Method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes
View Patent ↗Disclosed is a method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising: a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends; b) terminating the living chain ends; to produce a terminated block copolymer, with a member from the group consisting of an alcohol, hydrogen, and mixtures thereof, to prepare a terminated block copolymer; and c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C. in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl, wherein: (i) if the polymer is terminated with an alcohol and the alcohol is a linear alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to 1.2: (ii) if the polymer is terminated with an alcohol and the alcohol is a branched alcohol, the branched alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ration is from 0.05 to about 3.0: an (iii) if the polymer is terminated with an alcohol and the alcohol is a mixture of a linear alcohol and a branched alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the linear alcohol:living chain end molar ration is from 0.05 to 1.2.
1. A method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising:
a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends;
b) terminating the living chain ends with an alcohol, or a mixture of hydrogen and alcohol to prepare a terminated block copolymer; and
c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C. in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl,
wherein the alcohol is a linear alcohol or a mixture of a linear alcohol and a branched alcohol, and wherein
(i) if the polymer is terminated with the linear alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to 1.2;
(ii) if the polymer is terminated with the mixture of a linear alcohol and a branched alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the linear alcohol:living chain end molar ratio is from 0.05 to 1.2,
and wherein the linear alcohol is methanol, ethanol, n-propanol, n-butanol, n-pentanol or a mixture thereof.
2. The method of claim 1 wherein the alcohol is a linear alcohol.
3. The method of claim 2 wherein the alcohol:living chain end molar ratio is from 0.5:1 to 1.19:1.
4. The method of claim 3 wherein the alcohol:living chain end molar ratio is from 1.0:1 to 1.1:1.
5. The method of claim 1 wherein the alcohol is a mixture of methanol and 2-ethyl-1-hexanol.
6. The method of claim 1 wherein the alcohol is a mixture of linear alcohol and branched alcohol.
7. The method of claim 6 wherein the branched alcohol is selected from the group consisting of the tertiary alcohols, the β-branched primary aliphatic alcohols, the β,β-branched primary aliphatic alcohols, and the β,β-branched secondary aliphatic alcohols.
8. The method of claim 7 wherein the branched alcohol is selected from the group consisting of t-butanol, neopentyl alcohol, and 2-ethyl-1-hexanol.
9. The method of claim 1 wherein the catalyst is prepared using a carboxylate selected from the group consisting of cobalt neodecanoate, cobalt hexanoate, cobalt ethylhexanoate, cobalt heptanoate, cobalt octanoate, cobalt nonanoate, cobalt decanoate, cobalt dodecanoate, cobalt versatate, cobalt myristoate, cobalt palmidoate, cobalt stearate, cobalt oleoate, cobalt linoleoate, cobalt rhodinoate, cobalt naphthanoate, cobalt cyclohexylcarboxiate, cobalt salts of abietic resin acids, cobalt benzoate, and cobalt salts of alkyl-substituted aromatic acids in which the alkyl substitution has from 1 to 20 carbon atoms.
10. The method of claim 9 wherein the catalyst is prepared using cobalt neodecanoate.
11. The method of claim 1 wherein the catalyst is prepared using a carboxylate selected from the group consisting of cobalt ethyihexanoate, cobalt heptanoate, cobalt nonanoate, cobalt dodecanoate, cobalt versatate, cobalt myristoate, cobalt palmidoate, cobalt stearate, cobalt oleoate, cobalt linoleoate, cobalt rhodinoate, cobalt naphthanoate, cobalt cyclohexylcarboxiate, cobalt salts of abietic resin acids, cobalt benzoate, and cobalt salts of alkyl-substituted aromatic acids in which the alkyl substitution has from 1 to 20 carbon atoms.
