IP Library Granted Patent US 6,875,131
Granted Patent B2
US 6,875,131 · App. 10/391,823 · Granted Apr 5, 2005

Multi-layer golf ball

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Quick Facts
Patent No.
US 6,875,131
App. No.
10/391,823
Granted
Apr 5, 2005
Kind
B2
Abstract

A golf ball including a solid core having an outer diameter of less than about 1.59 inches; an outer cover layer having a first material hardness and including a urethane elastomer formed from a castable reactive liquid material; and a casing disposed between the core and the cover layer, the casing including polyurea and having an outer diameter of between about 1.59 inches and about 1.64 inches and a second material hardness of between about 30 and about 70 Shore D; wherein a ratio of the second material hardness to the first material hardness is greater than 1.5.

Claims (26)

1. A golf ball comprising:

a solid core having an outer diameter of less than about 1.59 inches and comprising polybutadiene and a cis-to-trans catalyst such that, upon curing, the core has a first amount of trans-polybutadiene at an interior location and a second amount of trans-polybutadiene at a surface location, the first amount being at least about 6 percent less than the second amount;

an outer cover layer having a first material hardness and comprising a elastomer formed from a castable reactive liquid material; and

a casing disposed between the core and the cover layer, the casing comprising polyurea and having an outer diameter of between about 1.59 inches and about 1.64 inches and a second material hardness of between about 30 and about 70 Shore D;

wherein a ratio of the second material hardness to the first material hardness is greater than 1.5.

2. The golf ball of claim 1 , wherein the first material hardness is less than about 45 Shore D.

3. The golf ball of claim 2 , wherein the first material hardness is between about 25 and about 40 Shore D.

4. The golf ball of claim 1 , wherein the second material hardness is between about 50 and about 65 Shore D.

5. The golf ball of claim 1 , wherein at least one of the casing and the outer cover layer has a thickness of less than about 0.05 inches.

6. The golf ball of claim 5 , wherein at least one of the casing and the outer cover layer has a thickness of between about 0.02 inches and about 0.04 inches.

7. The golf ball of claim 1 , wherein the core has a vinyl polybutadiene isomer content of less than about 7 percent.

8. The golf ball of claim 1 , wherein the elastomer is a polyurethane composition comprising the reaction product of at least one polyisocyanate, a polyol, and at least one curing agent.

9. The golf ball of claim 1 , wherein the core has a first hardness at a point in the interior and a surface having a second hardness differing from the first hardness by greater than 10 percent.

10. The golf ball of claim 1 , wherein the core comprises a polybutadiene having a Mooney viscosity of between about 40 and about 80, a resilience index of at least about 50, or a dynamic stiffness of less than about 50,000 N/m at −50° C.

11. The golf ball of claim 1 , wherein the golf ball has a dimple coverage of greater than about 75 percent.

12. The golf ball of claim 1 , wherein the casing further comprises ionic copolymers of ethylene and an unsaturated monocarboxylic acid; vinyl resins; polyolefins; polyurethanes; polyamides; thermoplastic and thermoset resins; metallocenes; acrylic resins; or thermoplastic polyesters.

13. The golf ball of claim 1 , wherein the casing material hardness is between about 40 and about 70 Shore D and the outer cover layer material hardness is less than about 40 Shore D.

14. The golf ball of claim 1 , wherein at least one of the core, casing, and cover layer are cast, reaction injection molded, liquid injection molded, injection molded, or a mixture thereof.

15. A golf ball comprising:

a core having an outer diameter of less than about 1.59 inches and comprising a polybutadiene having a vinyl content of less than about 7 percent and comprising a cis-to-trans catalyst such that, upon curing, the core has a first amount of trans-polybutadiene at an interior location and a second amount of trans-polybutadiene at a surface location, the first amount being at least about 6 percent less than the second amount;

an outer cover layer having a first material hardness and formed from a polyurethane composition comprising the reaction product of at least one polyisocyanate, a polyol, and at least one curing agent; and

a casing disposed between the core and the cover layer, the casing comprising polyurea and having an outer diameter of between about 1.59 inches and about 1.64 inches and a second material hardness of between about 30 and about 70 Shore D;

wherein a ratio of the second material hardness to the first material hardness is greater than 1.5 and the golf ball has a moment of inertia of less than about 83 g-cm 2 .

16. The golf ball of claim 15 , wherein at least one of the casing and the outer cover layer has a thickness of less than about 0.05 inches.

17. The golf ball of claim 15 , wherein at least one of the casing and the outer cover layer has a thickness of between about 0.02 inches and about 0.04 inches.

18. The golf ball of claim 15 , wherein at least one of the casing or cover layer are cast, reaction injection molded, liquid injection molded, injection molded, or a mixture thereof.

Assignments (3)
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027331/0725) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039938/0923 →
SECURITY AGREEMENT Recorded Dec 7, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027331/0725 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 19, 2003
From: CAVALLARO, CHRISTOPHER; WU, SHENSHEN
To: ACUSHNET COMPANY
Reel/Frame 013899/0112 →