Golf ball cores comprising a halogenated organosulfur compound
View Patent ↗A golf ball consisting of a core having a diameter of between about 1.54 and about 1.61 inches and a compression of between about 70 and about 80, the core comprising a polybutadiene rubber having a Mooney viscosity of less than about 50 and a halogenated organosulfur compound, or a salt thereof, present in an amount of at least about 2.2 parts per hundred parts of polybutadiene rubber, the halogenated organosulfur compound having the formula: where R 1 -R 5 are C 1 -C 8 alkyl groups; halogen groups; thiol groups; carboxylated groups; sulfonated groups; or hydrogen; and a cover having a thickness of less than about 0.05 inches, the cover consisting essentially of a first ionomeric material, a second ionomeric material, and a metallocene-catalyzed polymer.
1. A golf ball consisting of:
a core having a diameter of between about 1.54 and about 1.61 inches and a compression of between about 70 and about 80, the core comprising a polybutadiene rubber having a Mooney viscosity of less than about 50 and a halogenated organosulfur compound, or a salt thereof, present in an amount of at least about 2.2 parts per hundred parts of polybutadiene rubber, the halogenated organosulfur compound having the formula:
where R 1 -R 5 are C 1 -C 8 alkyl groups; halogen groups; thiol groups; carboxylated groups; sulfonated groups; or hydrogen; and
a cover having a thickness of less than about 0.05 inches, the cover consisting essentially of a first ionomeric material, a second ionomeric material, and a metallocene-catalyzed polymer.
2. The golf ball of claim 1 , wherein the core has a diameter of between about 1.57 and about 1.59 inches.
3. The golf ball of claim 1 , wherein the cover layer has a thickness of between about 0.04 inches and about 0.05 inches.
4. The golf ball of claim 1 , wherein the polybutadiene composition further comprises an α,β-unsaturated carboxylic acid or a metal salt thereof, an organic peroxide, and a filler.
5. The golf ball of claim 4 , wherein the α,β-unsaturated carboxylic acid or a metal salt thereof is present in an amount greater than about 30 parts per hundred parts of polybutadiene rubber.
6. The golf ball of claim 5 , wherein the α,β-unsaturated carboxylic acid or a metal salt thereof is present in an amount greater than about 40 parts per hundred parts of polybutadiene rubber.
7. The golf ball of claim 1 , wherein the at least one of the first and second ionomeric materials contain α,β-unsaturated carboxylic acid groups, or the salts thereof, that have been partially- or fully-neutralized.
8. The golf ball of claim 1 , wherein the halogenated organosulfur compound is present in an amount between about 2.2 parts and about 5 parts.
9. The golf ball of claim 1 , wherein the halogenated organosulfur compound is selected from the group consisting of pentachlorothiophenol or a metal salt of pentachlorothiophenol.
10. The golf ball of claim 9 , wherein the metal salt is selected from the group consisting of zinc, calcium, magnesium, sodium, and lithium.
11. The golf ball of claim 10 , wherein the metal salt is zinc.
12. The golf ball of claim 1 , wherein the first and second ionomeric materials comprise copolymers or terpolymers of ethylene and methacrylic acid or acrylic acid partially- or fully-neutralized with salts of zinc, sodium, lithium, magnesium, potassium, calcium, manganese, or nickel.
13. The golf ball of claim 1 , wherein the polybutadiene has a Mooney viscosity between about 35 and about 50.
14. The golf ball of claim 1 , wherein the polybutadiene has a polydispersity of less than about 2.
15. The golf ball of claim 1 , wherein the first ionomeric material present in an amount between about 50% and about 60%, the second ionomeric material present in an amount between about 15% and about 25%, and the metallocene-catalyzed polymer present in an amount between about 20% and about 30%.
16. The golf ball of claim 1 , wherein the core has a surface hardness and a geometric center hardness that differs from the surface hardness by at least about 20 Shore D.
17. The golf ball of claim 1 , wherein the golf ball has a coefficient of restitution of between about 0.813 and about 0.823.
18. A golf ball consisting of:
a core having a diameter of between about 1.58 and about 1.61 inches and a compression of between about 70 and about 80, the core comprising a polybutadiene rubber having a Mooney viscosity of less than about 50 and a halogenated organosulfur compound or a salt thereof; and
a cover having a thickness of less than about 0.05 inches, the cover consisting essentially of a first ionomeric material, a second ionomeric material, a metallocene-catalyzed polymer;
wherein the golf ball has a coefficient of restitution of greater than about 0.813.
19. The golf ball of claim 18 , wherein the halogenated organosulfur compound is present in an amount of at least about 2.2 parts per hundred parts of the polybutadiene rubber, the halogenated organosulfur compound having the formula:
where R 1 -R 5 are C 1 -C 8 alkyl groups; halogen groups; thiol groups; carboxylated groups; sulfonated groups; or hydrogen.
20. A golf ball consisting of:
a core having a diameter of between about 1.57 and about 1.59 inches and a compression of between about 70 and about 80, the core comprising a polybutadiene rubber having a Mooney viscosity of less than about 50 and a halogenated organosulfur compound selected from the group consisting of pentafluorothiophenol; 2-fluorothiophenol; 3-fluorothiophenol; 4-fluorothiophenol; 2,3-fluorothiophenol; 2,4-fluorothiophenol; 3,4-fluorothiophenol; 3,5-fluorothiophenol 2,3,4-fluorothiophenol; 3,4,5-fluorothiophenol; 2,3,4,5-tetrafluorothiophenol; 2,3,5,6-tetrafluorothiophenol; 4-chlorotetrafluorothiophenol; pentachlorothiophenol; 2-chlorothiophenol; 3-chlorothiophenol; 4-chlorothiophenol; 2,3-chlorothiophenol; 2,4-chlorothiophenol; 3,4-chlorothiophenol; 3,5-chlorothiophenol; 2,3,4-chlorothiophenol; 3,4,5-chlorothiophenol; 2,3,4,5-tetrachlorothiophenol; 2,3,5,6-tetrachlorothiophenol; pentabromothiophenol; 2-bromothiophenol; 3-bromothiophenol; 4-bromothiophenol; 2,3-bromothiophenol; 2,4-bromothiophenol; 3,4-bromothiophenol; 3,5-bromothiophenol; 2,3,4-bromothiophenol; 3,4,5-bromothiophenol; 2,3,4,5-tetrabromothiophenol; 2,3,5,6-tetrabromothiophenol; pentaiodothiophenol; 2-iodothiophenol; 3-iodothiophenol; 4-iodothiophenol; 2,3-iodothiophenol; 2,4-iodothiophenol; 3,4-iodothiophenol; 3,5-iodothiophenol; 2,3,4-iodothiophenol; 3,4,5-iodothiophenol; 2,3,4,5-tetraiodothiophenol; 2,3,5,6-tetraiodothiophenoland; zinc salts thereof, and metal salts thereof; and
a cover having a thickness of between about 0.02 inches and about 0.05 inches, the cover consisting essentially of a first ionomeric material present in an amount between about 50% and about 60%, a second ionomeric material present in an amount between about 15% and about 25%, and a metallocene-catalyzed polymer present in an amount between about 20% and about 30%.