Curable composition for heat conductive material
View Patent ↗The invention provides a curable composition for a heat conductive material, having an excellent durability, a satisfactory heat conductive property and a high productivity with easily controllable surface tackiness, a heat conductive material obtained from such curable composition and a method for controlling the surface tackiness of the composition after curing. The curable composition for the heat conductive material is formed by a curable composition of heat curable type based on crosslinking by a hydrosilylation reaction and including a saturated hydrocarbon polymer containing at least an alkenyl group in a molecule, a curing agent containing at least two hydrosilyl groups in a molecule and a hydrosilylation catalyst, to which a heat conductive filler is incorporated, thereby providing a flexible elastomer with a satisfactory heat conductivity and with an easily controllable surface tackiness.
1. A curable composition for a heat conductive material, comprising:
a substantially saturated hydrocarbon polymer including at least one alkenyl group in a molecule;
a curing agent including at least two hydrosilyl groups in a molecule;
a hydrosilylation catalyst;
at least one heat conductive filler selected from the group consisting of aluminum oxide, boron nitride, aluminum nitride, silicon carbide, aluminum hydroxide, crystalline silica, aluminum, copper, and silver; and
a plasticizer,
wherein the at least one heat conductive filler include particles of at least two sizes.
2. The curable composition for a heat conductive material according to claim 1 , wherein saturated hydrocarbon polymer is a polyisobutylene polymer.
3. The curable composition for a heat conductive material according to claim 1 , wherein the curing agent is polyorganohydrogen polysiloxane including at least two hydrosilyl groups in a molecule.
4. The curable composition for a heat conductive material according to claim 1 , wherein heat conductive filler content of the entire composition is not less than 25 vol. %.
5. The curable composition for a heat conductive material according to claim 1 , wherein a molar ratio of an amount of the hydrosilyl groups in curing agent to an amount of alkenyl groups in saturated hydrocarbon polymer is in a range from 1:0.5 to 1:5.
6. The curable composition for a heat conductive material according to claim 1 , wherein an average number of the hydrosilyl groups contained per molecule of curing agent is selected within a range of 2 to 40 units.
7. A cured material for a heat conductive material obtained from the composition according to claim 1 .
8. A cured material for a heat conductive material obtained from the composition according to claim 2 .
9. A cured material for a heat conductive material obtained from the composition according to claim 4 .
10. The cured material for a heat conductive material according to claim 7 , wherein cured material is a molded article.
11. The cured material for a heat conductive material according to claim 8 , wherein cured material is a molded article.
12. The cured material for a heat conductive material according to claim 9 , wherein cured material is a molded article.
13. The curable composition for a heat conductive material according to claim 1 , wherein the different particles sizes include a larger particle size greater than 10 μm and a smaller particle size less than or equal to 10 μm.
14. The curable composition for a heat conductive material according to claim 1 , wherein heat conductive filler comprises a heat conductive filler that is surface-treated with a silane coupling agent.
15. The curable composition for a heat conductive material according to claim 14 , wherein the silane coupling agent is selected from the group consisting of vinylsilane, epoxysilane, (meth)acrylsilane, titanate coupling agent, fatty acid, and resin acid.