Age-hardening copper alloy as material for producing casting molds
View Patent ↗An age-hardening copper alloy made of—as expressed in each case in weight %—0.4% to a maximum of 2% cobalt which is partially replaceable by nickel, 0.1% through 0.5% beryllium, optionally 0.03% through 0.5% zirconium, 0.005% through 0.1% magnesium and possibly a maximum of 0.15% of at least one element from the group including niobium, manganese, tantalum, vanadium, titanium, chromium, cerium and hafnium. The remainder is copper inclusive of production-conditioned impurities and usual processing additives. This copper alloy is used as the material for producing casting molds, in particular for the sleeves of continuous casting rolls as components of a two-roll casting installation.
1. An age-hardening copper alloy for producing casting molds, comprising in weight %: 0.4% through 2% cobalt, which may be partially substituted by nickel, 0.1% through 0.5% beryllium, manganese up to 0.15%, at least one element selected from the group consisting of niobium, tantalum, and vanadium, and a remainder of copper, wherein the alloy in the age-hardened state has an average grain size of 90 μm to 1,500 μm as per ASTM E 122, and an electrical conductivity of between 30 and 36 Sm/mm 2 .
2. The copper alloy according to claim 1 , which includes 0.03% through 0.5% zirconium and 0.005% through 0.1% magnesium.
3. The copper alloy according to claim 2 , which contains 0.03% to 0.35% zirconium and 0.005% to 0.05% magnesium.
4. The copper alloy according to claim 3 , having a ratio of cobalt to beryllium of between 2 and 15.
5. The copper alloy according to claim 2 , which contains less than 1.0% cobalt, 0.15% to 0.3% beryllium and 0.15% to 0.3% zirconium.
6. The copper alloy according to claim 5 , having a ratio of cobalt to beryllium of between 2 and 15.
7. The copper alloy according to claim 2 , having a ratio of cobalt to beryllium of between 2 and 15.
8. The copper alloy according to claim 7 , having a ratio of cobalt to beryllium of between 2.2 and 5.
9. The copper alloy according to claim 2 , further comprising up to 0.6% nickel in addition to cobalt.
10. The copper alloy according to claim 2 , which contains a maximum of 0.15% of at least one element from the group including niobium, manganese, tantalum, vanadium, titanium, chromium, cerium and hafnium.
11. The copper alloy according to claim 1 , having a ratio of cobalt to beryllium of between 2 and 15.
12. The copper alloy according to claim 11 , having a ratio of cobalt to beryllium of between 2.2 and 5.
13. The copper alloy according to claim 11 , which contains a maximum of 0.15% of at least one element from the group including niobium, manganese, tantalum, vanadium, titanium, chromium, cerium and hafnium.
14. The copper alloy according to claim 1 , further comprising up to 0.6% nickel in addition to cobalt.
15. A casting mold produced from the copper alloy according to claim 1 by hot working, solution treatment at 850° C. to 980° C., cold working up to 30%, and age-hardening at 400° C. to 550° C. within a time period of 2 to 32 h.
16. The casting mold according to claim 15 , which in the age-hardened state has an average grain size of 90 μm to 500 μm, as per ASTM E 112, a 0.2% yield strength of at least 450 MPa and an elongation at break of at least 12%.
17. A sleeve of a continuous casting roll of a two-roll casting installation which is submitted to a changing temperature stress under high roll pressures during close to final dimension casting of strips made of non-ferrous metals, made of the copper alloy according to claim 1 .