Friction modifier alkoxyamine salts of carboxylic acids as additives for fuel compositions and methods of use thereof
View Patent ↗A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkoxylated amine or etheramine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkoxylated amine, such as isohexyloxypropylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy. Moreover, the use of the friction modifier (a) in combination with a detergent package permits increased fuel efficiency to be obtained without increasing the incidence of IVD deposits in combustion engines running on a fuel modified with the additive concentrate.
1. A composition of matter useful as an additive concentrate for combustion engine fuels, comprising a saturated branched or cyclic carboxylic acid salt of isodecyloxypropylamine and a detergent package comprising detergent and carrier fluid.
2. The composition of claim 1 , wherein the carboxylic acid is selected from the group consisting of monocarboxylic acids, dicarboxylic acids, and polycarboxylic acids.
3. The composition of claim 1 , wherein the detergent of the detergent package is selected from the group consisting of Mannich bases, polyalkylene amines, polyalkylene succinimides polyether amines, singly or in combinations thereof.
4. The composition of claim 1 , further comprising a petroleum solvent.
5. A composition of matter useful as an additive concentrate for combustion engine fuels, comprising the reaction product from combining isodecyloxyproplymine and isostearic acid, and a detergent package comprising detergent and carrier fluid.
6. A method for increasing the fuel efficiency in a gasoline combustion engine, said method comprising combusting in the engine a gasoline fuel comprising a major amount of a fuel boiling in the gasoline boiling range, and a minor amount of a branched or cyclic saturated carboxylic acid salt of an alkoxylated amine or etheramine, wherein the amine is selected from the group consisting of
Isododecyloxypropylamine
Isotridecyloxypropylamine
C 12-15 alkyloxypropylamine
Isodecyloxypropyl-1,3-diaminopropane
Isododecyloxypropyl-1,3-diaminopropane
Isotridecyloxypropyl-3-diaminopropane
Isohexyloxypropylamine
2-ethylhexyloxypropylamine
Octyl/Decyloxypropylamine
Isodecyloxypropylamine
Isopropyloxypropylamine
Tetradecyloxypropylamine
Dodecyl/tetradecyloxypropylamine
Tetradecyl/dodecyloxypropylamine
Octadecyl/hexadecyloxypropylamine
Tetradecyloxypropyl-1,3-diaminopropane, and
C 12 –C 15 alkyloxypropyl-1,3-diaminopropane.
7. The method of claim 6 , wherein the saturated carboxylic acid salt of an alkoxylated amine or etheramine is present in the fuel in an amount sufficient to increase the fuel efficiency relative to the fuel efficiency obtained by combusting in said engine a gasoline fuel which does not comprise a saturated carboxylic acid salt of an alkoxylated amine or etheramine.
8. The method of claim 6 , wherein the engine has intake valves and the fuel further comprises a minor amount of a detergent in an amount sufficient to reduce the amount of intake valve deposits (IVD) formed relative to the amount of intake valve deposits formed by combusting in said engine a gasoline fuel which comprises in equivalent amount a friction modifier formed by combining a branched or cyclic saturated carboxylic acid and an alkoxylated amine or etheramine.