Aromatic polycarbonate resin composition and moldings
View Patent ↗Provided is an aromatic polycarbonate resin composition which comprises 100 parts by mass of an aromatic polycarbonate resin and from 0.001 to 1 part by mass of an additional thermoplastic resin that differs from the aromatic polycarbonate resin in the refractive index by at least 0.001 and which is so designed that the ratio (X)/(Y) is at least 0.5 wherein (X) indicates the spectral transmittance at 320 nm through a sample plate of the resin composition having a thickness of 2 mm and (Y) indicates the spectral transmittance at 633 nm through it. Having realized further increase in the transparency of aromatic polycarbonate resin, the resin composition gives moldings of which the transparency is comparable to that of acrylic resin for optical use, and the resin moldings have good impact resistance and heat resistance.
1. An aromatic polycarbonate resin composition which comprises 100 parts by mass of an aromatic polycarbonate resin and from 0.001 to 1 part by mass of an additional thermoplastic resin that differs from the aromatic polycarbonate resin in the refractive index by at least 0.001 and which is so designed that the ratio (X)/(Y) is at least 0.5 wherein (X) indicates the spectral transmittance at 320 nm through a sample plate of the resin composition having a thickness of 2 mm and (Y) indicates the spectral transmittance at 633 nm through it.
2. The aromatic polycarbonate resin composition as claimed in claim 1 , wherein the additional thermoplastic resin is an acrylic resin.
3. The aromatic polycarbonate resin composition as claimed in claim 1 , which contains from 0.005 to 0.2 parts by mass of a phosphorus-based antioxidant relative to 100 parts by mass of the aromatic polycarbonate resin.
4. The aromatic polycarbonate resin composition as claimed in claim 3 , wherein the phosphorus-based antioxidant is a compound derived from a phosphorus compound and pentaerythritol.
5. The aromatic polycarbonate resin composition as claimed in claim 4 , wherein the phosphorus-based antioxidant is bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol phosphite.
6. The aromatic polycarbonate resin composition as claimed in claim 1 , which contains from 0.01 to 2 parts by mass of a functional group-containing silicone compound and/or an alicyclic epoxy compound relative to 100 parts by mass of the aromatic polycarbonate resin.
7. A transparent molding comprising the aromatic polycarbonate resin composition of claim 1 .
8. An optical waveguide comprising the aromatic polycarbonate resin composition of claim 1 .
9. The aromatic polycarbonate resin composition as claimed in claim 1 , wherein the aromatic polycarbonate resin has a viscosity-average molecular weight between 10,000 and 100,000.
10. The aromatic polycarbonate resin composition as claimed in claim 1 , wherein the aromatic polycarbonate resin has a viscosity-average molecular weight between 11,000 and 40,000.
11. The aromatic polycarbonate resin composition as claimed in claim 1 , wherein the additional thermoplastic resin differs from the aromatic polycarbonate resin in the refractive index by between 0.01 and 0.2.
12. The aromatic polycarbonate resin composition as claimed in claim 1 , wherein the composition comprises from 0.05 to 0.5 parts by mass of an acrylic resin.
13. The aromatic polycarbonate resin compositions as claimed in claim 2 , wherein the acrylic resin is polymethyl methacrylate.
14. The aromatic polycarbonate resin composition as claimed in claim 3 , which contains from 0.01 to 0.1 parts by mass of a phosphorus-based antioxidant relative to 100 parts by mass of the aromatic polycarbonate resin.