Photothermographic material
View Patent ↗A photothermographic material comprising a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for a silver ion and a binder on one surface of a support, wherein a silver behenate-content of the non-photosensitive organic silver salt is 40 to 70 mol %, and the photothermographic material comprises a compound that can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 1 electron, one of during and after a subsequent reaction.
1. A photothermographic material comprising: a support; and a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for a silver ion and a binder disposed on one surface of the support, wherein a silver behenate-content of the non-photosensitive organic silver salt is 40 to 70 mol %, and the photothermographic material comprises a compound that can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 1 electron, during or after a subsequent reaction;
wherein the compound that can be one-electron-oxidized to provide the one-electron oxidation product is selected from compounds of following 1 to 5:
(1) a compound that can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 2 electron, one of during and after a subsequent bond cleavage reaction;
(2) a compound that has at least 2 adsorbable groups to the silver halide and can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 1 electron, one of during and after a subsequent bond cleavage reaction;
(3) a compound that can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 1 electron after a subsequent bond formation;
(4) a compound that can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 1 electron after a subsequent ring cleavage reaction; and
(5) a compound represented by X—Y, in which X represents a reducing group and Y represents a leaving group, and convertable by one-electron-oxidizing the reducing group to a one-electron oxidation product, which can be converted into an X radical by eliminating the leaving group in a subsequent X—Y bond cleavage reaction, 1 electron being released from the X radical.
2. The photothermographic material according to claim 1 , wherein said compounds of 1 to 5 have a sensitizing dye moiety.
3. The photothermographic material according to claim 1 , wherein said compounds of 1 and 3 to 5 have a adsorbable group to the silver halide.
4. The photothermographic material according to claim 1 , wherein said photothermographic material comprises polyvinylbutyral as said binder, a weight ratio of polyvinylbutyral to the total weight of the binder contained in a photosensitive layer being 50 to 100 weight %.
5. The photothermographic material according to claim 4 , wherein an amount of a residual solvent of methyl ethyl ketone is 0.1 to 150 mg/m 2 .
6. The photothermographic material according to claim 1 , wherein said photothermographic material comprises at least one of a compound represented by the following g formula (PO) and a compound represented by the following formula (M):
Q-(Y) n —C(Z 1 )(Z 2 )X Formula (PO)
wherein Q represents a heterocyclic group; Y represents a divalent linking group; n represents 0 or 1; Z 1 and Z 2 each represent a halogen atom; and X represents a hydrogen atom or an electron-withdrawing group:
wherein Z represents an atomic group forming a 5- or 6-membered aromatic heterocycle; and R represents a hydrogen atom, an alkyl group, an aralkyl group, an alkoxy group or an aryl group.
7. The photothermographic material according to claim 6 , wherein said photothermographic material comprises a compound represented by the following formula (PR):
wherein R 1 represents a hydroxyl group or a metal salt thereof; R 2 represents an alkyl group or an aryl group; and X represents an electron-withdrawing group or forms a ring containing an electron-withdrawing group with R 2 .
8. The photothermographic material according to claim 1 , wherein said photothermographic material comprises a compound represented by the following formula (T) and a heteroatom-containing macrocyclic compound:
wherein Ar represents an aromatic hydrocarbon group or an aromatic heterocyclic group; T 31 represents a divalent linking group comprising an aliphatic hydrocarbon group; J 31 represents a divalent linking group comprising an oxygen atom, a sulfur atom or a nitrogen atom; Ra, Rb, Rc and Rd each represent a hydrogen atom, an acyl group, an aliphatic hydrocarbon group, an aryl group or a heterocyclic group; alternatively, Ra and Rb, Rc and Rd, Ra and Rc, and Rb and Rd may bond together to form a nitrogen-containing heterocyclic group, respectively; M 31 represents an ion necessary to neutralize a charge of the compound; and k31 represents a number of ions necessary.
9. The photothermographic material according to claim 8 , wherein said compounds of 1 to 5 have a sensitizing dye moiety.
10. The photothermographic material according to claim 8 , wherein said compounds of 1 and 3 to 5 have a adsorbale group to the silver halide.
11. The photothermographic material according to claim 8 , wherein said photothermographic material comprises polyvinylbutyral as said binder, a weight ratio of polyvinylbutyral to the total weight of the binder contained in a photosensitive layer being 50 to 100% by weight.
12. The photothermographic material according to claim 11 , wherein an amount of a residual solvent of methyl ethyl ketone is 0.1 to 150 mg/m 2 .