Lithium polymer secondary battery
View Patent ↗A lithium polymer secondary battery which comprises a negative electrode, a positive electrode, and polymer electrolyte layers united respectively with the two electrodes and differing in viscoelastic behavior. In this battery, conformation to the expansion and shrinkage accompanying charge/discharge is easy and the interfacial resistance between each electrode and the polymer electrolyte is kept low.
1. A lithium secondary battery comprising an anode having an electroactive substance comprised of a carbonaceous substance capable of electrochemically inclusion and release of lithium, a cathode having an electroactive substance comprised of a chalcogenide compound containing lithium, and a polymer gel electrolyte layer sandwiched between the cathode and the anode, wherein said polymer gel electrolyte layer comprises a matrix of an ion-conductive polymer of polyether polyol (meth)acrylate retaining a nonaqueous electrolyte solution therein, wherein said polymer gel electrolyte layer is divided into a first sub-layer integrally formed with said cathode and a second sub-layer integrally formed with said anode, and wherein the precursor monomer of said ion-conductive polymer in said first sub-layer has a polymerizable functionality of 3, and the precursor monomer of said ion-conductive polymer in said second sub-layer has a polymerizable functionality less than 3, the precursor monomer of said ion-conductive polymer in said first sub-layer being a trihydric polyether polyol triacrylate and the precursor monomer of said ion-conductive polymer in said second sub-layer being a mixture of said trihydric polyether polymer triacrylate with triethylene glycol monomethyl ether acrylate at a weight ratio of 1:1.
2. The lithium polymer secondary battery according to claim 1 wherein the solvent of said nonaqueous electrolyte solution is selected from ethylene carbonate, propylene carbonate, ethyl methyl carbonate, dimethyl carbonate, diethyl carbonate, r-butyrolactone or a mixture thereof.
3. The lithium polymer secondary battery according to claim 1 wherein said electroactive substance of said anode is a particulate graphite having amorphous carbon attached to the surfaces thereof.
4. The lithium polymer secondary battery according to claim 1 wherein said polyether polyol poly(methacrylate) contains a plurality of polyether chains consisting of an ethylene oxide (EO) unit and optionally a propylene oxide (PO) unit.