Method for producing low-loss tunable ceramic composites with improved breakdown strengths
View Patent ↗The production of low-loss, tunable composite ceramic materials with improved breakdown strengths is disclosed. The composite materials comprise ferroelectric perovskites such as barium strontium titanate or other ferroelectric perovskites combined with other phases such as low-loss silicate materials and/or other low-loss oxides. The composite materials are produced in sheet or tape form by methods such as tape casting. The composite tapes exhibit favorable tunability, low loss and tailorable dielectric properties, and can be used in various microwave devices.
1. A method of making a layer of low-loss, tunable ceramic composite material with improved breakdown strength, the method comprising:
tape casting a slurry comprising a mixture of at least one electronically tunable ceramic material and at least one additional ceramic material to form a tape cast layer; and
sintering the tape cast layer, wherein the sintered tape cast layer has a breakdown strength of greater than about 8 V/micron.
2. The method of claim 1 , wherein the sintered tape cast layer has a thickness of from about 0.005 to about 2 mm.
3. The method of claim 1 , wherein the sintered tape cast layer has a thickness of from about 5 to about 50 microns.
4. The method of claim 1 , wherein the sintered tape cast layer has a thickness of greater than about 50 microns.
5. The method of claim 1 , wherein the sintered tape cast layer has an average grain size of less than about 10 microns.
6. The method of claim 1 , wherein the sintered tape cast layer has an average grain size of from about 2 to about 5 microns.
7. The method of claim 1 , wherein the sintered tape cast layer has a breakdown strength of greater than about 12 V/micron.
8. The method of claim 1 , further comprising tape casting another layer of the slurry over at least a portion of the tape cast layer to form a laminated structure.
9. The method of claim 8 , wherein the sintering step is performed after the laminated structure is formed.
10. The method of claim 1 , wherein the at least one electronically tunable ceramic material comprises from about 20 to about 99 weight percent of the tape cast layer and comprises barium strontium titanate, barium titanate, strontium titanate, barium calcium titanate, barium calcium zirconium titanate, lead titanate, lead zirconium titanate, lead lanthanum zirconium titanate, lead niobate, lead tantalate, potassium strontium niobate, sodium barium niobate/potassium phosphate, potassium niobate, lithium niobate, lithium tantalite, lanthanum tantalate, barium calcium zirconium titanate and/or sodium nitrate.
11. The method of claim 1 , wherein the at least one electronically tunable ceramic material comprises barium strontium titanate.
12. The method of claim 11 , wherein the barium strontium titanate is of the formula BaxSr1−xTiO3, where x is from about 0.15 to about 0.6.
13. A method of making a layer of low-loss, tunable ceramic composite material with improved breakdown strength, the method comprising:
tape casting a slurry comprising a mixture of at least one electronically tunable ceramic material and at least one additional ceramic material to form a tape cast layer; and
sintering the tape cast layer, wherein the at least one additional ceramic material comprises from about 3 to about 65 weight percent of the tape cast layer and comprises a silicate of at least one metal selected from Be, Mg, Ca, Sr, Ba, Ra, Li, Na, K, Rb, Cs, Al, Zr, Zn, Fr, B, Fe, Mn, Cu, Ce, Cr, La, Y, Ti, Ta, Nb, Mo, W, Ni, Pd, Pb and Bi.
14. The method of claim 13 , wherein the metal silicate comprises Mg2SiO4, CaSiO3, BaSiO3 and/or SrSiO3.
15. The method of claim 1 , wherein the at least one additional ceramic material comprises from about 1 to about 80 weight percent of the tape cast layer and comprises oxides of at least two metals selected from Be, Mg, Ca, Sr, Ba, Ra, Li, Na, K, Rb, Cs, Al, Zr, Zn, Fr, B, Fe, Mn, Cu, Cr, Ti, Ta, Nb, Mo, W, Ni, Pd, Pb, Bi, Si, Sn, Hf and rare earths.
16. The method of claim 15 , wherein the metal oxides comprise at least two metals selected from Mg, Si, Ca, Zr, Ti and Al.
17. The method of claim 15 , wherein the metal oxides are selected from Mg2SiO4, MgO, CaTiO3, MgZrSrTiO6, MgTiO3, MgAl2O4, WO3, SnTiO4, ZrTiO4, CaSiO3, CaSnO3, CaWO4, CaZrO3, MgTa2O6, MgZrO3, MnO2, PbO, Bi2O3 and La2O3.
18. The method of claim 1 , wherein the tape cast layer further comprises at least one low loss glass additive.
19. The method of claim 16 , wherein the low loss glass additive comprises from about 0.1 to about 60 weight percent of the tape cast layer.
20. The method of claim 1 , wherein the sintering is performed at a temperature of less than about 1,000° C.