Lithographic printing form and method of preparation and use thereof
View Patent ↗A positive working printing form precursor comprises a thermally imagable composition which includes a hydroxyl group-containing polymer, for example a novolak resin. The composition has a weight of less than 1.1 gm −2 . It has been found that using a low weight of the composition on the precursor improves the properties of the precursor, in particular by rendering the sensitivity of the precursor to imaging radiation less variable over time.
1. A method of producing a printing form from a printing form precursor, the method comprising:
(a) providing a positive working printing form precursor having a thermally imageable coating on a substrate, wherein the precursor is prepared by:
(i) applying to the substrate a composition in a solvent, wherein the composition includes a phenolic resin, and
(ii) subsequently removing solvent to leave an imageable coating on the substrate, such that the weight of the imageable coating on the substrate is less than 1.1 gm −2 ;
(b) following a period of at least 6 days after the precursor is prepared, exposing selected areas of the coating to heat, thereby rendering the exposed areas preferentially soluble in a developer solution, with the proviso that the precursor is not subjected to heat treatment after being prepared and prior to exposing; and
(c) developing the precursor in the developer solution to remove the exposed areas, wherein the developer solubility of the unexposed areas at the time of exposing is not significantly changed, as compared to the developer solubility of unexposed areas for an identically prepared precursor exposed after a period of only one day following preparation.
2. The method of claim 1 , wherein the substrate has a surface roughness value R a in the range 0.3 to 0.6 μm.
3. The method of claim 1 , wherein the phenolic resin comprises a novolak resin.
4. The method of claim 1 , wherein the phenolic resin comprises a polyhydroxystyrene resin.
5. The method of claim 1 , wherein the coating comprises a radiation absorbing compound, and the step of exposing selected areas of the coating is done by a method selected from the group consisting of (i) contacting the precursor with a heated body; (ii) exposing the coating to charged particle radiation, wherein the radiation is converted to heat by the radiation absorbing compound; and (iii) exposing the coating to electromagnetic radiation, wherein the radiation is converted to heat by the radiation absorbing compound.
6. The method of claim 1 , wherein the coating is imageable only by exposure to electromagnetic radiation entirely or predominantly in the range 600 to 1400 nm, and wherein the step of exposing includes exposing the selected areas of the coating to electromagnetic radiation in the range 600 to 1400 nm.
7. The method of claim 1 , wherein the coating includes a modifying means for modifying the dissolution rate of the coating in a developer compared to when the modifying means is not present in the coating.
8. The method of claim 1 , wherein the weight of the imageable coating on the substrate is no more than 1.0 gm −2 .
9. The method of claim 1 , wherein the weight of the imageable coating on the substrate is 1.0 gm −2 .
10. The method of claim 1 , wherein the imageable coating comprises:
at least 70% by weight of phenolic resins;
at least 1% by weight of a reversible insolubilizer compound;
at least 0.5% by weight of an infrared absorber compound; and
1% to 10% by weight of a siloxane.
11. The method of claim 10 , wherein the imageable coating comprises 2% to 15% by weight of the reversible insolubilizer compound.
12. The method of claim 10 , wherein the imageable coating comprises 0.5% to 8% by weight of a dye as the infrared absorber compound.
13. The method of claim 10 , wherein the imageable coating comprises 5% to 15% by weight of a pigment as the infrared absorber compound.
14. The method of claim 1 , wherein the precursor is not subjected to a heat treatment in the range 40 to 90° C. after being prepared and prior to exposing.
15. The method of claim 1 , wherein the step of exposing selected areas of the coating to heat follows a period of at least 28 days after the precursor is prepared.
16. The method of claim 1 , wherein the step of exposing selected areas of the coating to heat follows a period of at least 63 days after the precursor is prepared.
17. The method of claim 1 , wherein the step of exposing selected areas of the coating to heat follows a period of at least 182 days after the precursor is prepared.
18. A printing form produced by the method of claim 1 .