Process for preparing dimethyl propanephosphonate
View Patent ↗Process for preparing dimethyl propanephosphonate, characterized in that dimethyl phosphite is reacted with propene in the presence of a free-radical former at a reaction temperature of 60 to 95° C., the half life of the free-radical former being 0.1 to 20 min at the reaction temperature.
1. Process for preparing dimethyl propanephosphonate, comprising reacting dimethyl phosphite with propene in the presence of a free-radical former at a reaction temperature of 60 to 95° C., the half life of the free-radical former being 0.1 to 20 min at the reaction temperature,
wherein the dimethyl propanephosphonate is prepared at a yield that is more than 95% and formation of trimethyl phosphate in the amount of more than 0.1% by weight is avoided.
2. Process according to claim 1 , wherein the reaction temperature is 80 to 95° C.
3. Process according to claim 1 , wherein the half life of the free-radical former is 0.5 to 10 min at the reaction temperature.
4. Process according to claim 1 , wherein the free-radical former is used in an amount of 0.1 to 5 mol % based on propene.
5. Process according to claim 1 , wherein the free-radical former is used in an amount of 0.3 to 2 mol %, based on propene.
6. Process according to claim 1 , wherein tert-butyl peroxyneodecanoate or dilauroyl peroxide is used as free-radical former.
7. Process according to claim 1 , wherein the molar ratio of dimethyl phosphite propene is 1.0:1.0 to 3.0:1.0.
8. Process according to claim 1 , wherein the molar ratio of dimethyl phosphite to propene is 1.1:1.0 to 2.3:1.0.
9. Process according to claim 1 , wherein dimethyl phosphite with a trimethyl phosphate content of 0 to 0.1% by weight is used.
10. Process according to claim 1 , wherein dimethyl phosphite with a trimethyl phosphate content of 0 to 0.01% by weight is used.
11. Process according to claim 1 , wherein the reaction is carried out at a pressure of 150 to 6 000 mbar (absolute).
12. Process according to claim 1 , wherein the reaction is carried out at a pressure of 500 to 950 mbar (absolute).