IP Library Granted Patent US 7,077,985
Granted Patent B2
US 7,077,985 · App. 10/389,353 · Granted Jul 18, 2006

Injection molding of lens

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Quick Facts
Patent No.
US 7,077,985
App. No.
10/389,353
Granted
Jul 18, 2006
Kind
B2
Abstract

A flat or curved photochromic laminate structure and a plastic photochromic lens blank can be produced in a simple and efficient manner from relatively low-cost polymeric sheet materials. These laminates can be used to provide goggles, face shields, windows, window coverings, skylights, and optical lenses having efficient, uniform and high quality photochromic properties. The use of a polyesterurethane as the binder for the photochromic material has been found to improve the performance of the photochromic material. There may be a desire to have a protective exterior layer (e.g., an abrasion resistant layer) in combination with the lens system, but that may be provided in various methods. In the case of using the laminate in a goggle application, the laminate may be hard coated on one or both outer surfaces with an abrasion resistant coating, antireflective coating, and/or an anti-fog hard coating.

Claims (50)

1. A method of forming an ophthalmic lens comprising:

providing a mold having a concave portion and a convex portion, said mold also having a portion for forming an add corridor in a multifocal lens;

providing a laminate functional film;

placing said laminate functional film in said mold, wherein prior to the placing of said laminate functional film in said mold, said laminate functional film has been pre-shaped to a shape shallower than a surface in said mold into which said laminate functional film is being placed;

injecting a molten thermoplastic into said mold at a location adjacent to said portion for forming said add corridor;

maintaining a temperature of said mold within a range of approximately 270–290 degrees F. during the injection of said molten thermoplastic;

allowing said thermoplastic to cool; and,

removing the resulting ophthalmic lens having said laminate functional film from said mold.

2. A method according to claim 1 , wherein providing a laminate functional film includes providing a photochromic functional film.

3. A method according to claim 2 , wherein providing a photochromic functional film includes providing a photochromic layer having a polyester urethane binder and a photochromic compound, the photochromic layer adhered to one surface of a polymeric layer comprising a polycarbonate resin or a polysulfone resin.

4. A method according to claim 1 , wherein prior to placing said laminate functional film in said mold, the laminate functional film is preformed so that it is within the range of more than zero diopters and less than 4 diopters in curvature.

5. A method according to claim 1 , wherein prior to placing said laminate functional film in said mold, said laminate functional film is pretreated using at least one of the following pretreatments: heat, vacuum and dessication.

6. A method according to claim 1 , wherein the injecting of a molten thermoplastic into said mold includes injecting molten polycarbonate.

7. A method according to claim 1 , wherein the injecting of a molten thermoplastic into said mold includes injecting molten polysulfone.

8. A method of forming an ophthalmic lens comprising:

providing a mold having a concave portion and a convex portion said mold also having a segment for forming a stepped multifocal lens;

providing a laminate functional film;

placing said laminate functional film in said mold;

injecting a molten thermoplastic into said mold, wherein said molten thermoplastic is injected into said mold at a location as distant from said segment as practicable and wherein an edge of said segment encounters said molten thermoplastic prior to a remaining portion of said segment;

maintaining a temperature of said mold within a range of approximately 270–290 degrees F. during the injection of said molten thermoplastic;

allowing said thermoplastic to cool; and,

removing the resulting ophthalmic lens having said laminate functional film from said mold.

9. A method according to claim 8 , wherein providing a laminate functional film includes providing a photochromic functional film.

10. A method according to claim 9 , wherein providing a photochromic functional film includes providing a photochromic layer having a polyester urethane binder and a photochromic compound, the photochromic layer adhered to one surface of a polymeric layer comprising a polycarbonate resin or a polysulfone resin.

11. A method according to claim 8 , wherein prior to placing said laminate functional film in said mold, the laminate functional film is preformed so that it is within the range of 4 to zero diopters in curvature.

12. A method according to claim 8 , wherein prior to placing said laminate functional film in said mold, said laminate functional film is pretreated using at least one of the following pretreatments: heat, vacuum and dessication.

13. A method according to claim 8 , wherein the injecting of a molten thermoplastic into said mold includes injecting molten polycarbonate.

14. A method according to claim 8 , wherein the injecting of a molten thermoplastic into said mold includes injecting molten polysulfone.

15. A method of forming an ophthalmic lens comprising:

providing a mold having a concave portion and a convex portion, said mold also having a portion for forming an add corridor in a multifocal lens;

providing a laminate functional film;

placing said laminate functional film in said mold, wherein prior to the placing of said laminate functional film in said mold, said laminate functional film has been pre-shaped to a shape shallower than a surface in said mold into which said laminate functional film is being placed;

injecting a molten thermoplastic into said mold at a location adjacent to said portion for forming said add corridor;

maintaining a temperature of said mold within a predetermined temperature range during the injection of said molten thermoplastic;

allowing said thermoplastic to cool; and,

removing the resulting ophthalmic lens having said laminate functional film from said mold.

16. A method according to claim 15 , wherein providing a laminate functional film includes providing a photochromic functional film.

17. A method according to claim 16 , wherein providing a photochromic functional film includes providing a photochromic layer having a polyester urethane binder and a photochromic compound, the photochromic layer adhered to one surface of a polymeric layer comprising a polycarbonate resin or a polysulfone resin.

18. A method according to claim 15 , wherein prior to placing said laminate functional film in said mold, the laminate functional film is preformed so that it is within the range of more than zero diopters and less than 4 diopters in curvature.

19. A method according to claim 15 , wherein prior to placing said laminate functional film in said mold, said laminate functional film is pretreated using at least one of the following pretreatments: heat, vacuum and dessication.

20. A method according to claim 15 , wherein the injecting of a molten thermoplastic into said mold includes injecting molten polycarbonate.

