Resinous compositions, method of manufacture thereof and articles fabricated from the composition
View Patent ↗Disclosed are resinous compositions with excellent balance of impact, heat, flow and environmental stress crack resistance, comprising (i) at least one aromatic polycarbonate, (ii) at least one low molecular weight hydrocarbon resin derived from petroleum C 5 –C 9 feedstock and (iii) optionally a second thermoplastic resin which is not polycarbonate resin, (iv) optionally a rubber modified graft copolymer, and (v) optionally a polymeric or non-polymeric organic phosphorus species. Also disclosed is a method for the manufacture of the compositions and for the manufacture of articles thereof.
1. A polycarbonate resin composition comprising:
a) at least one aromatic polycarbonate, wherein the polycarbonate is a blend of a first polycarbonate not comprising siloxane units and as a second polycarbonate a linear multiblock copolymer of bisphenol A polycarbonate and polydimethylsiloxane;
b1) about between 4 wt % and about 30 wt % of a second thermoplastic resin comprising structural units derived from one or more monomers selected from the group consisting of vinyl aromatic monomers, monoethylenically unsaturated nitrile monomers, and C 1 –C 12 alkyl (meth)acrylate monomers;
b2) about between 5 wt % and about 30 wt % of one rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase; and
c) about 1 to 10 wt. % of at least one low molecular weight partially or fully hydrogenated hydrocarbon resin derived from petroleum C 9 monomer feedstock; wherein all amounts are based on the sum of the weights of components a–c inclusive of the composition.
2. The composition of claim 1 wherein the hydrocarbon resin has a numbered average molecular weight of less than 5,000.
3. The composition of claim 1 wherein the low molecular weight hydrocarbon resin derived from petroleum C 9 feedstock has a numbered average molecular weight of less than 2,500.
4. The composition of claim 1 wherein the second thermoplastic resin comprises structural units derived from styrene and acrylonitrile; and the rubber modified graft copolymer rubber phase comprises a polybutadiene or poly (styrene-butadiene) rubber and the rigid thermoplastic phase comprises a styrene-acrylonitrile copolymer.
5. An article fabricated from the composition of claim 1 .
6. The composition of claim 1 further comprising between about 0.5 wt % and about 15 wt %, based on the weight of the components a–c of the composition, of at least one polymeric or non-polymeric organic phosphorus species selected from the group consisting of aromatic or non-aromatic phosphate esters, thiophosphate esters, phosphonate esters, thiophosphonate esters, phosphinate esters, thiophosphinate esters, phosphines, triphenylphosphine, phosphine oxides, triphenylphosphine oxide, tris(2-cyanoethyl)phosphine oxide, thiophosphine oxides, and phosphonium salts.
7. A polycarbonate resin composition comprising:
a) at least one aromatic polycarbonate;
b) about between 0 wt % and about 50 wt % of a second thermoplastic resin comprising structural units derived from one or more monomers selected from the group consisting of vinyl aromatic monomers, monoethylenically unsaturated nitrile monomers, and C 1 –C 12 alkyl (meth)acrylate monomers; the second thermoplastic resin; and
c) about 1 to 10 wt. % of at least one low molecular weight partially or fully hydrogenated hydrocarbon resin derived from petroleum C 9 monomer feedstock; wherein all amounts are based on the sum of the weights of components a–c inclusive of the composition,
wherein the polycarbonate comprises a blend of a first polycarbonate not comprising siloxane units and as a second polycarbonate a linear multiblock copolymer of bisphenol A polycarbonate and polydimethylsiloxane.
8. An article fabricated from the composition of claim 7 .
9. The composition of claim 7 , further comprising between about 0.5 wt % and about 15 wt %, based on the weight of the components a–c of the composition, of at least one polymeric or non-polymeric organic phosphorus species selected from the group consisting of aromatic or non-aromatic phosphate esters, thiophosphate esters, phosphonate esters, thiophosphonate esters, phosphinate esters, thiophosphinate esters, phosphines, triphenylphosphine, phosphine oxides, triphenylphosphine oxide, tris(2-cyanoethyl)phosphine oxide, thiophosphine oxides, and phosphonium salts.
10. A method for improving polycarbonate resin composition performance comprising blending:
a) at least one aromatic polycarbonate, wherein the polycarbonate is a blend of a first polycarbonate not comprising siloxane units and as a second polycarbonate a linear multiblock copolymer of bisphenol A polycarbonate and polydimethylsiloxane;
b1) about between 4 wt % and about 30 wt % of a second thermoplastic resin which is not a polycarbonate;
b2) about between 5 wt % and about 30 wt % of one rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase;
c) about 1 to 1.0 wt. % of at least one partially or fully hydrogenated low molecular weight hydrocarbon resin derived from petroleum C 9 monomer feedstock;
wherein all amounts are based on the weight of components a–c inclusive of the composition.
11. The method of claim 10 wherein the hydrocarbon resin has a numbered average molecular weight of less than 5,000.
12. The method of claim 10 wherein the second thermoplastic resin comprises structural units derived from styrene and acrylonitrile; and the rubber modified graft copolymer rubber phase comprises a polybutadiene or poly (styrene-butadiene) rubber and the rigid thermoplastic phase comprises a styrene-acrylonitrile copolymer.
13. The method of claim 10 wherein the low molecular weight hydrocarbon resin derived from petroleum C 9 feedstock has a numbered average molecular weight of less than 2,500.
14. The method of claim 10 further comprising between about 0.5 wt % and about 15 wt %, based on the weight of the components a–c of the composition, of at least one polymeric or non-polymeric organic phosphorus species selected from the group consisting of aromatic or non-aromatic phosphate esters, thiophosphate esters, phosphonate esters, thiophosphonate esters, phosphinate esters, thiophosphinate esters, phosphines, triphenylphosphine, phosphine oxides, triphenylphosphine oxide, tris(2-cyanoethyl)phosphine oxide, thiophosphine oxides, and phosphonium salts.