Oriented acrylic hotmelts
View Patent ↗A pressure sensitive adhesive obtainable by free-radical polymerization, characterized in that at least 65% by weight of the adhesive is based on at least one acrylic monomer from the group of the compounds of the following general formula: where R 1 =H or CH 3 and the radical R 2 =H or CH 3 or is selected from the group consisting of branched or unbranched saturated alkyl groups having 2–20 carbon atoms, the average molecular weight of the adhesive is at least 65,000, applied to a carrier, the adhesive possesses a preferential direction, where the refractive index measured in the preferential direction n MD is greater than the refractive index measured in a direction perpendicular to the preferential direction n CD , the difference Δn=n MD −n CD being at least 1·10 −5 .
1. A pressure sensitive adhesive, oriented and crosslinked in the oriented state,
comprising a polymer at least 65% of which is made up of at least one acrylic monomer selected from the group consisting of monomers of the following formula:
where R 1 =H or CH 3 and the radical R 2 =H or CH 3 or is selected from the group consisting of branched or unbranched saturated alkyl groups having 2–20 carbon atoms,
the weight average molecular weight (M w ) of the polymer is at least 650,000,
the refractive index of the adhesive, measured in the oriented direction n MD is greater than the refractive index measured in a direction perpendicular to the oriented direction n CD , the difference Δn=n MD −n CD being at least 1•10 −5 .
2. The adhesive as claimed in claim 1 , wherein said alkyl groups have 4–9 carbon atoms.
3. The adhesive as claimed in claim 1 , wherein said monomer make-up of said polymer further comprises up to 35% by weight of one or more vinyl compounds selected from the group consisting of vinyl esters, vinyl halides, vinylidene halides and nitriles of ethylenically unsaturated hydrocarbons.
4. The adhesive as claimed in claim 1 , further comprising aging inhibitors, light stabilizers, ozone protectants, fatty acids, plasticizers, nucleators, blowing agents, accelerators or combinations thereof.
5. The adhesive as claimed in claim 1 , further comprising difunctional or polyfunctional acrylates or methacrylates, difunctional or polyfunctional isocyanates or difunctional or polyfunctional epoxides.
6. An adhesive tape comprising a carrier coated on one or both sides with the pressure sensitive adhesive of claim 1 , 2 , 3 , 4 or 5 .
7. A process for preparing oriented acrylic pressure sensitive adhesives, comprising the steps of:
polyrnerizing a mixture comprising at least one vinyl-, acrylic- or methacrylic monomer or a combination of said monomers, the weight average molecular weight (M W ) of the resulting polymers being more than 650,000,
subsequently extrusion coating the polymer composition onto a carrier,
subsequently crosslinking the polymer composition on the carrier by irradiation with electron beams.