Iron-based rare earth alloy nanocomposite magnet and method for producing the same
View Patent ↗An iron-based rare earth alloy nanocomposite magnet has a composition represented by (Fe 1-m T m ) 100-x-y-z Q x R y Ti z , where T is Co and/or Ni, Q is B and/or C and R is rare earth element(s) including substantially no La or Ce. x, y, z and m satisfy 10 at %<x≦17 at %, 7 at %≦y<10 at %, 0.5 at %≦z≦6 at % and 0≦m≦0.5, respectively. The magnet includes crystal grains of an R 2 T 14 Q type compound having an average grain size of 20 nm to 200 nm and a ferromagnetic iron-based boride that exists in a grain boundary between the crystal grains of the R 2 T 14 Q type compound. The boride is dispersed in, or present in the form of a film over, the grain boundary to cover at least partially the surface of the crystal grains of the R 2 T 14 Q type compound.
1. An iron-based rare earth alloy nanocomposite magnet having a composition represented by the general formula: (Fe 1-m T m ) 100-x-y-z Q x R y Ti z , where T is at least one element selected from the group consisting of Co and Ni; Q is at least one element selected from the group consisting of B and C; and R is at least one rare earth element including no La or Ce, the mole fractions x, y, z and m satisfying the inequalities of:
10 at %<x≦17 at %;
7 at %≦y<10 at %;
0.5 at %≦z≦6 at %; and
0≦m≦0.5, respectively; wherein
crystal grains of an R 2 T 14 Q type compound have an average grain size of about 20 nm to about 200 nm;
crystal grains of a ferromagnetic iron-based boride have an average crystal grain size smaller than the crystal grain size of the crystal grains of the R 2 T 14 Q type compound; and
the ferromagnetic iron-based boride is a soft magnetic phase and is dispersed in the grain boundary or present in the form of a film over the grain boundary to cover at least partially the surfaces of the crystal grains of the R 2 T 14 Q type compound.
2. The magnet of claim 1 , wherein the mole fractions x, y and z satisfy the inequalities of:
10 at %<x≦15 at %;
7 at %≦y≦9.3 at %; and
1.5 at %≦z≦5 at %.
3. The magnet of claim 1 , wherein the magnet further comprises crystalline phases, including the R 2 T 14 Q type compound and the ferromagnetic iron-based boride, at about 95 vol % or more in total, and amorphous phases at about 5 vol % or less.
4. The magnet of claim 3 , wherein the magnet comprises the R 2 T 14 Q type compound at about 65 vol % to about 85 vol %.
5. The magnet of claim 1 , wherein the crystal grains of the R 2 T 14 Q type compound have a Ti concentration of about 2 at % or less, and a Ti concentration in the grain boundary between the crystal grains of the R 2 T 14 Q type compound is higher than the Ti concentration inside the crystal grains of the R 2 T 14 Q type compound.
6. The magnet of claim 5 , wherein the Ti concentration in the grain boundary between the crystal grains of the R 2 T 14 Q type compound is about 7 at % or more.
7. The magnet of claim 1 , wherein the ferromagnetic iron-based boride has an average size of about 50 nm or less as measured along a thickness of the grain boundary.
8. The magnet of claim 1 , wherein the ferromagnetic iron-based boride is present in the form of a film having an average thickness of about 20 nm or less over the grain boundary between the crystal grains of the R 2 T 14 Q type compound.
9. The magnet of claim 1 , wherein the ferromagnetic iron-based boride exists in the grain boundary between the crystal grains of the R 2 T 14 Q type compound and has an average major axis length of about 1 nm to about 50 nm.
10. The magnet of claim 1 , wherein on an arbitrary cross section of the magnet, the crystal grains of the R 2 T 14 Q type compound have an average size that is greater than an average size of the ferromagnetic iron-based boride.
11. The magnet of claim 1 , wherein the mole fractions x and z satisfy the inequalities of:
10 at %<x≦14 at % and
0.5 at %≦z≦4 at %.
12. The magnet of claim 1 , wherein the ferromagnetic iron-based boride comprises at least one of Fe 3 B and Fe 23 B 6 .
13. The magnet of claim 1 , wherein the magnet has a thin strip shape having a thickness of about 10 μm to about 300 μm.
14. The magnet of claim 1 , wherein the magnet has been pulverized into powder particles.
15. The magnet of claim 14 , wherein the powder particles have a mean particle size of about 30 μm to about 250 μm.
16. The magnet of claim 1 , wherein the magnet has a remanence B r of about 0.80 T or more, a maximum energy product (BH) max of about 100 kJ/m 3 or more and a coercivity H cJ of about 480 kA/m or more.
17. The magnet of claim 1 , wherein the magnet has a remanence B r of about 0.85 T or more and a maximum energy product (BH) max of about 120 kJ/m 3 or more.
18. A bonded magnet obtained by molding a magnet powder, comprising a powder of the iron-based rare earth alloy magnet according to claim 14 , with a resin binder.
19. A bonded magnet obtained by molding a magnet powder, comprising a powder of the iron-based rare earth alloy magnet according to claim 15 , with a resin binder.