21. A method according to claim 15 , wherein the injecting of a molten thermoplastic into said mold includes injecting molten polysulfone.

22. A method according to claim 15 , wherein said multifocal lens is a progressive multifocal lens.

23. A method according to claim 15 , wherein said multifocal lens is an aspheric multifocal lens.

24. A method according to claim 1 , wherein said multifocal lens is a progressive multifocal lens.

25. A method according to claim 1 , wherein said multifocal lens is an aspheric multifocal lens.

26. A method according to claim 1 , wherein providing a laminate functional film includes providing a polarizing film.

27. A method according to claim 15 , wherein providing a laminate functional film includes providing a polarizing film.

28. A method according to claim 2 , wherein providing a photochromic functional film includes providing a photochromic layer having a polyester urethane binder.

29. A method according to claim 16 , wherein providing a photochromic functional film includes providing a photochromic layer having a polyester urethane binder.

Assignments (21)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2022
From: VISION EASE, LP
To: HOYA OPTICAL LABS OF AMERICA, INC.
Reel/Frame 059825/0497 →
RELEASE OF SECURITY INTEREST Recorded Aug 1, 2017
From: ANTARES CAPITAL LP
To: VISION EASE, LP
Reel/Frame 043402/0306 →
CHANGE OF NAME Recorded Nov 23, 2015
From: INSIGHT EQUITY A.P. X, LP
To: VISION EASE, LP
Reel/Frame 037154/0842 →
RELEASE OF SECURITY INTEREST Recorded Oct 30, 2015
From: ANTARES CAPITAL LP, AS AGENT
To: VISION EASE, LP (F/N/A INSIGHT EQUITY A.P. X, LP)
Reel/Frame 037009/0180 →
SECURITY INTEREST Recorded Oct 27, 2015
From: VISION EASE, LP (D/B/A VISION-EASE LENS)
To: ANTARES CAPITAL LP, AS ADMINISTRATIVE AGENT
Reel/Frame 036981/0268 →
ASSIGNMENT OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Sep 15, 2015
From: GENERAL ELECTRIC CAPITAL CORPORATION, AS RETIRING AGENT
To: ANTARES CAPITAL LP, AS SUCCESSOR AGENT
Reel/Frame 036616/0161 →
SECURITY INTEREST Recorded Sep 23, 2014
From: INSIGHT EQUITY A.P. X, LP (D/B/A VISION-EASE LENS)
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS AGENT
Reel/Frame 033810/0209 →
RELEASE OF SECURITY INTEREST Recorded Sep 23, 2014
From: PNC BANK, NATIONAL ASSOCIATION, AS REVOLVING AGENT
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 033810/0185 →
RELEASE OF SECURITY INTEREST Recorded Sep 23, 2014
From: PNC BANK, NATIONAL ASSOCIATION, AS TERM LOAN AGENT
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 033810/0143 →
SECURITY AGREEMENT Recorded Nov 8, 2012
From: INSIGHT EQUITY A.P. X, LP (D/B/A VISION-EASE LENS)
To: PNC BANK, NATIONAL ASSOCIATION, AS TERM LOAN AGENT
Reel/Frame 029261/0912 →
SECURITY AGREEMENT Recorded Nov 8, 2012
From: INSIGHT EQUITY A.P. X, LP (D/B/A VISION-EASE LENS)
To: PNC BANK, NATIONAL ASSOCIATION, AS REVOLVING AGENT
Reel/Frame 029261/0832 →
RELEASE OF SECURITY INTEREST Recorded Oct 30, 2012
From: REGIMENT CAPITAL SPECIAL SITUATIONS FUND IV, L.P.
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 029209/0926 →
RELEASE OF SECURITY INTEREST Recorded Oct 30, 2012
From: ORIX CORPORATE CAPITAL INC. (F/K/A ORIX FINANCE CORP.)
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 029209/0771 →
SECURITY AGREEMENT Recorded Mar 28, 2008
From: INSIGHT EQUITY A.P. X, LP
To: REGIMENT CAPITAL SPECIAL SITUATIONS FUND IV, L.P., AS AGENT
Reel/Frame 020710/0785 →
SECURITY AGREEMENT Recorded Dec 20, 2007
From: INSIGHT ESQUITY A.P. X, LP
To: ORIX FINANCE CORP.
Reel/Frame 020270/0664 →
RELEASE OF SECURITY INTEREST Recorded Dec 20, 2007
From: PNC BANK, NATIONAL ASSOCIATION
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 020270/0654 →
CORRECTION ASSIGNOR AND ANSSIGNEE ON PREVIOUS RECORDATION (SEE ENCLOSED COPY) AT REEL/FRAME 015370/0722 (PATENT AND PATENT APPLICATION SECURITY AGREEMENT) Recorded Nov 29, 2004
From: INSIGHT EQUITY A.P.X., LP
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 015409/0356 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 12, 2004
From: VISION-EASE LENS, INC.; BMC INDUSTRIES, INC.
To: INSIGHT EQUITY A.P.X., L.P.
Reel/Frame 015370/0561 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 12, 2004
From: PNC BANK, NATIONAL ASSOCIATION
To: INSIGHT EQUITY A.P. X, LP
Reel/Frame 015370/0722 →
TERMINATION OF SECURITY INTEREST Recorded Nov 12, 2004
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: VISION-EASE LENS, INC.
Reel/Frame 015370/0483 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2003
From: MAKI, ALAN D.; WOELFLE, ERIC J.; KROULIK, DARRELL B.; MORAVEC, THOMAS J.; TRAVNICEK, EDWARD A.; HAGE, MARTIN L.
To: VISION-EASE LENS, INC.
Reel/Frame 013838/0459 →