Natural fiber-filled polyolefin composites
View Patent ↗A process for preparing a composite material is disclosed wherein the process comprises: A) sizing a natural fiber with a reactive organosilane; B) mixing the sized natural fiber with a polyolefin resin; and C) adding a functionalized polyolefin coupling agent to the mixture of the sized natural fiber and the polyolefin resin to provide said composite material.
1. A process for preparing a composite material consisting essentially of the steps of:
A) sizing a natural fiber with a reactive organosilane;
B) mixing the sized natural fiber with a high density polyethylene resin; and
C) adding a functionalized polyolefin coupling agent to the mixture of the sized natural fiber and the high density polyethylene resin to provide said composite material;
wherein the functionalized polyolefin coupling agent is selected from the group consisting of maleic anhydride modified polypropylenes having a weight average molecular weight in the range of from about 20,000 to about 300,000 and comprising from about 0.6 to 310 moles of maleic anhydride per mole of polymer and maleic anhydride modified high density polyethylenes having a weight average molecular weight in the range of from about 20,000 to about 300,000 and comprising from about 0.6 to 310 moles of maleic anhydride per mole of polymer.
2. The process of claim 1 wherein the natural fiber is selected from the group consisting of wood flour, wood fiber, and agricultural fiber.
3. The process of claim 2 wherein the natural fiber is selected from the group consisting of wood flour, wood fiber, hemp, flax, and kenaf.
4. The process of claim 1 wherein the natural fiber is employed at a level in the range of from about 20 to about 85 weight % based on the weight of the total formulation.
5. The process of claim 1 wherein the reactive organosilane is selected from the group consisting of aminosilanes, epoxysilanes, alkoxysilanes, methacrylic silanes, mercaptosilanes, chlorosilanes, and oligomers, mixtures, and blends thereof.
6. The process of claim 1 wherein the reactive organosilane is γ-aminopropyltriethoxysilane.
7. The process of claim 1 wherein the reactive organosilane is selected from the group consisting of γ-aminopropyltriethoxysilane, γ-methacryloxypropyl trimethoxysilane, propyl triethoxy silane, vinyltriethoxysilane, vinyltri(2-methoxy-ethoxy)silane, β-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane, γ-glycidoxypropyltrimethoxysilane, γ-mercaptopropyltrimethoxysilane, n-β-(aminoethyl)-γ-aminopropyltrimethoxysilane, n-β-(aminoethoxyl)-γ-aminopropyltrimethoxysilane, γ-chloropropyltrimethoxysilane, and silylating agents having the general formula
or an oligomer thereof, wherein R 1 , R 2 , and R 3 are independently selected from the group consisting of alkoxy, alkyl, alkenyl, cycloalkyl, aryl, aralkyl, and organo-functional moieties.
8. The process of claim 1 wherein the natural fiber is employed at a level in the range of from about 40 to about 70 weight % based on the weight of the total formulation.
9. A composite material prepared by a process consisting essentially of the steps of:
A) sizing a natural fiber with a reactive organosilane;
B) mixing the sized natural fiber with a high density polyethylene resin; and
C) adding a functionalized polyolefin coupling agent to the mixture of the sized natural fiber and the high density polyethylene resin to provide said composite material;
wherein the functionalized polyolefin coupling agent is selected from the group consisting of maleic anhydride modified polypropylenes having a weight average molecular weight in the range of from about 20,000 to about 300,000 and comprising from about 0.6 to 310 moles of maleic anhydride per mole of polymer and maleic anhydride modified high density polyethylenes having a weight average molecular weight in the range of from about 20,000 to about 300,000 and comprising from about 0.6 to 310 moles of maleic anhydride per mole of polymer.
10. The composite material of claim 9 wherein the natural fiber is selected from the group consisting of wood flour, wood fiber, and agricultural fiber.
11. The composite material of claim 10 wherein the natural fiber is selected from the group consisting of wood flour, wood fiber, hemp, flax, and kenaf.
12. The composite material of claim 9 wherein the natural fiber is employed at a level in the range of from about 20 to about 85 weight % based on the weight of the total formulation.
13. The composite material of claim 9 wherein the reactive organosilane is selected from the group consisting of aminosilanes, epoxysilanes, alkoxysilanes, methacrylic silanes, mercaptosilanes, chlorosilanes, and oligomers, mixtures, and blends thereof.
14. The composite material of claim 9 wherein the reactive organosilane is selected from the group consisting of γ-aminopropyltriethoxysilane, γ-methacryloxypropyl trimethoxysilane, propyl triethoxy silane, vinyltriethoxysilane, vinyltri(2-methoxy-ethoxy)silane, β-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane, γ-glycidoxypropyltrimethoxysilane, γ-mercaptopropyltrimethoxysilane, n-β-(aminoethyl)-γ-aminopropyltrimethoxysilane, n-β-(aminoethoxyl)-y-aminopropyltrimethoxysilane, γ-chloropropyltrimethoxysilane, and silylating agents having the general formula
or an oligomer thereof, wherein R 1 , R 2 , and R 3 are independently selected from the group consisting of alkoxy, alkyl, alkenyl, cycloalkyl, aryl, aralkyl, and organo-functional moieties.
15. The composite material of claim 9 wherein the reactive organosilane is γ-aminopropyltriethoxysilane.
16. The composite material of claim 9 wherein the natural fiber is employed at a level in the range of from about 40 to about 70 weight % based on the weight of the total formulation.