Process for purifying alicyclic alcohols
View Patent ↗A process for purifying alicyclic alcohols by distillation, wherein the alicyclic alcohols are distilled in the presence of from 1 to 550 ppm of acidic compounds.
1. A process for purifying alicyclic alcohols by distillation, as the top product consisting of distilling the alicyclic alcohols in the presence of from 1 to 500 ppm of acidic compounds, based on the amount of the alicyclic alcohol used.
2. The process as claimed in claim 1 , wherein the alicyclic alcohols have from 7 to 17 carbon atoms in the molecule.
3. The process as claimed in claim 1 wherein acidic compounds used are selected from the group consisting of aliphatic or aromatic sulfonic acids, aliphatic or aromatic monobasic or polybasic carboxylic acids, acid salts of strong or weak mineral acids, strong or weak mineral acids, tetraalkylammonium salts of strong or weak mineral acids, solid nonmetal oxides and acidic ion exchangers.
4. The process of claim 1 wherein the acidic compound used is selected from the group consisting of paratoluenesulfonic acid, naphthalene-sulfonic acid, sulfanilic acid, camphorsulfonic acid, potassium hydrogen sulfate, sodium dihydrogen phosphate, tetrabutyl-ammonium hydrogen sulfate, 9-anthracene-carboxylic acid and diphosphorous pentoxide.
5. The process as claimed in claim 1 wherein the acidic compounds are added in an amount of 5–250 ppm, based on the amount of the alicyclic alcohol.
6. The process as claimed in claim 1 wherein the distillation is carried out at a temperature of from 100 to 240°C.
7. The process of claim 1 wherein the acidic compounds are added in an amount of 5 to 50 ppm based on the amount of the alicyclic alcohol.
8. A process for purifying alicyclic alcohols by distillation as the top product wherein the alicyclic alcohol used is an isomer mixture selected from the group consisting of 3,8-bis(hydroxymethyl)tricyclo[5.2.1.0 2,6 ]decane, 3,9-bis(hydroxymethyl)tricyclo[5.2.1.0 2,6 ]decane, 4,8-bis(hydroxymethyl)tricyclo[5.2.1.0 2,6 ]decane) and 4,9-bis(hydroxymethyl)tricyclo[5.2.1.0 2,6 ]decane, an isomer mixture of 8-hydroxymethyltricyclo[5.2.1.0 2,6 ]decane, 9-hydroxy-3-hydroxymethyltricyclo[5.2.1.0 2,6 ]decane, 8-hydroxy-4-hydroxymethyltricyclo[5.2.1.0 2,6 ]decane and 9-hydroxy-4-hydroxy-methltricyclo[5.2.1.0 2,6 ]decane, an isomer mixture of 1,4:5,8-dimethano-2,6-bis(hydroxymethyl)perhydrofluorene, 1,4:5,8-dimethano-2,7-bis(hydroxymethyl)perhydrofluorene and 1,4:5,8-dimethano-3,6-bis(hydroxymethyl)perhydrofluorene and 1,4:5,8-dimethano-3,7-bis(hydroxymethyl)perhydrofluorene, and 4,9:5,8-dimethano-1,6-bis(hydromethyl)perhydrobenz[f]idene, 4,9:5,8-dimethano-2,6-bis(hydroxymethyl)perhydrobenz[f]idene, 4,9:5,8-dimethano-2,7-bis(hydroxymethyl)perhydrobenz[f]idene and 4,9:5,8-dimethano-2,7-bis(hydroxymethyl)perhydrobenz[f]idene and an isomer mixture of 2-hydroxymethylbicyclo[2.2.1]heptane consisting of distilling the alicyclic alcohols in the presence of from 1 to 500 ppm of acidic compounds, based on the amount of the alicyclic alcohol used.