Process and apparatus for recovering sulphur from a gas stream containing sulphide
View Patent ↗Oxygen or oxygen-enriched air is employed to support combustion in furnaces ( 16 ) and ( 26 ) of part of the hydrogen sulphide content of a first feed gas stream. Sulphur vapour is extracted in condenser ( 32 ) from the resulting gas mixture so as to form a sulphur vapour depleted gas stream. The sulphur vapour depleted gas stream is passed into a catalytic reduction reactor ( 40 ) in which all the residual sulphur dioxide is reduced to hydrogen sulphide. This reduced gas mixture has water vapour extracted therefrom in a quench tower ( 52 ). The resulting water vapour depleted gas stream flows to a Claus plant for treatment typically together with a second feed gas steam comprising hydrogen sulphide. Employing both furnaces ( 16 ) and ( 26 ) makes it possible to obtain effective conversions to sulphur of the hydrogen sulphide in the feed gas without having the recycle any of the water vapour depleted gas.
1. A method of treating a feed gas stream comprising hydrogen sulphide, comprising the steps of:
a) in at least two furnaces in series oxidising to sulphur dioxide a part of the hydrogen sulphide content of at least one feed gas stream comprising hydrogen sulphide and reacting thus formed sulphur dioxide with residual hydrogen sulphide to form sulphur vapour and water vapour;
b) withdrawing from the downstream furnace a partially reacted gas stream including sulphur vapour, water vapour, residual hydrogen sulphide and residual sulphur dioxide;
c) extracting in a sulphur condenser, sulphur vapour from the partially reacted gas stream so as to form a sulphur vapour depleted gas stream;
d) catalytically reducing with hydrogen to hydrogen sulphide the sulphur dioxide and any sulphur vapour content of the sulphur vapour depleted gas stream so as to form a reduced gas stream;
e) extracting water vapour by condensation from the reduced gas stream so as to form a water vapour depleted gas stream; and
f) feeding without recycle the water vapour depleted gas stream to at least one Claus plant for recovering sulphur from hydrogen sulphide comprising at least one further furnace for the oxidation of hydrogen sulphide to sulphur dioxide and reaction of resulting sulphur dioxide with residual hydrogen sulphide, a first further sulphur condenser, and a plurality of stages of catalytic reaction, there being a second further sulphur condenser downstream of each stage of said catalytic reaction, and thereby extracting further sulphur vapour wherein:
a gas containing at least 80% by volume of oxygen molecules is employed to support combustion in step a),
the water vapour depleted gas stream contains at least 40% by volume of hydrogen sulphide, and
in step f) the catalytic reaction is a Claus reaction between hydrogen sulphide and sulphur dioxide or a selective oxidation of hydrogen sulphide to sulphur, or both reactions.
2. A method according to claim 1 , wherein in step f) each stage of catalytic reaction is a Claus reaction between hydrogen sulphide and sulphur dioxide.
3. A method according to claim 1 , in which the mole ratio of hydrogen sulphide to sulphur vapour in the sulphur vapour depleted gas stream is in the range of 4:1 to 10:1.
4. A method according to claim 1 , wherein the flow rate of oxygen to the upstream furnace in step a) is in the range of M to N where M=(0.8 a+b+0.16c) and N=(a+b+0.22c) where:
a) is the stoichiometric rate of supply of oxygen for the complete oxidation to nitrogen and water vapour of any ammonia in the feed gas stream;
b) is the stoichiometric rate of supply of oxygen for the complete combustion of any hydrocarbon(s) present in the feed gas stream; and
c) is the stoichiometric rate of oxygen supply required for the complete oxidation to sulphur dioxide and water vapour of hydrogen sulphide in the feed gas stream.
5. A method according to claim 1 wherein two furnaces are used, wherein the rate of supply of oxygen to the downstream furnace in step a) is in the range P to Q. where P=0.8 d+e+0.16f and Q=d+e+0.22f, where:
d) is the stoichiometric rate of oxygen required for the total oxidation to nitrogen and water vapour of any ammonia entering the downstream furnace;
e) is the rate of oxygen supply required for the total combustion to carbon dioxide and water vapour of any hydrocarbons entering the downstream furnace and
f) is the stoichiometric rate of oxygen supply required for the complete combustion of hydrogen sulphide entering the downstream furnace to water vapour and sulphur dioxide.
6. A method according to claim 1 , wherein the water condensation step e) is performed by direct contact of the reduced gas stream with water, the reduced gas stream being cooled by indirect heat exchange intermediate the catalytic reduction step d) and the water condensation step e).
7. A method according to claim 1 , wherein from 80 to 90% of the hydrogen sulphide entering step a) is converted to sulphur vapour upstream of the catalytic reduction step d).