Water-in-oil polymer dispersions with improved environmental compatibility
View Patent ↗The invention relates to water-in-oil polymer dispersions consisting of a continuous organic phase and water-soluble polymers finely distributed therein, wherein said polymers have a radical monomer content of less than 1,000 ppm. The invention also relates to a method for producing the inventive polymer dispersions and to their use of flocculation auxiliary agents, thickening agents and as additives for phytosanitary and anti-erosion agents.
1. A water-in-oil polymer dispersion, comprising a continuous organic phase comprising 20 to 80 wt % of a fatty acid ester that is practically immiscible with water, and a water-soluble polymer, and optionally one or more auxiliary agents finely distributed therein, and wherein said dispersion has a residual monomer content of less than 1000 ppm.
2. The water-in-oil polymer dispersion according to claim 1 , wherein said dispersion comprises:
A) 10 to 70 wt. % of a water-soluble polymer,
B) 0.5 to 10 wt. % of water-in-oil emulsifier,
C) 100 to 20,000 ppm of a residual monomer destructor,
D) 0.5 to 10 wt. % of an inverter, and
E) water to make up to 100 wt. %.
3. The water-in-oil polymer dispersion according to claim 1 , wherein the fatty acid ester 4 comprises linear saturated and unsaturated fatty acids, having an alkyl chain length of more than 11 carbon atoms, and of C 1 -C 4 alcohols or higher, unbranched alcohols; or a mixture of at least two of these esters.
4. The water-in-oil polymer dispersion according to claim 3 , wherein the fatty acid ester or the fatty acid esters are mixed with a hydrocarbon or a mixture of hydrocarbons, and wherein the boiling point of the hydrocarbon or of the mixture of hydrocarbons is below 200° C.
5. The water-in-oil polymer dispersion according to claim 1 , wherein the polymer comprises a polymer of acrylic acid and/or at let one acrylic acid derivative.
6. The water-in-oil polymer dispersion according to claim 1 , wherein the polymer comprises a polymer of at least one salt of acrylic acid and acrylamide.
7. The water-in-oil polymer dispersion according to claim 1 , wherein the polymer comprises a polymer of acrylic acid and/or a salt foacrylic acid, acrylamide and a salt of 2-acrylamido-2-methylpropane sulphonic acid.
8. The water-in-oil polymer dispersion according to claim 1 , wherein the polymer is present as polymer particles with dimensions less than 2 μm.
9. The water-in-oil polymer dispersion according to claim 1 , wherein said dispersion displays an EC 50 value determined, according t OECD Guideline 202, of over 10 mg/l.
10. The water-in-oil polymer dispersion according to claim 1 , wherein said dispersion displays an EC50 value, determined according to OECD Guideline 201, of over 10 mg/l.
11. A method for producing a water-in-oil polymer dispersion according to claim 1 , comprising polymerizing one or more monomers by reverse-phase emulsion polymerization, and wherein a residual monomer destructor is added to the polymer after polymerization.
12. The method according to claim 11 , wherein said residual monomer destructor is selected from substances from the group of acid and neutral salts of the acids derived from sulphur having an oxidation number below VI; substance having a hydrogen sulphide group; amines; Bunte salts; formamidine sulphinic acid; sulphur dioxide; aqueous and organic solutions of sulphur dioxide; thio urea or a mixture thereof.
13. The method according to claim 11 , wherein said residual monomer destructor is used in a quantity of 100 to 20,000 ppm, relative to the dispersion.
14. A method of flocculating particles and/or solids in a medium, comprising adding an effective amount of the water-in-oil polymer dispersion according to claim 1 , as a flocculation agent, to the medium.
15. A method of thickening a medium, comprising adding an effective amount of the water-in-oil polymer dispersion according to claim 1 , as thickening agent, to the medium.
16. A method of performing of a medium, comprising adding an effective amount of the water-in-oil polymer dispersion according to claim 1 , as an additive for a phytosanitary agent, optionally with one or more other biologically active agents, to the medium.
17. A method of reducing erosion of a medium, comprising adding an effective amount of the water-in-oil polymer dispersion according to claim 1 , as an additive for an anti-erosion agent, to the medium.
18. The method of claim 14 , wherein the medium comprises water.
19. The method of claim 14 , wherein the particles and/or solids are selected from coal, aluminum or petroleum.
20. A method for producing paper, comprising adding an effective amount of the water-in-oil polymer dispersion according to claim 1 , as an auxiliary agent, to one or more solvents used in paper production.
21. A method for producing sugar, comprising adding an effective amount of the water-in-oil polymer dispersion according to claim 1 , as an auxiliary agent, to one or more solvents used in sugar production.
22. The method according to claim 12 , wherein said residual monomer destructor is selected from sodium dithionite, sodium thiosulphate, sodium sulphite, sodium disulphite, sodium hydrogen sulphide, compounds from the group of thiols, mercaptoethanol, dodecyl mercaptan, thiopropionic acid, salts of thiopropionic acid, thiopropanesulphonic acid, salts of thiopropanesulphonic acid, amines with lop volatility, or a mixture thereof.