Lithium polymer secondary battery and method for manufacturing the same
View Patent ↗A lithium polymer secondary cell having a negative electrode, a positive electrode and, arranged between the electrodes, a polymer electrolyte layer, characterized in that the cell has been subjected to a heat treatment at a temperature of 40 to 60° C. after the assembly thereof. The polymer cell is freed of or is reduced in the adverse effect of a residual monomer and initiator on the performance of the cell. The polymer electrolyte is formed by cross-linking polymerization of a precursor monomer for an ion conducting polymer in a non-aqueous electrolyte, and the residual monomer and initiator contained therein is consumed by the heat treatment.
1. A method for manufacturing the lithium polymer secondary battery
comprising the steps of:
providing an anode having an electroactive substance comprised of a carbonaceous material capable of electrochemically inclusion and release of lithium and a cathode having an electroactive substance comprised of a chalcogenide compound containing lithium;
forming a polymer electrolyte layer comprised of a matrix of ion-conductive polymer retaining a nonaqueous electrolyte solution therein on the cathode and the anode, wherein said step of forming the polymer electrolyte layer comprises polymerizing and crosslinking a precursor monomer of said ion-conductive polymer in said nonaqueous solution containing a lithium salt in situ in the presence of a polymerization initiator;
joining the cathode and the anode together with their polymer electrolyte layers facing inwardly to manufacture the battery; and
subjecting the battery as manufactured to a heat treatment before charging the battery initially, whereby the amounts of the precursor monomer of said ion-conductive polymer and the polymerization initiator thereof remaining in said polymer electrolyte layers are decreased at least 40% after said heat treatment, wherein said heat treatment is carried out at a temperature between 40° C. and 60° C.
2. The method according to claim 1 further comprising the step of placing a porous substrate made of polyethylene, polypropylene or polyester as a support member on the at least one electrode before forming said polymer electrolyte layer.