Zinc diacrylate predispersed in high-cis polybutadiene
View Patent ↗The present invention provides a method and product that provides a dust-free homogeneous dispersion of zinc diacrylate in polybutadiene for use in golf balls. More specifically, the invention relates to a dispersion of zinc diacrylate in a special high-cis grade of polybutadiene commonly used by golf ball manufacturers. We have found that such a dispersion of ZDA can be made by using specific processing promoters, which not only allow the manufacture of the predispersion, but have a beneficial effect on the final properties of the golf ball. The processing promoters of the present invention enable more uniform dispersion of the ZDA into the polymer matrix, eliminate sticking to the mixer rotors, provide improved extrusion and pelletizing rates, as well as function as a separant to greatly minimize, if not totally eliminate, massing of the pelletized product. This dust-free pelletized product, which can optionally be supplied in slab form, is then sold to the golf ball manufacturer for direct addition to his mixer. The presence of the processing promoter also assists in the mixing of the product into the final golf ball compound as well as improve down-stream processing, such as extruding.
1. A rubber dispersion composition comprising:
a) from about 12 to 50 parts by weight of a polybutadiene based on the total weight of said dispersion;
b) from about 50 to 85 parts by weight of zinc diacrylate based on the total weight of said dispersion; and
c) from about 0.5 to 5 parts by weight of a processing promoter selected from the group consisting of low molecular weight polyethylene, fatty acids, zinc salts of fatty acids and mixtures thereof.
2. A composition according to claim 1 , wherein said polybutadiene is a high- cis-polybutadiene.
3. A composition according to claim 1 , wherein said dispersion comprises from 12 to 22 parts by weight of said polybutadiene.
4. A composition according to claim 3 , wherein said dispersion comprises 15 to 19 parts by weight of said polybutadiene.
5. A composition according to claim 1 , wherein said dispersion comprises 70 to 85 parts by weight of zinc diacrylate based on the total weight of said dispersion.
6. A composition according to claim 5 , wherein said dispersion comprises 75 to 85 parts by weight of zinc diacrylate based on the total weight of said dispersion.
7. A composition according to claim 1 , wherein said processing promoter is a low molecular weight polyethylene having a molecular weight from 750 to 2500.
8. A composition according to claim 1 , wherein said processing promoter is a blend of polymer olefin and polyethylene wax having a softening point around 112° C. and is present at 0.5 to 5.0 percent by weight of the total product.
9. A composition according to claim 8 , wherein said processing promoter is present at 2.5 to 3.5 percent by weight of the total product.
10. A composition according to claim 1 , wherein said processing promoter is a low molecular weight polyethylene with a softening point around 85° C.
11. A composition according to claim 10 , wherein said processing promoter is a low molecular weight polyethylene having a density of 1.33 g/cc and an ML(1+4)100° C. of 37.
12. A composition according to claim 1 , wherein said processing promoter comprises zinc salts of mainly unsaturated fatty acids.
13. A composition according to claim 1 , wherein said processing promoter is a blend of zinc salts of mainly saturated fatty acids having a density of 1.08 g/cc and a softening point about 100° C.
14. A composition according to claim 1 , wherein said fatty acid is oleic acid.
15. A composition according to claim 1 , wherein said zinc salts of fatty acids is a zinc salt of oleic acid.
16. A process for making a rubber dispersion comprising the steps of:
a) mixing i) from about 12 to 50 parts by weight of a polybutadiene based on the total weight of said dispersion; ii) from about 50 to 85 parts by weight of zinc diacrylate based on the total weight of said dispersion; and iii) from about 0.5 to 5 parts by weight of a processing promoter selected from the group consisting of low molecular weight polyethylene, fatty acids, zinc salts of fatty acids and mixtures thereof to form a homogeneous mixture;
b) extruding said homogeneous mixture; and then
c) pelletizing or slabbing said extruded homogeneous mixture.
17. A process according to claim 16 , wherein said polybutadiene is a high- cis-polybutadiene.
18. A process according to claim 16 , wherein said dispersion comprises from 12 to 22 parts by weight of said polybutadiene.
19. A process according to claim 18 , wherein said dispersion comprises 15 to 19 parts by weight of said polybutadiene.
20. A process according to claim 16 , wherein said dispersion comprises 70 to 85 parts by weight of zinc diacrylate based on the total weight of said dispersion.
21. A process according to claim 20 , wherein said dispersion comprises 75 to 85 parts by weight of zinc diacrylate based on the total weight of said dispersion.
22. A process according to claim 16 , wherein said processing promoter is a low molecular weight having a molecular weight from 750 to 2500 polyethylene.