Method for producing homo-and co-polymers of ethylene
The present invention provides a method for producing homo- and co-polymers of ethylene, or more particularly a method for producing homo- and co-polymers of ethylene in the presence of (a) a solid titanium catalyst produced by preparing a magnesium solution by contact-reacting a halogenated magnesium compound with an alcohol; reacting thereto an ester compound having at least one hydroxyl group and a silicon compound having at least one alkoxy group; and adding a mixture of a titanium compound and a silicon compound; (b) organometallic compounds of Group II or III of the Periodic Table; and (c) a cyclic nitrogen compound. The catalyst for homo- and co-polymerization of ethylene, produced according to the present invention, exhibits high activity, and the polymers produced by the method of the present invention by using said catalyst have the advantages of exhibiting high bulk densities and narrow molecular weight distributions.
1. A method for producing homo- and co-polymers of ethylene, which comprises carrying out polymerization in the presence of:
(a) a solid titanium catalyst produced by the method comprising:
(i) preparing a magnesium compound solution by contact-reacting a halogenated magnesium compound with an alcohol;
(ii) reacting the magnesium compound solution with electron donors, the electron donors comprising an ester compound having at least one hydroxyl group and a first silicon compound having at least one alkoxy group; and
(iii) reacting the mixture resulting from the reaction of the magnesium compound solution with electron donors with a titanium compound and a second silicon compound;
(b) organometallic compounds of Group II or III of the Periodic Table; and
(c) a cyclic nitrogen compound.
2. The method according to claim 1 , wherein said ester compound having at least one hydroxyl group is an unsaturated aliphatic acid ester having at least one hydroxyl group, an aliphatic monoester or polyester containing at least one hydroxyl group, an aromatic ester having at least one hydroxyl group, or an alicyclic ester having at least one hydroxyl group, and wherein said first silicon compound having at least one alkoxy group is represented by a general formula of R n Si(OR) 4-n , where R stands for a hydrocarbon having 1˜12 carbons; and n for an integer of 0˜3.
3. The method according to claim 1 , wherein said titanium compound is represented by a general formula of Ti(OR) a X 4-a , where R stands for a hydrocarbon group, X for a halogen atom, and a for a natural number of 0˜4; and wherein said silicon compound is represented by a general formula of R n SiCl 4-n , where R stands for hydrogen; an alkyl, alkoxy, haloalkyl, or aryl group having 1˜10 carbons; or a halosilyl or halosilylalkyl group having 1˜8 carbons; and n for a natural number of 0˜3.
4. The method according to claim 1 , wherein said titanium compound is a 4-halogenated titanium, a 3-halogenated alkoxytitanium, a 2-halogenated alkoxytitanium, and a tetralkoxytitanium and wherein said second silicon compound is silicon tetrachloride, a trichlorosilane, a dichlorosilane, or a monochlorosilane.
5. The method according to claim 1 , wherein said titanium compound is titanium tetrachloride, and said second silicon compound is silicon tetrachloride.
6. The method according to claim 1 , wherein said solid titanium catalyst is produced by further reacting the product of step (a)(iii) with an additional titanium compound.
7. The method according to claim 1 , wherein said cyclic nitrogen compound is 2,6-lutidine, 2,3-dimethylquinoxaline, quinaldine, 2,4,6-collidine, 2,4-dimethylquinoline, 2-picoline, 2,3,5,6-tetramethylpyrazine, phenazine, acridine, di-t-butylpyridine, or a mixture thereof.
8. The method according to claim 1 , wherein said ester compound having at least one hydroxyl group is an unsaturated aliphatic acid ester having at least one hydroxyl group; an aliphatic monoester or polyester containing at least one hydroxyl group; an aromatic ester having at least one hydroxyl group; or an alicyclic ester having at least one hydroxyl group.
9. The method according to claim 1 , wherein said first silicon compound is represented by a general formula of R n Si(OR) 4-n , where R stands for a hydrocarbon having 1˜12 carbons; and n for an integer of 0˜3.
10. The method according to claim 1 , wherein said titanium compound is represented by a general formula of Ti(OR) a X 4-n , where R stands for a hydrocarbon group, X for a halogen atom, and a for a natural number of 0˜4.
11. The method according to claim 1 , wherein said second silicon compound is represented by a general formula of R n SiCl 4-n , where R stands for hydrogen; an alkyl, alkoxy, haloalkyl, or aryl group having 1˜10 carbons; or a halosilyl or halosilylalkyl group having 1˜8 carbons; and n for a natural number of 0˜3.