Fuel cell stacking and sealing
View Patent ↗Various aspects of solid oxide fuel cell (SOFC) technology are described. One specific application includes a seal for connecting an outer surface of a fuel cell to a cell manifold that supports the fuel cell and delivers a fuel mixture to an inside portion of the fuel cell. The seal also separates the fuel mixture from the outer surface at the seal. And the seal is electrically conductive to allow flow of electric current between the outer surface and the cell manifold.
1. A fuel cell system comprising:
a. a plurality of fuel cells for chemically converting a fuel mixture into electric current, each fuel cell having an inner anode layer forming an anode, an electrolyte layer disposed on the inner anode layer, and an outer cathode layer disposed on the electrolyte layer, each fuel cell also having a metallic end cap bonded to the fuel cell such that a seal is made via a bond between the metallic structure of the end cap and a surface of the anode on an outside diameter of the fuel cell and current collection occurs across a bond between an inside diameter of the fuel cell and the end cap, the end cap including an orifice for allowing flow of fuel to an interior of the fuel cell, wherein the cathode and electrolyte layers terminate short of the manifold so as to allow the seal to be made to the surface of the anode on the outside diameter of the fuel cell;
b. a cell manifold for supporting the plurality of fuel cells and for delivering the fuel mixture to interior portions of the fuel cells, the manifold having a plurality of fuel cell receptacles in fluid communication with a fuel distribution plenum, each fuel cell receptacle mating with a connecting ferrule portion of the end cap of a fuel cell, such mating providing electrical connectivity between the manifold and the end caps and also providing for delivery of fuel from the fuel distribution plenum to the interior portions of the fuel cells through the end cap orifices; and
c. wherein the seal includes a leak-tight ceramic-to-metal joint.
2. A fuel cell system according to claim 1 , wherein the plurality of fuel cells are solid oxide fuel cells (SOFC's).
3. A fuel cell system according to claim 1 , wherein each seal is based on an alloy of at least one of gold, silver, palladium, or nickel.
4. A fuel cell system according to claim 3 , wherein the seal is based on inductive brazing of the alloy.
5. A fuel cell system according to claim 1 , wherein the anode surface of the fuel cell is based on a composite ceramic material.
6. A fuel cell system according to claim 5 , wherein the composite ceramic material is yttria-stabilized zirconia (YSZ).
7. A fuel cell system according to claim 1 , further comprising a current collector that makes a snap fit with the outer cathode layers of the fuel cells.
8. A fuel cell system according to claim 1 , wherein the outer cathode layer is based on lanthanum manganate.
9. A fuel cell system according to claim 1 , wherein the cell manifold is one of a plurality of cell manifolds, wherein each manifold holds a plurality of fuel cells in a common plane, and wherein the fuel cells attached to each manifold are connected in electrical parallel.
10. A fuel cell system according to claim 9 , wherein the cell manifolds are arranged in a vertical stack of fuel cells, and wherein the cell manifolds are connected in electrical series.
11. A fuel cell system according to claim 1 , wherein each end cap includes a stop ledge that abuts the cell manifold when the end cap is completely mated to the cell manifold.
12. A fuel cell system according to claim 11 , wherein the end cap is adapted for threading or press fitting of the end cap to the fuel cell manifold.