Granted Patent B2

US 7,034,086 · App. 10/403,442 · Granted Apr 25, 2006

Abstract

Claims (51)

1. A crosslinking composition comprising a compound having the structure of Formula I:

wherein Z is a hydrogen, an alkyl of 1 to about 18 carbon atoms, an aryl of about 6 to about 24 carbon atoms, an aralkyl of about 7 to about 24 carbon atoms, or —NR 2 R 2 ;

each R 2 is independently hydrogen, an alkyl, aryl or an aralkyl of 1 to about 18 carbon atoms or R 3 ;

wherein R 3 is —CHROR 1 , or

wherein R is alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl, having from 1 to about 24 carbon atoms; R 1 is a hydrogen, alkyl, aryl, aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; and wherein the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure;

B is a residue of a poly(alkylaldehyde) with n aldehyde groups;

n is an integer of 2 to about 8;

A is an amino moiety derived from the group consisting of guanamines and melamines.

2. The composition of claim 1 , wherein said compound having the Formula I is an oligomer having an number average molecular weight of from about 500 to about 5000.

3. A crosslinking composition comprising a compound having the structure of Formula II:

wherein Z is a hydrogen, an alkyl of 1 to about 18 carbon atoms, an aryl of 6 to about 24 carbon atoms, an aralkyl of 7 to about 24 carbon atoms, or —NHR 2 ;

each R 2 is independently hydrogen, an alkyl, aryl or an aralkyl of 1 to about 18 carbon atoms or R 3 ;

wherein R 3 is —CHROR 1 , or

wherein R is alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; R 1 is a hydrogen, alkyl, aryl, aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; and wherein the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure;

B is a residue of a poly(alkylaldehyde) with n aldehyde groups;

n is an integer of 2 to about 8;

A is an amino moiety derived from the group consisting of guanamines and melamines.

4. The composition of claim 3 , wherein said compound having the Formula II is in the form of an oligomer having an number average molecular weight of from about 500 to about 5000.

5. The crosslinking composition of claim 3 , wherein R 1 is derived from an alcohol selected from the group consisting of: methanol, ethanol, propanol, isopropanol, butanol, isobutanol, cyclohexanol, phenol, benzyl alcohol, monoalkyl ether of ethylene or propylene glycol and mixtures thereof.

6. The crosslinking composition of claim 3 , wherein Z is —NHR 2 , an alkyl of 1 to about 8 carbon atoms or an aryl of 6 to about 24 carbon atoms.

7. The crosslinking composition of claim 3 , wherein B is derived from glutaraldehyde, the reaction products of crotonaldehyde and polyhydritic alcohols or adducts and polymers of α,β-unsaturated aldehydes.

8. The crosslinking composition of claim 6 , wherein R is C 1 to C 8 alkyl and R 1 is a C 1 to C 8 alkyl or a C 1 to C 8 alkoxyalkyl.

9. The crosslinking composition of claim 1 , wherein about 10% to about 90% of the R 2 groups on a molar basis are —CHROR 1 .

10. The crosslinking composition of claim 3 , wherein R 1 is derived from methanol, butanol, monomethyl ether of ethylene glycol or monomethyl ether of propylene glycol.

11. A crosslinking composition comprising a compound having the structure of Formula III:

wherein Z is a hydrogen, an alkyl of 1 to about 18 carbon atoms, an aryl of 6 to about 24 carbon atoms, an aralkyl of 7 to about 24 carbon atoms, or —NR 2 R 2 ;

each R 2 is independently hydrogen, an alkyl, aryl or an aralkyl of 1 to about 24 carbon atoms or R 3 ;

R 3 is —CHROR 1 ; wherein R 1 is hydrogen, alkyl, aryl, aralkyl, or an alkaryl having from 1 to about 24 carbon atoms; and R is ethyl, or an aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms;

wherein the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure and with the provisos that at least some R 1 groups are derived from a mixture of two or more alcohols and at least one R 2 is R 3 .

12. A crosslinking composition comprising the structure of formula:

wherein Z is a hydrogen, an alkyl of 1 to about 18 carbon atoms, an aryl of 6 to about 24 carbon atoms, an aralkyl of 7 to about 24 carbon atoms, or —NHR 2 ;

each R 2 is independently hydrogen, an alkyl, aryl or an aralkyl of 1 to about 24 carbon atoms or R 3 ;

R 3 is —CHROR 1 ; wherein R 1 is hydrogen, alkyl, aryl, aralkyl or an alkaryl having from 1 to about 24 carbon atoms; and R is ethyl, or an aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms;

wherein the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure and with the provisos that at least some R 1 groups are derived from a mixture of two or more alcohols and at least one R 2 is R 3 .

13. The crosslinking composition of claim 12 , wherein R is ethyl.

14. The crosslinking composition of claim 13 , wherein R 1 is derived from two or more alcohols selected from the group consisting of: methanol, ethanol, propanol, isopropanol, butanol, isobutanol, cyclohexanol, phenol, benzyl alcohol, monoalkyl ether of ethylene or propylene glycol and mixtures thereof.

15. The crosslinking composition of claim 13 , wherein about 10% to about 90% of the R 2 groups on a molar basis are R 3.

16. The crosslinking composition of claim 13 , wherein Z is -NHR 2 , an alkyl of 1 to 8 carbon atoms or an aryl of 6 to 24 carbon atoms.

17. The crosslinking composition of claim 16 , wherein R 1 is a C 1 to C 8 alkyl or a C 1 to C 8 alkoxyalkyl.

18. A crosslinking composition comprising an oligomer compound having the Formula IV:

wherein Z is hydrogen, an alkyl of 1 to about 18 carbon atoms, an aryl of 6 to about 24 carbon atoms, an aralkyl of 7 to about 20 carbon atoms, or −NR 2 R 2 ;

each R 2 is independently hydrogen, an alkyl, aryl or an aralkyl of 1 to about 24 carbon atoms or R 3;

R 3 is −CHROR 1 ; wherein R 1 is hydrogen, an alkyl, aryl, aralkyl, or an alkaryl having from 1 to about 24 carbon atoms and R is ethyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to 24 carbon atoms;

n is 2 to about 50;

wherein the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure and with the provisos that at least some R groups are derived from a mixture of two or more alcohols and at least one R 2 is R 3 .

19. A crosslinking composition comprising an oligomer compound having the Formula V:

wherein Z is a hydrogen, an alkyl of 1 to about 18 carbon atoms, an aryl of 6 to about 24 carbon atoms, an aralkyl of 7 to about 24 carbon atoms, or —NR 2 R 2 ;

each R 2 is independently hydrogen, an alkyl, aryl or an aralkyl of 1 to about 18 carbon atoms or R 3 ;

R 3 is —CHROR 1 ; wherein R 1 is hydrogen, an alkyl, aryl, aralkyl, or an alkaryl, having from 1 to about 24 carbon atoms and R is ethyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl, having from 1 to about 24 carbon atoms;

n is 2 to about 50;

wherein the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure and with the provisos that at least some R 1 groups are derived from a mixture of two or more alcohols and at least one R 2 is R 3 .

Assignments (10)