Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas
View Patent ↗A process and catalyst are disclosed for the catalytic partial oxidation of light hydrocarbons to produce synthesis gas at superatmospheric pressures. A preferred catalyst used in the process includes a nickel-magnesium oxide solid solution and at least one promoter chosen from Cr, Mn, Mo, W, Sn, Re, Rh, Ru, Ir, Pt, La, Ce, Sm, Yb, Lu, Bi, Sb, In and P, and oxides thereof, carried on a refractory support.
1. A method of converting a light hydrocarbon and O 2 to a product mixture containing CO and H 2 , the process comprising:
forming a reactant gas mixture comprising a light hydrocarbon and O 2 ; and
passing said reactant gas mixture over a catalyst comprising
at least one first promoter chosen from the group consisting of Cr, Mn, La, Ce, and oxides thereof;
at least one second promoter chosen from the group consisting of Pt, Rh, and oxides thereof;
a solid solution comprising nickel and/or nickel oxide and magnesium oxide; and
a refractory support,
said catalyst having enhanced stability and enhanced resistance to coking under
catalytic partial oxidation promoting conditions,
such that a product mixture containing CO and H 2 is produced, and further wherein said catalyst comprises from about 4.0 to about 8.8 wt % Mg, from about 4.3 to about to about 11.3 wt % Ni and about 0.05 wt % Pt.
2. The method of claim 1 wherein said catalyst comprises about 8.8 wt % Mg, about 4.3 wt % Ni and about 0.05 wt % Pt.
3. The method of claim 1 wherein said catalyst comprises about 4.1 wt % Mg, about 10.2 wt % Ni, about 15 wt % Mn and about 0.05 wt % Pt.
4. The method of claim 1 wherein said catalyst comprises about 4.0 wt % Mg, about 10.6 wt % Ni, about 1.4 wt % La and about 0.05 wt % Pt.
5. The method of claim 1 wherein said catalyst comprises about 4.0 wt % Mg, about 11.3 wt % Ni, about 1.5 wt % Ce and about 0.05 wt % Pt.
6. The method of claim 1 wherein said catalyst support comprises a refractory material chosen from the group consisting of zirconia, MgO stabilized zirconia, zirconia stabilized alumina, yttrium stabilized zirconia, calcium stabilized zirconia, alumina, cordierite, mullite, titania, silica, magnesia, niobia, vanadia, nitrides and caibides, and combinations thereof.
7. The method of claim 1 wherein said support comprises a monolith.
8. The method of claim 1 wherein said support comprises a plurality of discrete siructures.
9. The method of claim 8 wherein the longest characteristic dimension or each said discrete structure is in the range of 50 microns to 6 mm in length.
10. A method of converting a light hydrocarbon and O 2 to a product mixture containing CO and H 2 , the process comprising:
forming a reactant gas mixture comprising a light hydrocarbon and O 2 ; and passing said reactant gas mixture over a catalyst such that a product mixture containing CO and H 2 is produced,
wherein said catalyst comprises
platinum;
a solid solution comprising nickel and/or nickel oxide and magnesium oxide; and
a refractory support, and
further wherein said catalyst comprises:
0.05-25 wt % Mg (wt % relative to total weight of catalyst)
1.0-5 atomic ratio of Ni (atomic ratio relative to the amount of Mg);
0.0001-0.01 atomic ratio of Pt (atomic ratio relative to the amount of Mg); and
0.05-1.0 atomic ratio of Cr (atomic ratio relative to the amount of Mg),
deposited on the refractory support.
11. The method of claim 10 wherein said catalyst comprises:
3-8 wt % Mg (wt % relative to total weight of catalyst)
1.0-3.0 atomic ratio of Ni (atomic ratio relative to the amount of Mg);
0.0001-0.005 atomic ratio of Pt (atomic ratio relative to the amount of Mg); and
0.05-0.5 atomic ratio of Cr (atomic ratio relative to the amount of Mg);
deposited on a refractory support.
12. A method of converting a light hydrocarbon and O 2 to a product mixture containing CO and H 2 , the process comprising:
forming a reactant gas mixture comprising a light hydrocarbon and O 2 ; and
passing said reactant gas mixture over a catalyst such that a product mixture containing CO and H 2 is produced,
wherein said catalyst comprises
a solid solution comprising nickel and/or nickel oxide and magnesium oxide;
chromium;
at least one promoter consisting of Pt; and
a refractory support, and
wherein said catalyst comprises Cr deposited on the refractory support with an atomic ratio of Cr relative to the amount of Mg between 0.05 and 1.0 and
wherein said catalyst comprises 0.01-0.5 wt % Pt deposited on the refractory support (wt % relative to total weight of catalyst)..