Amorphous coke for special carbon material and production process for the same
View Patent ↗Provided are an amorphous coke for a special carbon material characterized in that it is an amorphous coke obtained by blending a coal tar base heavy oil and/or a petroleum base heavy oil with a resin and subjecting the mixture to thermal decomposition polycondensation; it has a larger thermal expansion coefficient than that of a coke obtained from a heavy oil alone; and a molded article of the coke is shrunk by 0.3% or more in terms of a volume change rate before and after the treatment when it is subjected to graphitizing treatment, and a production process of an amorphous coke for a special carbon material characterized in that in subjecting a coal tar base heavy oil or a petroleum base heavy oil to thermal decomposition polycondensation, the raw material is blended with a resin to modify a coke crystal structure.
1. A production process of an amorphous coke for a special carbon material characterized in that in subjecting a heavy oil comprising at least one selected from the group consisting of high boiling tar oil, tar pitch, decant oil, ethylene tar and a vacuum residue of a low sulfur crude oil used as a principal raw material to thermal decomposition polycondensation, the raw material is blended with at least one resin selected from the group consisting of a polyethylene terephthalate resin, a polystyrene resin, a urethane resin, a polyethylene resin and a polypropylene resin in a blending proportion falling in a range of 5 to 50 percent by weight to modify a coke crystal structure, and the thermal decomposition polycondensation is carried out by delayed coking treatment in which the raw material mixed with the at least one resin is subjected to thermal treatment in a range of 400 to 550° C. and then to coking reaction to produce a raw coke and in which the raw coke is subjected to calcination treatment at 1200 to 1500° C., wherein the kind of the resin and a blending amount thereof are controlled so that the resulting coke has a larger thermal expansion coefficient than that of a coke obtained from the raw material blended with no resin.