12. The method of claim 1 wherein the linear alcohol is methanol.
13. A method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising:
a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends;
b) terminating the living chain ends with a member from the group consisting of an alcohol, or a mixture of hydrogen and alcohol to prepare a terminated block copolymer; and
c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C. in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl,
wherein
the alcohol is a linear alcohol and the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to 1.2,
and wherein the linear alcohol is methanol, ethanol, n-propanol, n-butanol, n-pentanol or a mixture thereof.
14. The method of claim 13 wherein the catalyst is prepared using cobalt neodecanoate.
15. The method of claim 13 wherein the linear alcohol is methanol.
16. A method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising:
a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends;
b) terminating the living chain ends with a member from the group consisting of an alcohol, hydrogen, and mixtures thereof, to prepare a terminated block copolymer; and
c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C. in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl, wherein the carboxylate is cobalt neodecanoate,
wherein
(i) if the polymer is terminated with an alcohol and the alcohol is linear alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to 1.2;
(ii) if the polymer is terminated with an alcohol and the alcohol is a branched alcohol, the branched alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to about 3.0; and
(iii) if the polymer is terminated with an alcohol and the alcohol is a mixture of a linear alcohol and a branched alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the linear alcohol:living chain end molar ratio is from 0.05 to 1.2.
17. The method of claim 16 wherein the alcohol is a linear alcohol.
18. The method of claim 16 wherein the alcohol:living chain end molar ratio is from 0.5:1 to 1.19:1.
19. The method of claim 16 wherein the alcohol:living chain end molar ratio is from 1.0:1 to 1.1:1.
20. The method of claim 16 wherein the alcohol is selected from the group consisting of methanol, 2-ethyl-1-hexanol, and mixtures thereof.
21. The method of claim 16 wherein the alcohol is a branched alcohol.
22. The method of claim 21 wherein the branched alcohol is selected from the group consisting of the tertiary alcohols, the β-branched primary aliphatic alcohols, the β,β-branched primary aliphatic alcohols, and the β,β-branched secondary aliphatic alcohols.
23. The method of claim 22 wherein the branched alcohol is selected from the group consisting of t-butanol, neopentyl alcohol, and 2-ethyl-1-hexanol.
24. The method of claim 17 wherein the linear alcohol is selected from the group consisting of methanol, ethanol, n-propanol, n-butanol, n-pentanol or a mixture thereof.
25. The method of claim 17 wherein the linear alcohol is methanol.
26. A method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising:
a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends;
b) terminating the living chain ends with a member from the group consisting of an alcohol, hydrogen, and mixtures thereof, to prepare a terminated block copolymer; and
c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C. in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl,
wherein the catalyst is prepared using a carboxylate selected from the group consisting of cobalt ethylhexanoate, cobalt versatate, cobalt myristoate, cobalt palmidoate, cobalt stearate, cobalt oleoate, cobalt linoleoate, cobalt rhodinoate, cobalt naphthanoate, cobalt cyclohexylcarboxiate, cobalt salts of abietic resin acids, cobalt benzoate, and cobalt salts of alkyl-substituted aromatic acids in which the alkyl substitution has from 1 to 20 carbon atoms,
wherein:
(i) if the polymer is terminated with an alcohol and the alcohol is linear alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to 1.2;
(ii) if the polymer is terminated with an alcohol and the alcohol is a branched alcohol, the branched alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to about 3.0; and
(iii) if the polymer is terminated with an alcohol and the alcohol is a mixture of a linear alcohol and a branched alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the linear alcohol:living chain end molar ratio is from 0.05 to 1.2.
27. The method of claim 11 , wherein the catalyst is prepared using a carboxylate selected from the group consisting of cobalt ethyihexanoate, cobalt versatate, cobalt myristoate, cobalt palmidoate, cobalt stearate, cobalt oleoate, cobalt linoleoate, cobalt rhodinoate, cobalt naphthanoate, cobalt cyclohexylcarboxiate, cobalt salts of abietic resin acids, cobalt benzoate, and cobalt salts of alkyl-substituted aromatic acids in which the alkyl substitution has from 1 to 20 carbon atoms.