IP Library Granted Patent US 6,863,969
Granted Patent B2
US 6,863,969 · App. 10/382,183 · Granted Mar 8, 2005

Fiber-reinforced matrix compositions

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Quick Facts
Patent No.
US 6,863,969
App. No.
10/382,183
Granted
Mar 8, 2005
Kind
B2
Abstract

Synthetic polymer reinforcing fibers provide dispersability and strength in matrix materials such as concrete, masonry, shotcrete, and asphalt. The individual fiber bodies, substantially free of stress fractures and substantially non-fibrillatable, have generally quadrilateral cross-sectional profiles along their elongated lengths. Preferred fibers and matrix materials having such fibers demonstrate excellent finishability in addition to dispersion and toughness properties.

Claims (52)

1. A matrix composition, comprising:

a matrix material selected from the group consisting of adhesives, asphalt, composite materials, plastics, elastomers, and hydratable cementitious materials; and

a plurality of individual fiber bodies having an elongated length defined between two opposing ends and comprising at least one synthetic polymer, said individual fiber bodies having surfaces that are substantially free of stress fractures induced by mechanical-flattening of the fiber bodies between opposed rollers, said individual fiber bodies being substantially nonfibrillatable into smaller fiber units after mixing in said matrix material to the extent necessary to achieve substantially uniform dispersal of the fibers therein, and said fiber bodies having a generally quadrilateral cross-sectional profile along said elongated length, thereby having width, thickness, and length dimensions

wherein the average width is no less than 1.0 mm;

wherein the average width is no more than 5.0 mm;

wherein the average thickness is no less than 0.05 mm;

wherein the average thickness is no more than 0.2 mm;

wherein the average length is no less than 20 mm; and

wherein the average length is no more than 75 mm.

2. The matrix composition of claim 1

wherein said fiber bodies have a Young's modulus of elasticity no less than 4 Giga Pascals;

wherein said fiber bodies have a Young's modulus of elasticity no more than 20 Giga Pascals;

wherein said fiber bodies have a tensile strength no less than 400 Mega Pascals;

wherein said fiber bodies have a tensile strength of no more than 1600 Mega Pascals;

wherein said fiber bodies have a minimum load carrying capacity in tension mode no less than 20 Newtons per fiber body;

wherein said fiber bodies have a minimum load carrying capacity in tension mode no greater than 1000 Newtons per fiber body;

wherein said fiber bodies have an average bendability “B” not less than 100 mN −1 *m −2 ; and

wherein said fiber bodies have an average bendability “B” not more than 2500 mN −1 *m −2 ;

said bendability “B” of said fibers being determined in accordance with the formula, B=1/(3·E·I), wherein the moment of inertia “I” for a generally quadrilateral is computed in accordance with the formula, I={fraction ( 1 / 12 )}·w·t 3 , wherein “w” is the average width and “t” is the average thickness of the generally quadrilateral cross-section.

3. The matrix composition of claim 1 wherein, in said plurality of individual fiber bodies, said individual fiber bodies are separated from each other.

4. The matrix composition of claim 1 wherein, in said plurality of individual fiber bodies, said at least one synthetic polymer is selected from the group consisting of polyethylene, polypropylene, polyoxymethylene, poly(vinylidine fluoride), poly(methyl pentene), poly(ethylene-chlorotrifluoroethylene), poly(vinyl fluoride), poly(ethylene oxide), poly(ethylene terephthalate), poly(butylene terephthulene), polyanide, polybutene, and thermotrophic liquid crystal polymers.

5. The matrix composition of claim 1 wherein, in said plurality of individual fiber bodies, said at least one synthetic polymer is polypropylene.

6. The matrix composition of claim 2 wherein said matrix material is a cementitious material.

7. The matrix composition of claim 2 wherein said fiber bodies comprise polypropylene in an amount no less than 75% by weight and said fiber bodies comprise polypropylene in an amount up to 100%.

8. The matrix composition of claim 1 wherein said fiber bodies comprise a blend of at least two polymers or a co-polymer comprising at least two of said polymers.

9. The matrix composition of claim 5 wherein said fiber bodies comprise polypropylene and polyethylene.

10. The matrix composition of claim 2 wherein said matrix material is concrete, and said fibers are embedded in said concrete, said concrete having compressive strength in the range of 15 to 40 MPa wherein the average R e,3 value is between 20 and 60%, said concrete having finishability whereby said embedded fibers do not substantially pop out of said concrete.

11. The matrix composition of claim 1 wherein said fibers are twisted.

12. The matrix composition of claim 1 wherein said matrix material is asphalt.

13. The matrix composition of claim 1 wherein said individual fiber bodies have a variability of thickness or width along the individual fiber body length of no less than 2.5 percent deviation from average thickness or width as the case may be, and wherein said individual fiber bodies have a variability of thickness or width along the individual fiber body length of no greater than 25 percent deviation from the average thickness or width as the case may be.

