Process for alkali saponification of cellulose ester film surface
View Patent ↗A process for alkali saponification of polymer film is disclosed. The process comprises the steps of applying solution of an alkali onto a polymer film having a temperature of not lower than room temperature, and washing away the alkaline solution from the film.
1. A process for alkali saponification of only one side of a cellulose ester film surface, which comprises the steps of heating a cellulose ester film at a temperature of higher than room temperature, coating a solution of an alkali in a mixture of water and an organic solvent at a mixing ratio of water/organic solvent in the range of 5/95 to 60/40 by weight onto the only one side of the cellulose ester film surface, keeping the temperature of the film not lower than the room temperature, and washing away the alkaline solution from the film.
2. The process as defined in claim 1 , wherein the steps are carried out while conveying the cellulose ester film.
3. The process as defined in claim 1 , wherein the normality of the alkaline solution is in the range of 0.1 to 5 N, and the amount of the coated alkaline solution is in the range of 1 to 50 ml/m 2 .
4. The process as defined in claim 1 , wherein the alkali is a hydroxide of alkali metal, and the organic solvent is selected from the group consisting of alcohols having 1 to 8 carbon atoms, ketones having 1 to 6 carbon atoms, esters having 1 to 6 carbon atoms, and polyhydric alcohols having 1 to 6 carbon atoms.
5. The process as defined in claim 1 , wherein the alkaline solution contains a nonionic surface active agent in an amount of 0.1 to 10 wt. %.
6. The process as defined in claim 5 , wherein the nonionic surface active agent is represented by the formula (1):
R1-L1-Q1 (1)
in which R1 is an alkyl group having 8 or more carbon atoms; L1 is a bond or a divalent linking group between R1 and Q1; and Q1 is a nonionic hydrophilic group.
7. The process as defined in claim 5 , wherein the nonionic surface active agent is represented by the formula (2):
R2-L2-Q2 (2)
in which R2 is an alkyl group having 8 or more carbon atoms; L2 is a bond or a divalent linking group between R2 and Q2; and Q2 is a nonionic hydrophilic group selected from the group consisting of polyoxyethylene unit having a polymerization degree of 5 to 150, polyglycerol unit having a polymerization degree of 3 to 30, and a hydrophilic saccharide chain unit.
8. The process as defined in claim 1 , wherein the cellulose ester film has a thickness in the range of 30 to 200 μm.
9. The process as defined in claim 1 , wherein the cellulose ester film surface is coated with the solution by die coater, a roll coater, a rod coater, a gravure coater or a blade coater.