Bonding compositions for chlorinated polymers and methods of using the same
A composition, and a method of using the composition, are described which composition comprising: (A) at least one chlorinated polyvinyl chloride or mixture of at least one polyvinyl-chloride and at least one chlorinated polyvinyl-chloride thereof; (B) at least one volatile organic liquid which is a solvent for the polymer of (A); and (C) a stabilizer comprising (i) an organophosphite compound, at least one hindered phenol, at least one of an organotin compound or mixtures thereof, and (ii) at least one metal-containing carbonate salt. The composition and methods of the present invention act to retard the loss of chlorine from the resins of the adhesive compositions and to absorb or otherwise inactive any lost chlorine. The compositions of the invention are useful in a variety of applications including use as adhesives, cements (including solvent cements) glues or pastes for holding together materials by surface attachment, and as sealants which are load-bearing elastic jointing and insulating materials.
1. A composition comprising:
(A) at least one chlorinated polyvinyl chloride;
(B) at least one volatile organic liquid which is a solvent for the chlorinated polyvinyl chloride; and
(C) a stabilizer comprising (i) at least one organophosphite compound, at and (ii) at least one metal-containing carbonate salt.
2. The composition of claim 1 wherein the solvent (B) comprises a lower alcohol, a ketone, an aldehyde, an ester, an ether, a halogenated solvent, tetrahydrofuran, N-Methyl pyrollidone, dimethyl-formamide or mixture of two or more thereof.
3. The composition of claim 1 , wherein the organophosphite compound is an alkyl diaryl phosphite, a dialkyl aryl phosphite, a trialkyl phosphite, an triayl phosphite, a tris(alkylaryl)phosphine, tris(arylalkyl) phosphite, a dialkyl pentaerythritol diphosphite, a diaryl pentaerythritol diphosphite, an alkyl aryl pentaerythritol diphosphite, a dialkyl phosphite, a diaryl phosphite, analkyl phosphite an aryl phosphite, their metal salts or mixtures of two or more of the phosphites or their metal salts.
4. The composition of claim 1 wherein the carbonate salt is a sodium, magnesium or aluminum carbonate salt.
5. The composition of claim 1 wherein the salt comprises an aluminum containing salt.
6. A composition comprising (A) at least one chlorinated polyvinyl chloride or a mixture of at least one chlorinated polyvinyl chloride and at least one polyvinyl chloride, (B) at least one volatile organic liquid which is a solvent for chlorinated polyvinyl chloride, and (C) a stabilizer comprising (i) at least one organophosphite compound, and (ii) at least one metal-containing carbonate salt.
7. The composition of claim 6 wherein the organophosphite compound is an alkyl diaryl phosphite, a dialkyl aryl phosphite, a trialkyl phosphite, a triaryl phosphite, a tris(alklylaryl)phosphite, tris(arylalkyl) phosphite, a dialkyl pentaerythritol diphosphite, a diaryl pentaerythritol diphosphite, an alkyl aryl pentaerythritol diphosphite, a dialkyl phosphite, a diaryl phosphite, an alkyl phosphite an aryl phosphite, their metal salts or mixtures of two or more of the phosphites or their metal salts.
8. The composition of claim 6 wherein the solvent (B) comprises a lower alcohol, a ketone, an aldehyde, an ester, an ether, a halogenated solvent, tetrahydrofuran, N-methyl pyrollidone, dimethyl-formamide or mixtures of two or more thereof.
9. The composition of claim 6 wherein the carbonate salt is a sodium, magnesium or aluminum carbonate salt.
10. The composition of claim 6 wherein the salt comprises an aluminum containing salt.