Adhesive additives and adhesive compositions containing an adhesive additive
View Patent ↗Adhesive additives that are used in conjunction with polyisocyanate resins to form adhesive compositions. The adhesive additives contain castor oil, a mixture of castor oil and triglycerides, or a reaction product from the transesterification of one or more polyols and one or more triglycerides. The adhesive compositions are well suited for use as a binder in the manufacture of various composite products, particularly composite wood products including OSB construction panels and laminate composites.
1. A wood composite comprising a material selected from the group consisting of wood strands, wood particles, and cellulose fibers, and a cured binder, wherein the cured binder comprises a crosslinked polymer that is a reaction product of one or more polyisocyanate resins, and an adhesive additive containing castor oil and one or more triglycerides, wherein the castor oil and the one or more triglycerides are provided as a weight ratio of castor oil to triglyceride from about 4:1 to about 1:4.
2. The wood composite of claim 1 wherein the one or more polyisocyanate resins is selected from the group consisting of polyphenylene diisocyanate and polymethylene polyphenyl isocyanates.
3. The wood composite of claim 1 wherein the crosslinked polymer is prepared from the polyisocyanate resins and the adhesive additive provided in a weight ratio of resin to adhesive additive from about 3:1 to about 1:1.
4. The wood composite of claim 1 wherein the weight ratio of castor oil to triglyceride is from about 3:1 to about 1:2.
5. The wood composite of claim 1 wherein the one or more triglycerides is selected from the group consisting of soybean oil, canola oil, corn oil, and linseed oil.
6. The wood composite of claim 1 wherein the material is wood strands and the wood composite is oriented strand board.
7. A wood composite comprising a material selected from the group consisting of wood strands, wood particles, and cellulose fibers, and a cured binder, wherein the cured binder comprises a crosslinked polymer that is a reaction product of one or more polyisocyanate resins and castor oil, wherein the resins and the castor oil are provided in a respective weight ratio of from about 3:1 to about 1:2, and the cured binder is present in an amount of 1% to 10% by weight based on the weight of the material.
8. The wood composite of claim 7 wherein the resins and the castor oil are provided in a respective weight ratio from about 3:2 to about 2:3.
9. A wood composite comprising wood strands and a cured binder, wherein the binder comprises a crosslinked polymer that is a reaction product of one or more polyisocyanate resins and an adhesive additive, the adhesive additive comprising a reaction product from the transesterification of one or more polyols and one or more triglycerides, and a weight ratio of polyol to triglyceride provides a calculated hydroxyl functionality of about 1.3 to about 2.6 in the transesterified reaction product.
10. The wood composite of claim 9 wherein the polyol is selected from the group consisting of of trimethylolpropane, pentaerythritol, castor oil, dipentaerythritol, tripentaerythritol, 1,2,4-butanetriol, 1,2,6-hexanetriol, glycerol, erythritol, sorbitol, mannitol, xylitol, castor oil, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, neopentylglycol, cyclohexane dimethanol, 2,2,4-trimethyl pentanediol, dicyclopentadienediol, ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, triethylene glycol, and polyethylene glycol.
11. The wood composite of claim 9 wherein the polyisocyanate resins and the adhesive additive are provided in a weight ratio of resin to additive from about 3:1 to about 1:1.
12. The wood composite of claim 9 wherein the one or more triglycerides is selected from the group consisting of soybean oil, canola oil, corn oil, and linseed oil.
13. A composite comprising synthetic fibers and a cured binder, wherein the cured binder comprises a crosslinked polymer that is a reaction product of one or more polyisocyanate resins, and an adhesive additive containing castor oil and one or more triglycerides, wherein the castor oil and the one or more triglycerides are provided as a weight ratio of castor oil to triglyceride from about 4:1 to about 1:4.
14. The composite of claim 13 wherein the synthetic fibers comprise organic polymers selected from the group consisting of polyacrylonitrile, aromatic polyamides, aliphatic polyamides, polyesters, poly(vinyl chloride), and poly(vinyl alcohol) and combinations thereof.
15. The composite of claim 13 wherein the synthetic fibers comprise an inorganic material selected from the group consisting of glass, metal, and ceramic.
16. A composite comprising synthetic fibers and a cured binder, wherein the cured binder comprises a crosslinked polymer that is a reaction product of one or more polyisocyanate resins and castor oil, wherein the resins and the castor oil are provided in a respective weight ratio of from about 3:1 to about 1:2, and the cured binder is present in an amount of 1% to 10% by weight based on the weight of the material.
17. The composite of claim 16 wherein the synthetic fibers comprise organic polymers selected from the group consisting of polyacrylonitrile, aromatic polyamides, aliphatic polyamides, polyesters, poly(vinyl chloride), and poly(vinyl alcohol) and combinations thereof.
18. The composite of claim 16 wherein the synthetic fibers comprise an inorganic material selected from the group consisting of glass, metal, and ceramic.
19. A composite comprising synthetic fibers and a cured binder, wherein the binder comprises a crosslinked polymer that is a reaction product of one or more polyisocyanate resins and an adhesive additive, the adhesive additive comprising a reaction product from the transesterification of one or more polyols and one or more triglycerides, and a weight ratio of polyol to triglyceride provides a calculated hydroxyl functionality of about 1.3 to about 2.6 in the transesterified reaction product.
20. The composite of claim 19 wherein the synthetic fibers comprise organic polymers selected from the group consisting of polyacrylonitrile, aromatic polyamides, aliphatic polyamides, polyesters, poly(vinyl chloride), and poly(vinyl alcohol) and combinations thereof.
21. The composite of claim 19 wherein the synthetic fibers comprise an inorganic material selected from the group consisting of glass, metal, and ceramic.