface of the filaments while they are being drawn and before the filaments are assembled into strands.
18. The process as claimed in claim 16 , wherein a first stable composition having a viscosity of between 20 and 500 cP is deposited on the surface of the filaments and at least one second stable composition, fed separately from the first, having a viscosity of between 20 and 500 cP is deposited on the surface of the filaments or of the strand or strands at the earliest while the first composition is being deposited and at the latest while the strand or strands are being collected, the difference in viscosity between the compositions deposited being less then 250 cP, the mixture of the compositions deposited forming a sizing composition being curable at room temperature and comprising
a solution having a solvent content of less than 5% by weight;
is said solution comprising at least 45% by weight of components capable of curing,
wherein at least 40% of said components capable of curing have a molecular mass of between 750 and 5000; and
wherein said components capable of curing comprise
at least one mixture comprising
one or more components having at least one acrylic reactive functional group and/or methacrylic reactive functional group, and
one or more components having at least one primary amine reactive functional group and/or secondary amine reactive functional group.
19. The process as claimed in claim 18 , wherein the first composition comprises at least one component having at least one acrylic reactive functional group and/or methacrylic reactive functional group and in that the second composition comprises at least one component having at least one primary amine reactive functional group and/or secondary amine reactive functional group.
20. A composite, comprising:
at least one organic material and/or inorganic material and sized glass strands,
wherein all or some of the glass strands are sized glass strands as claimed in claim 1 .