Polymer welding using ferromagnetic particles
View Patent ↗An apparatus and method for bonding polymeric materials is provided. The apparatus and method both utilize ferromagnetic materials in association with the polymeric materials to be bonded together. The polymeric materials, and the ferromagnetic material, are placed within a magnetic field, which causes hysterisis losses in the magnetic field, and thus elevation in the temperature of both the ferromagnetic material and the polymeric materials to the point where the polymeric materials melt and fuse together. The ferromagnetic materials only rise in temperature to their Curie temperatures, at which point the hysterisis losses cease, and the polymeric material stops being heated. Removing the electromagnetic field allows for cooling and fusing. An interface composition may also be placed between the two polymeric materials to be bonded.
1. A method of bonding multiple polymeric elements to form a catheter sized for insertion into a lumen of a body, comprising:
providing a molding device having ferromagnetic particles distributed therethrough, the molding device comprising an inner mandrel sized to form the shaft of the catheter and an outer shell sized to form a balloon of the catheter;
placing a first polymeric element into operative association on the mandrel to form the shaft and placing a second polymeric element into operative association inside the outer shell to form the balloon on the shaft;
placing an interface composition into operative association with the multiple polymeric elements, the interface composition containing the first polymeric element and the second polymeric element, said interface composition being free of ferromagnetic particles;
closing the outer shell to clamp the polymeric elements together between the inner mandrel and outer shell; and
exposing the molding device to an electromagnetic field thereby heating the polymeric elements and interface composition at least to a fusion temperature of the polymeric element with the highest fusion temperature.
2. The method of claim 1 , wherein the molding device is a clam shell mold.
3. The method of claim 1 , wherein the ferromagnetic particles are selected from the group consisting of Fe 3 O 4 , Fe 2 O 3 , Cr 2 O 3 , and FeCr 2 O 4 .
4. The method of claim 1 , wherein the ferromagnetic particles have sizes in the range of about five nanometers to about one hundred nanometers.
5. The method of claim 1 , wherein the first polymeric element and the second polymeric element are dissimilar and the interface composition is placed between the first and second polymeric elements.
6. The method of claim 1 , wherein the first polymer is a thermoplastic elastomer material and the second polymer is a non-compatible thermoplastic elastomer material.
7. A method of bonding multiple polymeric elements together to form a catheter sized for insertion into a lumen of a body, comprising:
providing a first polymeric element comprising a first polymer on an inner mandrel sized to form a tubular shaft of the catheter;
providing a second polymeric element comprising a second polymer in an outer clam shell sized to form a balloon or an outer tubular shaft of the catheter, at least one of the mandrel and outer clam shell containing ferromagnetic particles;
applying an interface composition, not including ferromagnetic particles, but including the first polymer, and the second polymer to a surface of at least one of the first and second polymeric elements;
engaging the first and second polymeric elements at an interface with the interface composition being placed between the first and second polymeric elements by clamping the clam shell around the mandrel with the first and second polymeric elements and interface composition disposed therebetween; and
exposing the at least one of the mandrel and outer clam shell containing ferromagnetic particles to an electromagnetic field, the exposing step causing said elements and composition to rise in temperature and thereby fuse the first and second polymeric elements together.
8. The method of claim 7 , wherein the first polymer and the second polymer are the same polymer.
9. The method of claim 7 , wherein the first polymeric element and the second polymeric element are dissimilar.
10. The method of claim 7 , wherein the first polymer is a thermoplastic elastomer material and the second polymer is a non-compatible thermoplastic elastomer material.
11. The method of claim 7 , wherein the ferromagnetic particles are selected from the group consisting of Fe 3 O 4 , Fe 2 O 3 , Cr 2 O 3 , and FeCr 2 O 4 .
12. The method of claim 7 , wherein the ferromagnetic particles have sizes in the range of about five nanometers to about one hundred nanometers.
13. A method of bonding multiple polymeric elements to form a balloon catheter sized for insertion into a lumen of a body, comprising:
providing a molding device comprising an inner mandrel sized to form a shaft of the catheter and an outer clam shell sized to form a balloon of the catheter, at least one of the mandrel and outer clam shell containing ferromagnetic particles;
placing multiple polymeric elements into operative association with the molding device including a first polymeric element on the mandrel to form the shaft and a second polymeric clement in the clam shell to form the balloon;
wherein one polymeric element contacts an adjacent polymeric element at an interface;
wherein the ferromagnetic particles are present within about 500 nm of a plane parallel to surfaces of two adjacent polymeric elements, said plane equidistant from said surfaces at the interface;
placing an interface composition into operative association with the multiple polymeric elements at the interfaces, the interface composition containing the first polymeric element and the second polymeric element, said interface composition being free of ferromagnetic particles;
closing the outer shell around the inner mandrel with the polymeric elements disposed therebetween to form the balloon catheter; and
exposing the molding device to a magnetic field thereby heating the polymeric elements and interface composition at least to a fusion temperature of the polymeric element with the highest fusion temperature.
14. The method of claim 13 , wherein the ferromagnetic particles are selected from the group consisting of Fe 3 O 4 , Fe 2 O 3 , Cr 2 O 3 , and FeCr 2 O 4 .
15. The method of claim 13 , wherein the ferromagnetic particles have sizes in the range of about five nanometers to about one hundred nanometers.
16. The method of claim 13 , wherein the first polymer of the second placing step is a thermoplastic elastomer material and the second polymer of the second placing step is a non-compatible thermoplastic elastomer material.