Heat-sensitive lithographic printing plate precursor
View Patent ↗A heat-sensitive lithographic printing plate precursor comprising on a support, a hydrophilic layer having a protrusion structure on at least one surface thereof.
1. A heat-sensitive lithographic printing plate precursor comprising on a support, a hydrophilic layer having a protrusion structure on at least one surface thereof, wherein the protrusions have a diameter of from 0.3 to 5.0 μm and a height of from 0.2 to 2.0 μm, and the hydrophilic layer comprises (i) a particulate hydrophilic substance having an average diameter ranging from 0.3 to 5.0 μm or (ii) a colloidal particulate and a flocculant.
2. The heat-sensitive lithographic printing plate precursor as claimed in claim 1 , wherein (1) an ink-receptive layer and (2) the hydrophilic layer as claimed in claim 1 are provided in this order on the support.
3. The heat-sensitive lithographic printing plate precursor as claimed in claim 1 , wherein (1) an ink-receptive layer, (2) the hydrophilic layer as claimed in claim 1 , and (3) a hydrophilic overcoat layer removable on a printing machine are provided in this order on the support.
4. The heat-sensitive lithographic printing plate precursor as claimed in claim 1 , wherein the hydrophilic layer is a layer formed by applying and drying a coating liquid containing a colloidal particulate oxide or hydroxide of at least one element selected from beryllium, magnesium, aluminum, silicon, titanium, boron, germanium, tin, zirconium, iron, vanadium, antimony, and transition metals; and a flocculant.
5. The heat-sensitive lithographic printing plate precursor as claimed in claim 2 , wherein the hydrophilic layer contains a colloidal particulate oxide or hydroxide of at least one element selected from beryllium, magnesium, aluminum, silicon, titanium, boron, germanium, tin, zirconium, iron, vanadium, antimony, and transition metals, and the ink-receptive layer contains a flocculant soluble in a solvent for coating the hydrophilic layer.
6. The heat-sensitive lithographic printing plate precursor as claimed in claim 3 , wherein the hydrophilic layer contains a colloidal particulate oxide or hydroxide of at least one element selected from beryllium, magnesium, aluminum, silicon, titanium, boron, germanium, tin, zirconium, iron, vanadium, antimony, and transition metals, and the ink-receptive layer contains a flocculant soluble in a solvent for coating the hydrophilic layer.
7. The heat-sensitive lithographic printing plate precursor as claimed in claim 5 , wherein the flocculant is a compound capable of forming at least one kind of ion selected from a calcium ion, an aluminum ion, a sodium ion, a potassium ion, a lithium ion, an ammonium ion, a quaternary ammonium ion, a fluoride ion, a chloride ion, a nitrate ion, an acetate ion, a sulfate ion and a phosphate ion.
8. The heat-sensitive lithographic printing plate precursor as claimed in claim 6 , wherein the flocculant is a compound capable of forming at least one kind of ion selected from a calcium ion, an aluminum ion, a sodium ion, a potassium ion, a lithium ion, an ammonium ion, a quaternary ammonium ion, a fluoride ion, a chloride ion, a nitrate ion, an acetate ion, a sulfate ion and a phosphate ion.
9. The heat-sensitive lithographic printing plate precursor as claimed in claim 2 , wherein the hydrophilic layer is a layer formed by applying and drying a coating liquid which contains a solvent capable of dissolving an organic polymer in the ink-receptive layer at a content ranging from 1 to 40% based on the entire solvent of the coating liquid.
10. The heat-sensitive lithographic printing plate precursor as claimed in claim 3 , wherein the hydrophilic layer is a layer formed by applying and drying a coating liquid which contains a solvent capable of dissolving an organic polymer in the ink-receptive layer at a content ranging from 1 to 40% based on the entire solvent of the coating liquid.
11. The heat-sensitive lithographic printing plate precursor as claimed in claim 1 , wherein the protrusions are formed independently of surface shape of the support.
12. The heat-sensitive lithographic printing plate precursor as claimed in claim 1 , wherein the protrusions are semispherical, ellipsoidal or columnar in shape.