14. A matrix composition comprising a concrete matrix material and a plurality of individual fiber bodies having an elongated length defined between two opposing ends and comprising at least one synthetic polymer, said individual fiber bodies having surfaces that are substantially free of stress fractures induced by mechanical-flattening of the fiber bodies between opposed rollers, said individual fiber bodies being substantially nonfibrillatable into smaller fiber units after mixing in wet concrete to the extent necessary to achieve substantially uniform dispersal of the fibers therein, and said fiber bodies having a generally quadrilateral cross-sectional profile along said elongated length, thereby having width, thickness, and length dimensions

wherein the average width is no less than 1.0 mm;

wherein the average width is no more than 5.0 mm;

wherein the average thickness is no less than 0.075 mm;

wherein the average thickness is no more than 0.15 mm;

wherein the average length is no less than 20 mm;

wherein the average length is no more than 75 mm;

wherein said fiber bodies have a Young's modulus of elasticity no less than 4 Giga Pascals;

wherein said fiber bodies have a Young's modulus of elasticity no more than 20 Giga Pascals;

wherein said fiber bodies have a tensile strength no less than 400 Mega Pascals;

wherein said fiber bodies have a thensile strength of no more than 1600 Mega Pascals;

wherein said fiber bodies have a minimum load carrying capacity in tension mode no less than 20 Newtons per fiber body;

wherein said fiber bodies have a minimum load carrying capacity in tension mode no greater than 1000 Newtons per fiber body;

wherein said fiber bodies have an average bendability “B” not less than 100 mN −1 *m −2 ; and

wherein said fiber bodies have an average bendability “B” not more than 2500 mN −1 *m −2 ;

said bendability “B” of said fibers being determined in accordance with the formula, B=1/(3·E·I), wherein the moment of inertia “I” for a generally quadrilateral is computed in accordance with the formula, I={fraction (1/12)}·w·t 3 , wherein “w” is the average width and “t” is the average thickness of the generally quadrilateral cross-section.

15. The matrix composition of claim 14 wherein said fiber bodies have an average square area to volume ratio no less than 10.5 mm −1 ; and wherein said fiber bodies have an average square area to volume ratio no more than 42 mm −1 .

16. The matrix composition of claim 14 wherein said fiber bodies are polypropylene.

17. The matrix composition of claim 14 wherein said fibers are comprised of polyethylene and polypropylene.

18. The matrix composition of claim 14 wherein said fibers are present in said concrete matrix material in an amount no less than 0.05% by volume and not greater than 10% by volume.

19. The matrix composition of claim 14 wherein said individual fiber bodies are coated.

20. The matrix composition of claim 14 further comprising a superplasticizer, water reducer, air entrainer, air detrainer, corrosion inhibitor, set accelerator, set retarder, shrinkage reducing admixture, fly ash, silica fume, or a mixture thereof.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Sep 27, 2022
From: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
To: DE NEEF CONSTRUCTION CHEMICALS (US) INC.; VERIFI LLC; GCP APPLIED TECHNOLOGIES INC.
Reel/Frame 061553/0521 →
RELEASE OF SECURITY AGREEMENT RECORDED AT REEL/FRAME NO.: 032159/0384 Recorded Apr 3, 2018
From: GOLDMAN SACHS BANK USA, AS THE COLLATERAL AGENT
To: W.R. GRACE & CO.-CONN.
Reel/Frame 045832/0887 →
CORRECTIVE ASSIGNMENT TO CORRECT THE APPLICATION NUMBER 13353676 PREVIOUSLY RECORDED ON REEL 037701 FRAME 0396. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 17, 2016
From: W. R. GRACE & CO.-CONN.
To: GCP APPLIED TECHNOLOGIES INC.
Reel/Frame 038289/0821 →
SECURITY INTEREST Recorded Mar 7, 2016
From: GCP APPLIED TECHNOLOGIES INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 038012/0407 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 5, 2016
From: W. R. GRACE & CO.-CONN.
To: GCP APPLIED TECHNOLOGIES INC.
Reel/Frame 037701/0396 →
RELEASE OF SECURITY INTEREST Recorded Feb 2, 2016
From: GOLDMAN SACHS BANK USA
To: W. R. GRACE & CO.-CONN.
Reel/Frame 037681/0323 →
SECURITY AGREEMENT Recorded Feb 4, 2014
From: W.R. GRACE & CO.-CONN.
To: GOLDMAN SACHS BANK USA, AS THE COLLATERAL AGENT
Reel/Frame 032159/0384 →