Method for determining the concentration of hydrogen peroxide in a process stream and a spectrophotometric system for the same

1. A method of determining the hydrogen peroxide concentration of a chemical process stream containing at least one interfering component comprising:

adding to said chemical process stream containing hydrogen peroxide, a molybdate solution, wherein said solution contains an excess of molybdate ions,

measuring by UV spectroscopy, the absorption at wavelength at or between about 300 and about 450 nm (Absorption A) and at or between about 292 to about 302 nm (Absorption B); and

determining the concentration of hydrogen peroxide by comparing the two absorption measurements.

2. The method according to claim 1 , wherein the molybdate solution has a concentration of less than about 3.2 mmol/L.

3. The method according to claim 1 , wherein the absorption (Absorption A) is measured between about 330 and 375 nm.

4. The method according to claim 1 , wherein the absorption (Absorption 8 ) is measured at between about 294 and 300 nm.

5. The method according to claim 1 , wherein said chemical process stream is an aqueous stream.

6. The method according to claim 4 , wherein said chemical process stream is at least one of 4 pulp or paper processing stream, a wastewater stream, or a textile bleaching stream.

7. The method according to claim 1 , wherein the chemical process stream is a pulp stream and the at least one interfering component is chosen from dissolved lignin.

8. The method according to claim 1 , wherein said chemical process stream is a pulp or paper process stream and wherein the stream first is treated in an acidic medium to precipitated dissolved lignin.

9. The method according to claim 1 , wherein the molybdate solution is produced comprising an ammonium salt of molybdenum.

10. The method according to claim 1 , wherein the two absorption measurements are compared by the following equation:

C

=

k

1

V

⁢

sample

⁡

[

k

3

⁢

A

X

-

k

2

⁡

(

k

3

⁢

A

Y

-

A

Y

o

)

-

A

X

o

]

wherein C is the concentration of hydrogen peroxide (in g/L) V sample is the sample volume in (mL), A x and A y represent the absorption of peroxymolybdate complex and the isosbestic point, respectively, wherein the variables A 0 x and A 0 y represent the absorption measurements of the molybdate solution before the sample was added at X and the isosbestic point, k 1 , is a calibration constant, k 2 is a correction factor, and k 3 is a dilution factor.

11. The method according to claim 1 , wherein the concentration of hydrogen peroxide in said process stream is changed in response to said determination.

12. An on-line system for measuring hydrogen peroxide concentration of a chemical process stream containing at least one interfering component comprising:

means for removing a sample from said chemical process stream;

means for determining the UV adsorption of said sample at least two wavelengths;

means for determining the concentration of hydrogen peroxide in said chemical process stream; and

a means for introducing a molybdate solution to said sample.

13. The system according to claim 12 , wherein said means for removing a sample is a pump.

14. The system according to claim 12 , further comprising cooling means for cooling said sample prior to measuring the UV adsorption.

15. The system according to claim 12 , wherein said means for determining the UV adsorption is a UV spectrometer.

16. The system according to claim 15 , wherein said means for determining the UV adsorption further comprises a light source.

17. The system according to claim 16 , wherein the sample is passed through a flow cell between said UV spectrometer and said light source.

18. The system according to claim 12 , wherein said means for determining the concentration of hydrogen peroxide is a computer.

19. An on-line system for measuring hydrogen peroxide concentration of a chemical process stream containing at least one interfering component comprising:

means for removing a sample from said chemical process stream;

means for determining the UV adsorption of said sample at least two wavelengths;

means for determining the concentration of hydrogen peroxide in said chemical process stream; and

a means for introducing a molybdate solution to said sample;

wherein said means for introducing a molybdate solution to said sample is an injection valve.