The invention relates to a process for the preparation of propylene oxide and an alkenyl aryl, which process involves: (1) reacting an alkyl aryl hydroperoxide with propene to yield propylene oxide and an aryl alcohol; and, (2) contacting, at elevated temperature, feed containing the aryl alcohol obtained in step (1) with a heterogeneous dehydration catalyst to yield an alkenyl aryl, in which process the feed of step (2) has at most 0.30% wt of compounds having a molecular weight of at least 195.
1. A process for the preparation of propylene oxide and an alkenyl aryl, which process comprises:
(1) reacting an alkyl aryl hydroperoxide with propene to yield propylene oxide and an aryl alcohol; and,
(2) contacting, at elevated temperature, feed comprising the aryl alcohol obtained in step (1) with a heterogeneous dehydration catalyst to yield an alkenyl aryl,
in which process the feed of step (2) comprises at most 0.30% wt of compounds having a molecular weight of at least 195.
2. The process according to claim 1 , in which process the aryl alcohol is selected from the group consisting of 1-phenyl ethanol and substituted 1-phenyl ethanol.
3. The process according to claim 2 , in which the feed is a distillate comprising aryl alcohol.
4. The process according to claim 3 , wherein the feed comprises at least 0.001% wt of compounds having a molecular weight of at least 195.
5. The process according to claim 1 , in which process the catalyst comprises an alumina-based catalyst.