Tailoring material composition for optimization of application-specific switchable holograms
View Patent ↗The present invention offers control over—and the ability to optimize—the performance parameters of switchable holograms. The present invention offers the ability to tailor the properties of a hologram to a desired application and thus make application-specific holograms. The invention relates to polymer-dispersed liquid crystal materials subject to control and optimization of the performance parameters of switchable holograms. Such variability allows tailoring the properties to application-specific devices. Specifically, the present invention provides an improved polymer-dispersed liquid crystal system that allows variation of: 1) haze, 2) switching voltage, 3) electrical power dissipation, 4) switching stability (voltage creep), 5) switching contrast ratio (range), 6) dynamic stability, and 7) the operating temperature range.
1. A polymer-dispersed liquid crystal material for forming a polymer-dispersed liquid crystal optical element comprising:
at least one acrylic acid monomer;
at least one type of liquid crystal material;
a photoinitiator dye;
a co-initiator; and
at surfactant.
2. The polymer-dispersed liquid crystal material for forming a polymer-dispersed liquid crystal optical element according to claim 1 , further comprising:
a polymer matrix formed upon polymerization of the polymer-dispersed liquid crystal material containing the at least one acrylic acid monomer in an amount sufficient to increase the conductivity of the polymer matrix and cause a reduction in the switching voltage.
3. A polymer-dispersed liquid crystal material for forming a polymer-dispersed liquid crystal optical element comprising:
a first polymerizable monomer and a second polymerizable monomer;
at least one type of liquid crystal material;
a photoinitiator dye;
a co-initiator; and
a reactive di lent;
wherein the first polymerizable monomer and the second polymerizable monomer are polymerized according to different chemical processes.
4. The polymer-dispersed liquid crystal material according to claim 3 , wherein the first polymerizable monomer is polymerized using a first polymerizing means and the second polymerizable monomer is polymerized using a second polymerizing means.
5. The polymer-dispersed liquid crystal material according to claim 4 , wherein the first and second polymerizing means are selected from the group consisting of: visible radiation, ultraviolet radiation, heat, electron beam, and reactants.
6. The polymer-dispersed liquid crystal material according to claim 4 , wherein at least one of the first and second polymerizing means is ultraviolet radiation.
7. The polymer-dispersed liquid crystal material according to claim 3 , wherein the first polymerizable monomer is polymerized at a first time and the second polymerizable monomer is polymerized at a second time.
8. The polymer-dispersed liquid crystal material according to claim 3 , wherein the first polymerizable monomer is an acrylate and the second polymerizable monomer is a thiol-ene.
9. The polymer-dispersed liquid crystal material according to claim 3 , wherein the first polymerizable monomer comprises approximately 30–50% of the polymer-dispersed liquid crystal material and the second polymerizable monomer comprises approximately 5–20% of the polymer-dispersed liquid crystal material.
10. The polymer-dispersed liquid crystal material according to claim 3 , wherein the first polymerizable monomer is polymerized by a free-radical chemical reaction anti the second polymerizable monomer is polymerized by a step-growth chemical reaction.
11. A switchable optical element having an improved contrast ratio comprising:
a polymer matrix having a first index of refraction;
a liquid crystal having a second index of refraction; and
an alkyl chain additive, wherein the alkyl chain additive modifies the second index of refraction so that upon application of a voltage to the switchable optical element the first index of refraction is matched with the second index of refraction and produces minimum diffraction efficiency within the switchable optical element.
12. A switchable optical element according to claim 11 , wherein the amount of alkyl chain additive within the switchable optical element is determined based on the following equation:
f
a
:
LC
=
n
min
-
n
p
n
min
-
n
a
,
wherein, n min is the minimum index of refraction of the liquid crystal, n p is the index of refraction of the polymer matrix, n a is the index of refraction of the allyl chain additive, and mixed with the LC will lower the effective LC index and f a:LC is the relative-volume-fraction of alkyl chain additive to liquid crystal.
13. The switchable optical element according to claim 11 , wherein the alkyl chain additive is selected from the group consisting of: nonane, decane, dodecane, undecane, tridecane, tetradecane, pentadecane, hexadecane, and heptadecane.
14. A method for increasing the operating temperature of a switchable optical element comprising:
adding a diluent to a polymer-dispersed liquid crystal material;
exposing the polymer-dispersed liquid crystal material to white light for a predetermined amount of time; and
exposing the polymer-dispersed liquid crystal material to a heat cycle.
15. The method according to claim 14 , wherein the diluent is selected from the group consisting of decanoic acid and dodecanoic acid.
16. The method according to claim 14 , wherein the heat cycle comprises the following temperatures in order 25 degrees Celsius, 75 degrees Celsius, and 25 degrees Celsius.
17. A polymer-dispersed liquid crystal material for forming a switchable polymer-dispersed liquid crystal optical element comprising:
at least one polymerizable monomer,
at least one type of liquid crystal material;
a photoinitiator dye;
a reactive diluent; and
an additive monomer acrylate with branched alkyl chains, wherein the additive monomer acrylate reduces the switching voltage of the polymer-dispersed liquid crystal optical element.
18. The polymer-dispersed liquid crystal material according to claim 17 , wherein the additive monomer acrylate is selected from the group consisting of t-butyl acrylate, t-butyl methacrylate, isopropyl acrylate, and isopropyl methacrylate.
19. A polymer-dispersed liquid crystal material for forming a polymer-dispersed liquid crystal optical element comprising:
at least one acrylic acid monomer;
at least one type of liquid crystal material;
a photoinitiator dye;
a co-initiator;
a surfactant;
wherein a polymer matrix is formed upon polymerization of the polymer-dispersed liquid crystal material containing the at least one acrylic acid monomer in an amount sufficient it to increase the conductivity of the polymer matrix and cause a reduction in the switching voltage; and
further wherein the at least one acrylic acid monomer is approximately 1.0–1.5 percent of the weight of the polymer-dispersed liquid crystal material.
20. A polymer-dispersed liquid crystal material for forming a polymer-dispersed liquid crystal optical element comprising:
at least one acrylic acid monomer;
at least one type of liquid crystal material;
a photoinitiator dye;
at co-initiator,
a surfactant;
wherein a polymer matrix is formed upon polymerization of the polymer-dispersed liquid crystal material containing the at least one acrylic acid monomer in an amount sufficient to increase the conductivity of the polymer matrix and cause a reduction in the switching voltage; and
further wherein the acrylic acid monomer is replaced by at least one of the following selected from the group consisting of: a reactive ionic material, an aromatic material, a polypyrrole, and an acrylated or methacrylated acid of the type H 2 CCH—(CO)O—R—(CO)OH, where R is a linear or branched alkyl chain.