IP Library Granted Patent US 6,878,786
Granted Patent B2
US 6,878,786 · App. 10/402,303 · Granted Apr 12, 2005

Process for the polymerization of olefins

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Quick Facts
Patent No.
US 6,878,786
App. No.
10/402,303
Granted
Apr 12, 2005
Kind
B2
Abstract

Process for the polymerization of olefins comprising contacting olefins under polymerization conditions in the presence of a catalyst system comprising the product obtained by contacting: (A) at least one transition metal organometallic compound, pyrolidyl bis(η-cyclopentadienyl)methylzirconium being excluded, and (B) an organometallic compound obtained by contacting: (a) a Lewis base having formula (I):  wherein R a , R b , R c and R d , equal to or different from each other, are selected from the group consisting of hydrogen, halogen, linear or branched, saturated or unsaturated, C 1 -C 10 alkyl, C 6 -C 20 aryl, C 7 -C 20 arylalkyl and C 7 -C 20 alkylaryl groups; with b) a Lewis acid of formula (II) MtR 1 3   (II)  wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R 1 , equal to or different from each other, are selected from the group consisting of halogen, halogenated C 6 -C 20 aryl and halogenated C 7 -C 20 alkylaryl groups; and (C) optionally an alkylating agent.

Claims (12)

1. A process for the polymerization of olefins comprising contacting one or more olefins under polymerization conditions in the presence of a catalyst system comprising the product obtained by contacting:

(A) at least one transition metal organometallic compound, pyrolidyl bis(η-cyclopentadienyl)methylzirconium being excluded, and

(B) an organometallic compound obtained by contacting:

(a) a Lewis base having formula (I):

 wherein R a , R b , R c and R d , equal to or different from each other, are selected from the group consisting of hydrogen, halogen, linear or branched, saturated or unsaturated, C 1 -C 10 alkyl, C 6 -C 20 aryl, C 7 -C 20 arylalkyl and C 7 -C 20 alkylaryl groups, optionally containing O, S, N, P, Si or halogen atoms, or two or more adjacent substituents R a , R b , R c and R d form one or more C 4 -C 7 rings, optionally containing O, S, N, P or Si atoms, that can bear substituents; with

b) a Lewis acid of formula (II)

MtR 1 3   (II)

 wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R 1 , equal to or different from each other, are selected from the group consisting of halogen, halogenated C 6 -C 20 aryl and halogenated C 7 -C 20 alkylaryl groups; two R 1 groups optionally form with the metal Mt one condensed ring; and

(C) optionally an alkylating agent.

2. The process according to claim 1 wherein ethylene is homopolymerized or copolymerized with a comonomer of formula CH 2 ═CHR′, wherein R′ is a linear, branched or cyclic C 1 -C 20 alkyl radical, or with a cycloolefin.

3. The process according to claim 2 wherein propylene is homopolymerized.

4. The process according to claim 2 for the preparation of elastomeric copolymers of ethylene with α-olefins of formula CH 2 ═CHR″, wherein R″ is a C 1 -C 10 alkyl radical, optionally contain minor proportions of units deriving from polyenes.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0705 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0856 →
SECURITY AGREEMENT Recorded Aug 4, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; BASELL POLYOLEFIN GMBH; LYONDELL CHEMICAL COMPANY; EQUISTAR CHEMICALS, L.P.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 021354/0708 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS AND PATENT APPLICATIONS Recorded Mar 26, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; EQUISTAR CHEMICALS. LP.; LYONDELL CHEMICAL COMPANY; LYONDELL CHEMICAL TECHNOLOGY, L.P.; LYONDELL PETROCHEMICAL COMPANY; NATIONAL DISTILLERS AND CHEMICAL CORPORATION; OCCIDENTAL CHEMICAL CORPORATION; OLIN CORPORATION; QUANTUM CHEMICAL CORPORATION; BASELL POLYOLEFIN GMBH
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 020704/0562 →