Film and film structures having improved oxygen transmission, forming, and puncture resistances
View Patent ↗A breathable film involving at least one polymeric layer of 100% neutralized ionomer containing sufficient aliphatic, mono-functional organic acid salt to essentially triple the oxygen transmission value (OTV) and/or at least one polymeric layer of metallocene polyethylene (mPE) optional blended with low density polyethylene and preferably in combination with one or more outer layers of highly neutralized ionomer (e.g., Surlyn®). Such polymeric film and polymeric film structure has sufficient oxygen permeability, water vapor transmission, formability, and structural strength to be useful in wrapping food products requiring breathable films such as case ready meat, fish, sausage, fresh produce, and the like.
1. An oxygen permeable polymeric film consisting essentially of a blend of (a) one or more aliphatic, mono-functional organic acids having fewer than 36 carbon atoms or salts thereof and (b) one or more E/X/Y copolymers where E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer and wherein 100% of all the acid moieties of (a) and of (b) are nominally neutralized wherein the oxygen permeation rate of the film normalized to one mil thickness is greater than 800 cc-mil/100 in 2 ·day·atm.
2. An oxygen permeable polymeric film of claim 1 wherein acids are neutralized to the corresponding salts of magnesium, sodium, zinc or mixtures thereof.
3. An oxygen permeable polymeric film of claim 2 wherein said blend of (a) and (b) further comprises an antioxidant.
4. An oxygen permeable polymeric film of claim 1 wherein the oxygen permeation rate of said permeable film normalized to one mil thickness is greater than 800 cc-mil/100 in 2 ·day·atm.
5. An oxygen- and moisture-permeable multilayer polymeric film wherein the oxygen permeation rate of the film normalized to one mil thickness is greater than 800 cc-mil/100 in 2 ·day·atm and the film comprises
(i) at least one polymeric layer consisting essentially of an E/X/Y copolymer where E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer and wherein from 15% to 80% of the acid is neutralized;
(ii) at least one other polymeric layer consisting essentially of a blend of (a) one or more aliphatic, mono-functional organic acids having fewer than 36 carbon atoms or salts thereof and (b) one or more E/X/Y copolymers where E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer and wherein 100% of all acid moieties of (a) and of (b) are nominally neutralized to the corresponding salts of magnesium, sodium, zinc or mixtures thereof; and
(iii) at least one additional polymeric layer consisting essentially of a metallocene polyethylene having a density of less than 0.91 g/cc; or a blend of a metallocene polyethylene having a density of less than 0.91 g/cc and a low density polyethylene.
6. An oxygen and moisture permeable polymeric film of claim 5 wherein component (ii) further comprises an antioxidant.
7. An oxygen and moisture permeable multilayer polymeric film wherein the oxygen permeation rate of the film normalized to one mil thickness is greater than 800 cc-mil/100 in 2 ·day·atm and the film comprises
(i) at least one polymeric layer consisting essentially of a blend of (a) one or more aliphatic, mono-functional organic acids having fewer than 36 carbon atoms or salts thereof and (b) one or more E/X/Y copolymers where E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer and wherein 100% of all acids of (a) and of (b) are nominally neutralized to the corresponding salts of magnesium, sodium, zinc or mixtures thereof; and
(ii) at least one additional polymeric layer consisting essentially of a metallocene polyethylene having a density of less than 0.91 g/cc; or a blend of a metallocene polyethylene having a density of less than 0.91 g/cc and a low density polyethylene.
8. An oxygen and moisture permeable polymeric film of claim 7 wherein component (i) further comprises an antioxidant.
9. An oxygen and moisture permeable multilayer polymeric film wherein the oxygen permeation rate of the film normalized to one mil thickness is greater than 800 cc-mil/100 in 2 ·day·atm and the film comprises
(i) at least one polymeric layer consisting essentially of an E/X/Y copolymer where E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer and wherein from 15% to 80% of the acid is neutralized; and
(ii) at least one other polymeric layer consisting essentially of a blend of (a) one or more aliphatic, mono-functional organic acids having fewer than 36 carbon atoms or salts thereof and (b) one or more E/X/Y copolymers where E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer and wherein 100% of all acid moieties of (a) and of (b) are nominally neutralized to the corresponding salts of magnesium, sodium, zinc or mixtures thereof.
10. An oxygen and moisture permeable polymeric film of claim 9 wherein component (ii) further comprises an antioxidant.
11. An oxygen and moisture permeable multilayer polymeric film of claim 9 comprising three polymeric layers wherein both outer layers consist essentially of said E/X/Y copolymer of (i) and a middle layer consists essentially of said blend of E/X/Y copolymer and aliphatic, mono-functional organic acid 100% nominally neutralized of (ii).
12. A packaged food product comprising an article of food enclosed in a multilayer polymer film, wherein
at least one layer of said film consists essentially of a blend of (a) one or more aliphatic, mono-functional organic acids having fewer than 36 carbon atoms or salts thereof and (b) one or more E/X/Y copolymers;
E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer;
100% of all the acid moieties of (a) and of (b) are neutralized to the corresponding salts of magnesium, sodium, zinc or mixtures thereof and
the oxygen permeation rate of the film normalized to one mil thickness is greater than 800 cc-mil/100 in 2 ·day·atm.
13. A packaged food product of claim 12 wherein said aliphatic, mono-functional organic acid is selected from the group consisting of palmitic acid, stearic acid, oleic acid, and mixtures thereof.
14. A packaged food product of claim 13 wherein said blend of (a) and (b) further comprises an antioxidant.
15. A packaged food product comprising an article of food enclosed in a multilayer polymer film, wherein the oxygen permeation rate of the film normalized to one mil thickness is greater than 800 cc-mil/100 in 2 *day*atm and at least one layer of said film consists essentially of:
(i) a blend of (a) one or more aliphatic, mono-functional organic acids having fewer than 36 carbon atoms or salts thereof and (b) one or more E/X/Y copolymers where E is derived from ethylene, X is derived from C 3 to C 8 α,β-ethylenically unsaturated carboxylic acids, and Y is derived from a softening comonomer, or ionomers of said E/X/Y copolymers, wherein X is about 3 to 30 wt. % of said E/X/Y copolymer, and Y is 0 to about 30 wt. % of said E/X/Y copolymer and wherein 100% of all acid moieties of (a) and of (b) are nominally neutralized to the corresponding salts of magnesium, sodium, zinc or mixtures thereof; and
(ii) at least one additional polymeric layer consisting essentially of a metallocene polyethylene.
16. A packaged food product of claim 15 wherein (i) further comprises an antioxidant.